skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Palladium–gold single atom alloy catalysts for liquid phase selective hydrogenation of 1-hexyne

Journal Article · · Catalysis Science and Technology
DOI:https://doi.org/10.1039/C7CY00794A· OSTI ID:1469929

Silica supported and unsupported PdAu single atom alloys (SAAs) were investigated for the selective hydrogenation of 1-hexyne to hexenes under mild conditions.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0012573
OSTI ID:
1469929
Journal Information:
Catalysis Science and Technology, Vol. 7, Issue 19; Related Information: IMASC partners with Harvard University (lead); Fritz Haber Institute; Lawrence Berkeley National Laboratory; Lawrence Livermore National Laboratory; University of Kansas; Tufts University; ISSN 2044-4753
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (59)

Palladium Nanoparticle Size Effect in 1-Hexyne Selective Hydrogenation journal August 2007
Oxidation of Methane to Methanol with Hydrogen Peroxide Using Supported Gold-Palladium Alloy Nanoparticles journal December 2012
Physical and chemical properties of bimetallic surfaces journal January 1996
New developments in hydrogenation catalysis particularly in synthesis of fine and intermediate chemicals journal February 2005
Formation of monometallic Au and Pd and bimetallic Au–Pd nanoparticles confined in mesopores via Ar glow-discharge plasma reduction and their catalytic applications in aerobic oxidation of benzyl alcohol journal May 2012
Identification of Non-Precious Metal Alloy Catalysts for Selective Hydrogenation of Acetylene journal June 2008
Role of the Support in Determining the Vibrational Properties of Carbonyls Formed on Pd Supported on SiO 2 −Al 2 O 3 , Al 2 O 3 , and MgO journal May 2007
Tackling CO Poisoning with Single-Atom Alloy Catalysts journal May 2016
Synergetic effect of gold in Au/Pd catalysts during hydrodesulfurization reactions of model compounds journal April 2003
Enhancement in Aerobic Alcohol Oxidation Catalysis of Au 25 Clusters by Single Pd Atom Doping journal June 2012
Catalytically active Au-O(OH) x - species stabilized by alkali ions on zeolites and mesoporous oxides journal November 2014
Selective hydrogenation of acetylene in excess ethylene using Ag- and Au–Pd/SiO2 bimetallic catalysts prepared by electroless deposition journal January 2014
Catalytically highly active top gold atom on palladium nanocluster journal October 2011
An In Situ Spectroscopic Study of Prochiral Reactant–Chiral Modifier Interactions on Palladium Catalyst: Case of Alkenoic Acid and Cinchonidine in Various Solvents journal August 2013
Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit journal October 2015
A Common Single-Site Pt(II)–O(OH) x – Species Stabilized by Sodium on “Active” and “Inert” Supports Catalyzes the Water-Gas Shift Reaction journal March 2015
Photochemical route for synthesizing atomically dispersed palladium catalysts journal May 2016
Water co-catalyzed selective dehydrogenation of methanol to formaldehyde and hydrogen journal August 2016
Nanocrystalline gold and gold palladium alloy catalysts for chemical synthesis journal January 2008
Hydrogenation of acetylene over low loaded Pd and Pd-Au/SiO2 catalysts journal April 2002
Alkali-Stabilized Pt-OHx Species Catalyze Low-Temperature Water-Gas Shift Reactions journal September 2010
Selective Hydrogen Production from Formic Acid Decomposition on Pd–Au Bimetallic Surfaces journal July 2014
High performing and stable supported nano-alloys for the catalytic hydrogenation of levulinic acid to γ-valerolactone journal March 2015
Bimetallic Au–Pd catalysts for selective hydrogenation of butadiene: Influence of the preparation method on catalytic properties journal January 2013
Supported nitrogen-modified Pd nanoparticles for the selective hydrogenation of 1-hexyne journal April 2011
The liquid-phase hydrogenation of 1-heptyne over Pd–Au/TiO 2 catalysts prepared by the combination of incipient wetness impregnation and deposition–precipitation journal January 2013
Ligand ordering determines the catalytic response of hybrid palladium nanoparticles in hydrogenation journal January 2016
Gold-Palladium Core-Shell Nanocrystals with Size and Shape Control Optimized for Catalytic Performance journal December 2012
On the Role of Surface Modifications of Palladium Catalysts in the Selective Hydrogenation of Acetylene journal October 2008
Pd–Au bimetallic catalysts: understanding alloy effects from planar models and (supported) nanoparticles journal January 2012
Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations journal March 2012
Supported Palladium–Gold Alloy Catalysts for Efficient and Selective Hydrosilylation under Mild Conditions with Isolated Single Palladium Atoms in Alloy Nanoparticles as the Main Active Site journal January 2017
Alkali promotion of alumina-supported ruthenium catalysts for hydrogenation of levulinic acid to γ-valerolactone journal March 2017
Shape-controlled synthesis of Au–Pd bimetallic nanocrystals for catalytic applications journal January 2016
AuPd alloy formation in Au-Pd/Al2O3 catalysts and its role on aromatics hydrogenation journal April 2005
Preparation of Pdshell–Aucore/SiO2 catalyst and catalytic activity for acetylene hydrogenation journal November 2008
Selective Oxygen-Assisted Reactions of Alcohols and Amines Catalyzed by Metallic Gold: Paradigms for the Design of Catalytic Processes journal December 2016
Selective Hydrogenation of Acetylene over Au/Al 2 O 3 Catalyst journal November 2000
Interactions of Hydrogen and Carbon Monoxide on Pd–Au Bimetallic Surfaces journal January 2014
A Stable Single-Site Palladium Catalyst for Hydrogenations journal July 2015
Effect of surface temperature on the sorption of hydrogen by Pd(111) journal March 1987
Pd–Au single-crystal surfaces: Segregation properties and catalytic activity in the selective hydrogenation of 1,3-butadiene journal November 2005
In situ ATR-IR study of prochiral 2-methyl-2-pentenoic acid adsorption on Al2O3 and Pd/Al2O3 journal January 2011
Direct synthesis of hydrogen peroxide from H2 and O2 using TiO2-supported Au–Pd catalysts journal November 2005
The Promotional Effect of Gold in Catalysis by Palladium-Gold journal October 2005
Single-Atom Pd 1 /Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene journal August 2015
Efficient and Durable Au Alloyed Pd Single-Atom Catalyst for the Ullmann Reaction of Aryl Chlorides in Water journal April 2014
Single Atom Hot-Spots at Au–Pd Nanoalloys for Electrocatalytic H 2 O 2 Production journal December 2011
Rational nanoparticle synthesis to determine the effects of size, support, and K dopant on Ru activity for levulinic acid hydrogenation to γ-valerolactone journal June 2015
Acido-basicity of lanthana/alumina catalysts and their activity in ethanol conversion journal January 2017
Single atom alloy surface analogs in Pd0.18Cu15 nanoparticles for selective hydrogenation reactions journal January 2013
Selective non-oxidative dehydrogenation of ethanol to acetaldehyde and hydrogen on highly dilute NiCu alloys journal May 2017
Promotional effect of Pd single atoms on Au nanoparticles supported on silica for the selective hydrogenation of acetylene in excess ethylene journal January 2014
Preparation of Egg-Shell Type Pd-Ag and Pd-Au Catalysts by Selective Deposition and Hydrogenation of 1,3-Butadiene book January 1993
Advances in the Design of Nanostructured Catalysts for Selective Hydrogenation journal December 2015
Hydrogen production from formic acid decomposition at room temperature using a Ag–Pd core–shell nanocatalyst journal April 2011
Switching Off Hydrogen Peroxide Hydrogenation in the Direct Synthesis Process journal February 2009
Selective Hydrogenation of 1,3-Butadiene in the Presence of an Excess of Alkenes over Supported Bimetallic Gold−Palladium Catalysts journal May 2010
Controlling Hydrogen Activation, Spillover, and Desorption with Pd–Au Single-Atom Alloys journal January 2016