Ion transport in gel and gel–liquid systems for LiClO 4 -doped PMMA at the meso- and nanoscales

doi:10.1039/C7NR06719D

Title: Ion transport in gel and gel–liquid systems for LiClO ₄ -doped PMMA at the meso- and nanoscales

Abstract

Ionic transport in gel electrolytes at the nano- and mesoscales is explored experimentally using single pores.

Authors:

Plett, Timothy ^[1]; Thai, Mya Le ^[2]; Cai, Josslyn ^[1]; Vlassiouk, Ivan ^[3]; Penner, Reginald M. ^[2];

^[4]

Department of Physics and Astronomy; University of California; Irvine; USA
Department of Chemistry; University of California; Irvine; USA
Oak Ridge National Laboratory; Oak Ridge; USA
Department of Physics and Astronomy; University of California; Irvine; USA; Department of Chemistry

Publication Date:: 2017-01-01

Research Org.:: Energy Frontier Research Centers (EFRC) (United States). Nanostructures for Electrical Energy Storage (NEES)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI Identifier:: 1469900

DOE Contract Number:: SC0001160

Resource Type:: Journal Article

Journal Name:: Nanoscale

Additional Journal Information:: Journal Volume: 9; Journal Issue: 42; Related Information: NEES partners with University of Maryland (lead); University of California, Irvine; University of Florida; Los Alamos National Laboratory; Sandia National Laboratories; Yale University; Journal ID: ISSN 2040-3364

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: bio-inspired, energy storage (including batteries and capacitors), defects, charge transport, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats


                    Plett, Timothy, Thai, Mya Le, Cai, Josslyn, Vlassiouk, Ivan, Penner, Reginald M., and Siwy, Zuzanna S. Ion transport in gel and gel–liquid systems for LiClO 4 -doped PMMA at the meso- and nanoscales.  United States: N. p., 2017. 
        Web.  doi:10.1039/C7NR06719D.

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                    Plett, Timothy, Thai, Mya Le, Cai, Josslyn, Vlassiouk, Ivan, Penner, Reginald M., & Siwy, Zuzanna S. Ion transport in gel and gel–liquid systems for LiClO 4 -doped PMMA at the meso- and nanoscales.  United States.  doi:10.1039/C7NR06719D.

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                    Plett, Timothy, Thai, Mya Le, Cai, Josslyn, Vlassiouk, Ivan, Penner, Reginald M., and Siwy, Zuzanna S. Sun .  
        "Ion transport in gel and gel–liquid systems for LiClO 4 -doped PMMA at the meso- and nanoscales".  United States.  doi:10.1039/C7NR06719D.

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@article{osti_1469900,

  title        = {Ion transport in gel and gel–liquid systems for LiClO 4 -doped PMMA at the meso- and nanoscales},

  author       = {Plett, Timothy and Thai, Mya Le and Cai, Josslyn and Vlassiouk, Ivan and Penner, Reginald M. and Siwy, Zuzanna S.},

  abstractNote = {Ionic transport in gel electrolytes at the nano- and mesoscales is explored experimentally using single pores.},

  doi          = {10.1039/C7NR06719D},

  journal      = {Nanoscale},

  issn         = {2040-3364},

  number       = 42,

  volume       = 9,

  place        = {United States},

  year         = {2017},

  month        = {1}

}

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DOI: 10.1039/C7NR06719D

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Title: Ion transport in gel and gel–liquid systems for LiClO 4 -doped PMMA at the meso- and nanoscales

Abstract

Citation Formats

The zeta potential of PMMA in contact with electrolytes of various conditions: Theoretical and experimental investigation: General journal, December 2013

Rectification of Ionic Current in a Nanofluidic Diode journal, March 2007

Lithium Electrode Morphology during Cycling in Lithium Cells journal, January 1988

Ion-Complexation-Induced Changes in the Interaction Parameter and the Chain Conformation of PS- b -PMMA Copolymers journal, July 2008

A Lithographically Patterned Capacitor with Horizontal Nanowires of Length 2.5 mm journal, March 2014

Ionic conductivity of a single porous MnO 2 mesorod at controlled oxidation states journal, January 2015

Comparison of bipolar and unipolar ionic diodes journal, June 2010

Ion-Current Rectification in Nanopores and Nanotubes with Broken Symmetry journal, April 2006

Solid-State Ionic Diodes Demonstrated in Conical Nanopores journal, March 2017

Network structure of poly(methyl methacrylate)-based gels and gel electrolytes journal, May 2006

Pore structure and function of synthetic nanopores with fixed charges: tip shape and rectification properties journal, June 2008

Transport phenomena in nanofluidics journal, July 2008

Rectified Ion Transport through Concentration Gradient in Homogeneous Silica Nanochannels journal, October 2007

A pH-Tunable Nanofluidic Diode with a Broad Range of Rectifying Properties journal, February 2009

Ion Current Rectification at Nanopores in Glass Membranes journal, March 2008

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Atomic Layer Deposition of the Solid Electrolyte LiPON journal, July 2015

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Single Conical Nanopores Displaying pH-Tunable Rectifying Characteristics. Manipulating Ionic Transport With Zwitterionic Polymer Brushes journal, February 2009

Study of the ion conduction of polymer electrolytes confined in micro and nanopores journal, June 2003

Ionic Current Rectification in Organic Solutions with Quartz Nanopipettes journal, August 2015

Current Rectification at Quartz Nanopipet Electrodes journal, November 1997

Conical Nanopore Membranes: Controlling the Nanopore Shape journal, February 2006

Microstructural Effects on Charge-Storage Properties in MnO 2 -Based Electrochemical Supercapacitors journal, April 2009

A Poisson/Nernst-Planck model for ionic transport through synthetic conical nanopores journal, July 2005

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Electroosmotic Flow Can Generate Ion Current Rectification in Nano- and Micropores journal, December 2009

Ionic conduction, rectification, and selectivity in single conical nanopores journal, March 2006

Electro-responsive asymmetric nanopores in polyimide with stable ion-current signal journal, March 2003

Tunable Negative Differential Electrolyte Resistance in a Conical Nanopore in Glass journal, June 2012

Structural forces as a result of nonlocal water polarizability journal, September 1987

Probing Porous Structure of Single Manganese Oxide Mesorods with Ionic Current journal, November 2013

Structural and Electrochemical Analysis of PMMA Based Gel Electrolyte Membranes journal, January 2015

Fabrication of hydrogel-coated single conical nanochannels exhibiting controllable ion rectification characteristics journal, January 2015

Electrochemical Synthesis of Bi 1– x Sb x Nanowires with Simultaneous Control on Size, Composition, and Surface Roughness journal, December 2011

Fabrication of a Synthetic Nanopore Ion Pump journal, October 2002

Ionic Current Rectification through Silica Nanopores journal, January 2009

Electric Double Layer near Soft Permeable Interfaces. 1. Local Electrostatic journal, June 1994

100k Cycles and Beyond: Extraordinary Cycle Stability for MnO 2 Nanowires Imparted by a Gel Electrolyte journal, April 2016

Note on nonaqueous electrokinetic transport in charged porous media journal, September 1984

Long Cycle-Life Secondary Lithium Cells Utilizing Tetrahydrofuran journal, January 1984

History, Evolution, and Future Status of Energy Storage journal, May 2012

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Title: Ion transport in gel and gel–liquid systems for LiClO ₄ -doped PMMA at the meso- and nanoscales

The zeta potential of PMMA in contact with electrolytes of various conditions: Theoretical and experimental investigation: General
journal, December 2013

Rectification of Ionic Current in a Nanofluidic Diode
journal, March 2007

Lithium Electrode Morphology during Cycling in Lithium Cells
journal, January 1988

Ion-Complexation-Induced Changes in the Interaction Parameter and the Chain Conformation of PS- b -PMMA Copolymers
journal, July 2008

A Lithographically Patterned Capacitor with Horizontal Nanowires of Length 2.5 mm
journal, March 2014

Ionic conductivity of a single porous MnO ₂ mesorod at controlled oxidation states
journal, January 2015

Comparison of bipolar and unipolar ionic diodes
journal, June 2010

Ion-Current Rectification in Nanopores and Nanotubes with Broken Symmetry
journal, April 2006

Solid-State Ionic Diodes Demonstrated in Conical Nanopores
journal, March 2017

Network structure of poly(methyl methacrylate)-based gels and gel electrolytes
journal, May 2006

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journal, June 2008

Transport phenomena in nanofluidics
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journal, October 2007

A pH-Tunable Nanofluidic Diode with a Broad Range of Rectifying Properties
journal, February 2009

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journal, March 2008

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004

Rectification of nanopores in aprotic solvents – transport properties of nanopores with surface dipoles
journal, January 2015

Nanofluidic Ionic Diodes. Comparison of Analytical and Numerical Solutions
journal, July 2008

Diode-like single-ion track membrane prepared by electro-stopping
journal, November 2001

Ionic Selectivity of Single Nanochannels
journal, July 2008

Ion transfer across electrodialysis membranes in the overlimiting current range: stationary voltage current characteristics and current noise power spectra under different conditions of free convection
journal, July 1992

Atomic Layer Deposition of the Solid Electrolyte LiPON
journal, July 2015

AC ionic conductivity and DC polarization method of lithium ion transport in PMMA–LiBF4 gel polymer electrolytes
journal, January 2012

Impedance studies on plasticized PMMA-LiX [X: CF3SO3−, N(CF3SO2)2−] polymer electrolytes
journal, April 2007

Single Conical Nanopores Displaying pH-Tunable Rectifying Characteristics. Manipulating Ionic Transport With Zwitterionic Polymer Brushes
journal, February 2009

Study of the ion conduction of polymer electrolytes confined in micro and nanopores
journal, June 2003

Ionic Current Rectification in Organic Solutions with Quartz Nanopipettes
journal, August 2015

Current Rectification at Quartz Nanopipet Electrodes
journal, November 1997

Conical Nanopore Membranes: Controlling the Nanopore Shape
journal, February 2006

Microstructural Effects on Charge-Storage Properties in MnO ₂ -Based Electrochemical Supercapacitors
journal, April 2009

A Poisson/Nernst-Planck model for ionic transport through synthetic conical nanopores
journal, July 2005

Effect of Crystallographic Structure of MnO ₂ on Its Electrochemical Capacitance Properties
journal, February 2008

Electroosmotic Flow Can Generate Ion Current Rectification in Nano- and Micropores
journal, December 2009

Ionic conduction, rectification, and selectivity in single conical nanopores
journal, March 2006

Electro-responsive asymmetric nanopores in polyimide with stable ion-current signal
journal, March 2003

Tunable Negative Differential Electrolyte Resistance in a Conical Nanopore in Glass
journal, June 2012

Structural forces as a result of nonlocal water polarizability
journal, September 1987

Probing Porous Structure of Single Manganese Oxide Mesorods with Ionic Current
journal, November 2013

Structural and Electrochemical Analysis of PMMA Based Gel Electrolyte Membranes
journal, January 2015

Fabrication of hydrogel-coated single conical nanochannels exhibiting controllable ion rectification characteristics
journal, January 2015

Electrochemical Synthesis of Bi _{1– x} Sb _x Nanowires with Simultaneous Control on Size, Composition, and Surface Roughness
journal, December 2011

Fabrication of a Synthetic Nanopore Ion Pump
journal, October 2002

Ionic Current Rectification through Silica Nanopores
journal, January 2009

Electric Double Layer near Soft Permeable Interfaces. 1. Local Electrostatic
journal, June 1994

100k Cycles and Beyond: Extraordinary Cycle Stability for MnO ₂ Nanowires Imparted by a Gel Electrolyte
journal, April 2016

Note on nonaqueous electrokinetic transport in charged porous media
journal, September 1984

Long Cycle-Life Secondary Lithium Cells Utilizing Tetrahydrofuran
journal, January 1984

History, Evolution, and Future Status of Energy Storage
journal, May 2012

Effect of nanopore geometry on ion current rectification
journal, March 2011

Biosensing with Nanofluidic Diodes
journal, June 2009

Engineered voltage-responsive nanopores
journal, January 2010

Rectification properties of conically shaped nanopores: consequences of miniaturization
journal, January 2013