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Title: Structure and dynamic NMR behavior of rhodium complexes supported by Lewis acidic group 13 metallatranes

Abstract

Z-type complexes featuring Rh → Al and Rh → Ga interactions show distorted Rh centers and fluxionality on the NMR timescale.

Authors:
 [1];  [1]; ORCiD logo [1]
  1. Department of Chemistry; Minneapolis; USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1469886
DOE Contract Number:  
SC0012702
Resource Type:
Journal Article
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 46; Journal Issue: 17; Related Information: ICDC partners with University of Minnesota(lead); Argonne National Laboratory; Clemson University; Dow Chemical Company; Northwestern University; Pacific Northwest National Laboratory; University of California Davis; University of Washington; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
catalysis (heterogeneous), materials and chemistry by design, synthesis (novel materials)

Citation Formats

Moore, James T., Smith, Nicholas E., and Lu, Connie C. Structure and dynamic NMR behavior of rhodium complexes supported by Lewis acidic group 13 metallatranes. United States: N. p., 2017. Web. doi:10.1039/C6DT04769F.
Moore, James T., Smith, Nicholas E., & Lu, Connie C. Structure and dynamic NMR behavior of rhodium complexes supported by Lewis acidic group 13 metallatranes. United States. doi:10.1039/C6DT04769F.
Moore, James T., Smith, Nicholas E., and Lu, Connie C. Sun . "Structure and dynamic NMR behavior of rhodium complexes supported by Lewis acidic group 13 metallatranes". United States. doi:10.1039/C6DT04769F.
@article{osti_1469886,
title = {Structure and dynamic NMR behavior of rhodium complexes supported by Lewis acidic group 13 metallatranes},
author = {Moore, James T. and Smith, Nicholas E. and Lu, Connie C.},
abstractNote = {Z-type complexes featuring Rh → Al and Rh → Ga interactions show distorted Rh centers and fluxionality on the NMR timescale.},
doi = {10.1039/C6DT04769F},
journal = {Dalton Transactions},
issn = {1477-9226},
number = 17,
volume = 46,
place = {United States},
year = {2017},
month = {1}
}

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