Structure and dynamic NMR behavior of rhodium complexes supported by Lewis acidic group 13 metallatranes

Moore, James T.; Smith, Nicholas E.; Lu, Connie C.

doi:10.1039/C6DT04769F

Title: Structure and dynamic NMR behavior of rhodium complexes supported by Lewis acidic group 13 metallatranes

Journal Article · Sun Jan 01 00:00:00 EST 2017 · Dalton Transactions

DOI:https://doi.org/10.1039/C6DT04769F· OSTI ID:1469886

Moore, James T. ^[1]; Smith, Nicholas E. ^[1];

^[1]

Department of Chemistry; Minneapolis; USA

Z-type complexes featuring Rh → Al and Rh → Ga interactions show distorted Rh centers and fluxionality on the NMR timescale.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0012702

OSTI ID:: 1469886

Journal Information:: Dalton Transactions, Vol. 46, Issue 17; Related Information: ICDC partners with University of Minnesota(lead); Argonne National Laboratory; Clemson University; Dow Chemical Company; Northwestern University; Pacific Northwest National Laboratory; University of California Davis; University of Washington; ISSN 1477-9226

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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