Reversible S0/MgSx Redox Chemistry in a MgTFSI2/MgCl2 /DME Electrolyte for Rechargeable Mg/S Batteries

Gao, Tao; Hou, Singyuk; Wang, Fei; Ma, Zhaohui; Li, Xiaogang; Xu, Kang; Wang, Chunsheng

doi:10.1002/ange.201708241

Title: Reversible S⁰/MgS_x Redox Chemistry in a MgTFSI₂/MgCl₂ /DME Electrolyte for Rechargeable Mg/S Batteries

Journal Article · Mon Aug 28 00:00:00 EDT 2017 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201708241· OSTI ID:1469863

Gao, Tao ^[1]; Hou, Singyuk ^[1]; Wang, Fei ^[1]; Ma, Zhaohui ^[1]; Li, Xiaogang ^[1]; Xu, Kang ^[2]; Wang, Chunsheng ^[1]

Univ. of Maryland, College Park, MD (United States)
Army Research Lab., Adelphi, MD (United States)

Abstract The redox chemistry of magnesium and its application in rechargeable Mg batteries has received increasing attention owing to the unique benefits of Mg metal electrodes, namely high reversibility without dendrite formation, low reduction potentials, and high specific capacities. The Mg/S couple is of particular interest owing to its high energy density and low cost. Previous reports have confirmed the feasibility of a rechargeable Mg/S battery; however, only limited cycling stability was achieved, and the complicated procedure for the preparation of the electrolytes has significantly compromised the benefits of Mg/S chemistry and hindered the development of Mg/S batteries. Herein, we report the development of the first rechargeable Mg/S battery with a MgTFSI ₂ /MgCl ₂ /DME electrolyte (DME=1,2‐dimethoxyethane, TFSI=bis(trifluoromethanesulfonyl)imide) and realize the best cycling stability among all reported Mg/S batteries by suppressing polysulfide dissolution. Mechanistic studies show that the battery works via S ⁰ /MgS _x redox processes and that the large voltage hysteresis is mainly due to the Mg anode overpotential.

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Research Organization:: Univ. of Maryland, College Park, MD (United States). Energy Frontier Research Center (EFRC) Nanostructures for Electrical Energy Storage (NEES)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001160

OSTI ID:: 1469863

Alternate ID(s):: OSTI ID: 1393994

Journal Information:: Angewandte Chemie, Vol. 129, Issue 43; Related Information: NEES partners with University of Maryland (lead); University of California, Irvine; University of Florida; Los Alamos National Laboratory; Sandia National Laboratories; Yale University; ISSN 0044-8249

Publisher:: German Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Reversible S0/MgSx Redox Chemistry in a MgTFSI2/MgCl2 /DME Electrolyte for Rechargeable Mg/S Batteries

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Title: Reversible S⁰/MgS_x Redox Chemistry in a MgTFSI₂/MgCl₂ /DME Electrolyte for Rechargeable Mg/S Batteries