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Title: The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion

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Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
DOE Contract Number:  
Resource Type:
Journal Article
Journal Name:
Nature Reviews. Materials
Additional Journal Information:
Journal Volume: 2; Journal Issue: 8; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; Journal ID: ISSN 2058-8437
Nature Publishing Group
Country of Publication:
United States
membrane, carbon capture, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Trickett, Christopher A., Helal, Aasif, Al-Maythalony, Bassem A., Yamani, Zain H., Cordova, Kyle E., and Yaghi, Omar M. The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion. United States: N. p., 2017. Web. doi:10.1038/natrevmats.2017.45.
Trickett, Christopher A., Helal, Aasif, Al-Maythalony, Bassem A., Yamani, Zain H., Cordova, Kyle E., & Yaghi, Omar M. The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion. United States. doi:10.1038/natrevmats.2017.45.
Trickett, Christopher A., Helal, Aasif, Al-Maythalony, Bassem A., Yamani, Zain H., Cordova, Kyle E., and Yaghi, Omar M. Tue . "The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion". United States. doi:10.1038/natrevmats.2017.45.
title = {The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion},
author = {Trickett, Christopher A. and Helal, Aasif and Al-Maythalony, Bassem A. and Yamani, Zain H. and Cordova, Kyle E. and Yaghi, Omar M.},
abstractNote = {},
doi = {10.1038/natrevmats.2017.45},
journal = {Nature Reviews. Materials},
issn = {2058-8437},
number = 8,
volume = 2,
place = {United States},
year = {2017},
month = {7}

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Mixed-Metal Zeolitic Imidazolate Frameworks and their Selective Capture of Wet Carbon Dioxide over Methane
journal, June 2016

Current status and development of membranes for CO2/CH4 separation: A review
journal, January 2013

Synthesis, Structure, Assembly, and Modulation of the CO 2 Adsorption Properties of a Zinc-Adeninate Macrocycle
journal, June 2009

  • An, Jihyun; Fiorella, Richard P.; Geib, Steven J.
  • Journal of the American Chemical Society, Vol. 131, Issue 24
  • DOI: 10.1021/ja901869m

Probing the mechanism of CO 2 capture in diamine-appended metal–organic frameworks using measured and simulated X-ray spectroscopy
journal, January 2015

  • Drisdell, Walter S.; Poloni, Roberta; McDonald, Thomas M.
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 33
  • DOI: 10.1039/C5CP02951A

Metal-organic framework nanosheets as building blocks for molecular sieving membranes
journal, December 2014

High and selective CO2 uptake, H2 storage and methanol sensing on the amine-decorated 12-connected MOF CAU-1
journal, January 2011

  • Si, Xiaoliang; Jiao, Chengli; Li, Fen
  • Energy & Environmental Science, Vol. 4, Issue 11
  • DOI: 10.1039/c1ee01380g

Metal Insertion in a Microporous Metal−Organic Framework Lined with 2,2′-Bipyridine
journal, October 2010

  • Bloch, Eric D.; Britt, David; Lee, Chain
  • Journal of the American Chemical Society, Vol. 132, Issue 41, p. 14382-14384
  • DOI: 10.1021/ja106935d

The iron member of the CPO-27 coordination polymer series: Synthesis, characterization, and intriguing redox properties
journal, July 2012

Post-combustion CO2 capture with the HKUST-1 and MIL-101(Cr) metal–organic frameworks: Adsorption, separation and regeneration investigations
journal, September 2013

Interfacial Design of Mixed Matrix Membranes for Improved Gas Separation Performance
journal, March 2016

  • Wang, Zhenggong; Wang, Dong; Zhang, Shenxiang
  • Advanced Materials, Vol. 28, Issue 17
  • DOI: 10.1002/adma.201504982

Alumina-supported cobalt–adeninate MOF membranes for CO 2 /CH 4 separation
journal, January 2014

  • Xie, Zhenzhen; Li, Tao; Rosi, Nathaniel L.
  • J. Mater. Chem. A, Vol. 2, Issue 5
  • DOI: 10.1039/C3TA14058J

Metal-Organic Frameworks for CO 2 Chemical Transformations
journal, October 2016

Application of a High-Throughput Analyzer in Evaluating Solid Adsorbents for Post-Combustion Carbon Capture via Multicomponent Adsorption of CO 2 , N 2 , and H 2 O
journal, April 2015

  • Mason, Jarad A.; McDonald, Thomas M.; Bae, Tae-Hyun
  • Journal of the American Chemical Society, Vol. 137, Issue 14
  • DOI: 10.1021/jacs.5b00838

Multipoint Interactions Enhanced CO 2 Uptake: A Zeolite-like Zinc–Tetrazole Framework with 24-Nuclear Zinc Cages
journal, November 2012

  • Cui, Ping; Ma, Yu-Guang; Li, Huan-Huan
  • Journal of the American Chemical Society, Vol. 134, Issue 46
  • DOI: 10.1021/ja3063138

A highly permeable and selective amino-functionalized MOF CAU-1 membrane for CO 2 –N 2 separation
journal, January 2014

  • Yin, Huimin; Wang, Jinqu; Xie, Zhong
  • Chem. Commun., Vol. 50, Issue 28
  • DOI: 10.1039/C4CC00068D

Plasmon-Enhanced Photocatalytic CO 2 Conversion within Metal–Organic Frameworks under Visible Light
journal, December 2016

  • Choi, Kyung Min; Kim, Dohyung; Rungtaweevoranit, Bunyarat
  • Journal of the American Chemical Society, Vol. 139, Issue 1
  • DOI: 10.1021/jacs.6b11027

De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities
journal, September 2010

  • Farha, Omar K.; Özgür Yazaydın, A.; Eryazici, Ibrahim
  • Nature Chemistry, Vol. 2, Issue 11, p. 944-948
  • DOI: 10.1038/nchem.834

Adsorption of CO2 and CH4 on a magnesium-based metal organic framework
journal, January 2011

Evaluating metal–organic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption
journal, January 2011

  • Mason, Jarad A.; Sumida, Kenji; Herm, Zoey R.
  • Energy & Environmental Science, Vol. 4, Issue 8, p. 3030-3040
  • DOI: 10.1039/c1ee01720a

New Prototype Isoreticular Metal−Organic Framework Zn 4 O(FMA) 3 for Gas Storage
journal, June 2009

  • Xue, Ming; Liu, Yun; Schaffino, Roxanna M.
  • Inorganic Chemistry, Vol. 48, Issue 11
  • DOI: 10.1021/ic900486r

Remarkably Enhanced Gas Separation by Partial Self-Conversion of a Laminated Membrane to Metal-Organic Frameworks
journal, January 2015

  • Liu, Yi; Pan, Jia Hong; Wang, Nanyi
  • Angewandte Chemie International Edition, Vol. 54, Issue 10
  • DOI: 10.1002/anie.201411550

Cobalt Imidazolate Metal-Organic Frameworks Photosplit CO 2 under Mild Reaction Conditions
journal, December 2013

  • Wang, Sibo; Yao, Wangshu; Lin, Jinliang
  • Angewandte Chemie International Edition, Vol. 53, Issue 4
  • DOI: 10.1002/anie.201309426

A Hafnium-Based Metal–Organic Framework as an Efficient and Multifunctional Catalyst for Facile CO2 Fixation and Regioselective and Enantioretentive Epoxide Activation
journal, October 2014

  • Beyzavi, M. Hassan; Klet, Rachel C.; Tussupbayev, Samat
  • Journal of the American Chemical Society, Vol. 136, Issue 45, p. 15861-15864
  • DOI: 10.1021/ja508626n

Metal–Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water
journal, June 2014

  • Fracaroli, Alejandro M.; Furukawa, Hiroyasu; Suzuki, Mitsuharu
  • Journal of the American Chemical Society, Vol. 136, Issue 25, p. 8863-8866
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MOF Crystal Chemistry Paving the Way to Gas Storage Needs: Aluminum-Based soc -MOF for CH 4 , O 2 , and CO 2 Storage
journal, October 2015

  • Alezi, Dalal; Belmabkhout, Youssef; Suyetin, Mikhail
  • Journal of the American Chemical Society, Vol. 137, Issue 41
  • DOI: 10.1021/jacs.5b07053

Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature
journal, December 2005

  • Millward, Andrew R.; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 127, Issue 51, p. 17998-17999
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Metal–Organic Frameworks as a Potential Platform for Selective Treatment of Gaseous Sulfur Compounds
journal, October 2016

  • Vellingiri, Kowsalya; Deep, Akash; Kim, Ki-Hyun
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 44
  • DOI: 10.1021/acsami.6b10482

Cooperative insertion of CO2 in diamine-appended metal-organic frameworks
journal, March 2015

  • McDonald, Thomas M.; Mason, Jarad A.; Kong, Xueqian
  • Nature, Vol. 519, Issue 7543
  • DOI: 10.1038/nature14327

Polymer–Metal–Organic Frameworks (polyMOFs) as Water Tolerant Materials for Selective Carbon Dioxide Separations
journal, January 2016

  • Zhang, Zhenjie; Nguyen, Ha Thi Hoang; Miller, Stephen A.
  • Journal of the American Chemical Society, Vol. 138, Issue 3
  • DOI: 10.1021/jacs.5b11034

A Triazole-Containing Metal–Organic Framework as a Highly Effective and Substrate Size-Dependent Catalyst for CO 2 Conversion
journal, February 2016

  • Li, Pei-Zhou; Wang, Xiao-Jun; Liu, Jia
  • Journal of the American Chemical Society, Vol. 138, Issue 7
  • DOI: 10.1021/jacs.5b13335

Metal–organic framework membranes: from synthesis to separation application
journal, January 2014

  • Qiu, Shilun; Xue, Ming; Zhu, Guangshan
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS00159A

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

  • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
  • Science, Vol. 341, Issue 6149, p. 1230444-1230444
  • DOI: 10.1126/science.1230444

Comparative Study of Hydrogen Sulfide Adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) Metal−Organic Frameworks at Room Temperature
journal, July 2009

  • Hamon, Lomig; Serre, Christian; Devic, Thomas
  • Journal of the American Chemical Society, Vol. 131, Issue 25
  • DOI: 10.1021/ja901587t

Application of metal–organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide
journal, January 2009

  • Dietzel, Pascal D. C.; Besikiotis, Vasileios; Blom, Richard
  • Journal of Materials Chemistry, Vol. 19, Issue 39, p. 7362-7370
  • DOI: 10.1039/b911242a