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Title: Reaction mechanism of the selective reduction of CO 2 to CO by a tetraaza [Co II N 4 H] 2+ complex in the presence of protons

Abstract

The tetraaza [Co II N 4 H] 2+ complex ( 1 ) is remarkable for its ability to selectively reduce CO 2 to CO with 45% Faradaic efficiency and a CO to H 2 ratio of 3 : 2.

Authors:
 [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [5]
  1. Joint Center for Artificial Photosynthesis, Lawrence Berkeley National Laboratory, Berkeley, USA
  2. Department of Physics, Scientific Computing, Materials Science and Engineering, High Performance Material Institute, Condensed Matter Theory-National High Magnetic Field Laboratory, Florida State University, Tallahassee, USA, Department of Chemical & Biomedical Engineering, Florida A&M University – Florida State University, Joint College of Engineering, Tallahassee
  3. Joint Center for Artificial Photosynthesis, Lawrence Berkeley National Laboratory, Berkeley, USA, Department of Chemical and Biomolecular Engineering, University of California, Berkeley
  4. Joint Center for Artificial Photosynthesis, Lawrence Berkeley National Laboratory, Berkeley, USA, Department of Physics, Scientific Computing, Materials Science and Engineering, High Performance Material Institute, Condensed Matter Theory-National High Magnetic Field Laboratory, Florida State University, Tallahassee
  5. Joint Center for Artificial Photosynthesis, Lawrence Berkeley National Laboratory, Berkeley, USA, Department of Chemistry, University of California, Berkeley
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1469422
Grant/Contract Number:  
SC00004993
Resource Type:
Journal Article: Publisher's Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics Journal Volume: 20 Journal Issue: 37; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Garza, Alejandro J., Pakhira, Srimanta, Bell, Alexis T., Mendoza-Cortes, Jose L., and Head-Gordon, Martin. Reaction mechanism of the selective reduction of CO 2 to CO by a tetraaza [Co II N 4 H] 2+ complex in the presence of protons. United Kingdom: N. p., 2018. Web. doi:10.1039/C8CP01963K.
Garza, Alejandro J., Pakhira, Srimanta, Bell, Alexis T., Mendoza-Cortes, Jose L., & Head-Gordon, Martin. Reaction mechanism of the selective reduction of CO 2 to CO by a tetraaza [Co II N 4 H] 2+ complex in the presence of protons. United Kingdom. doi:10.1039/C8CP01963K.
Garza, Alejandro J., Pakhira, Srimanta, Bell, Alexis T., Mendoza-Cortes, Jose L., and Head-Gordon, Martin. Mon . "Reaction mechanism of the selective reduction of CO 2 to CO by a tetraaza [Co II N 4 H] 2+ complex in the presence of protons". United Kingdom. doi:10.1039/C8CP01963K.
@article{osti_1469422,
title = {Reaction mechanism of the selective reduction of CO 2 to CO by a tetraaza [Co II N 4 H] 2+ complex in the presence of protons},
author = {Garza, Alejandro J. and Pakhira, Srimanta and Bell, Alexis T. and Mendoza-Cortes, Jose L. and Head-Gordon, Martin},
abstractNote = {The tetraaza [Co II N 4 H] 2+ complex ( 1 ) is remarkable for its ability to selectively reduce CO 2 to CO with 45% Faradaic efficiency and a CO to H 2 ratio of 3 : 2.},
doi = {10.1039/C8CP01963K},
journal = {Physical Chemistry Chemical Physics},
number = 37,
volume = 20,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on September 3, 2019
Publisher's Accepted Manuscript

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Works referenced in this record:

Macrocyclic [N42-] Coordinated Nickel Complexes as Catalysts for the Formation of Oxalate by Electrochemical Reduction of Carbon Dioxide
journal, November 2000

  • Rudolph, Manfred; Dautz, Sylvana; Jäger, Ernst-Gottfried
  • Journal of the American Chemical Society, Vol. 122, Issue 44, p. 10821-10830
  • DOI: 10.1021/ja001254n