The Effect of Membrane Properties on Performance and Transports inside Polymer Electrolyte Membrane Fuel Cells
Abstract
The primary focus of this work is evaluation, modeling, and comparison of fuel cell properties for a sulfonated aromatic hydrocarbon polymer membrane under fuel cell operations against the standard commercial Nafion membrane. Membrane characterization of transport properties were reported. The fuel cell performance, current distribution mapping, and water balance measurements of both membrane were also examined at different humidity conditions. The studies show that at high RH, the hydrocarbon membrane gives better performance with less water flooding when compared with standard Nafion. However at low RH, where the membrane needs more hydration and conducting of the proton, the standard Nafion membrane shows higher performance than hydrocarbon membrane. Local distributions of current density, water content and liquid water in hydrocarbon membranes were simulated and compared with a Nafion 212 membrane. Both experimental data and model predictions show that the hydrocarbon membrane gives more uniform current distributions than that of the Nafion membrane. The computational model can predict water transport across the membrane and can be used to observe flooding in PEMFC.
- Authors:
- Publication Date:
- Research Org.:
- Giner, Inc., Newton, MA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Fuel Cell Technologies Office; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office (HFTO)
- OSTI Identifier:
- 1469413
- Alternate Identifier(s):
- OSTI ID: 1545797
- Grant/Contract Number:
- EE0000471
- Resource Type:
- Journal Article: Published Article
- Journal Name:
- Journal of the Electrochemical Society
- Additional Journal Information:
- Journal Name: Journal of the Electrochemical Society Journal Volume: 165 Journal Issue: 11; Journal ID: ISSN 0013-4651
- Publisher:
- The Electrochemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Current Density Distribution; Membrane characterization; water balance measurement
Citation Formats
Shimpalee, S., Lilavivat, V., Xu, H., Rowlett, J. R., Mittelsteadt, C., and Van Zee, J. W. The Effect of Membrane Properties on Performance and Transports inside Polymer Electrolyte Membrane Fuel Cells. United States: N. p., 2018.
Web. doi:10.1149/2.0081813jes.
Shimpalee, S., Lilavivat, V., Xu, H., Rowlett, J. R., Mittelsteadt, C., & Van Zee, J. W. The Effect of Membrane Properties on Performance and Transports inside Polymer Electrolyte Membrane Fuel Cells. United States. https://doi.org/10.1149/2.0081813jes
Shimpalee, S., Lilavivat, V., Xu, H., Rowlett, J. R., Mittelsteadt, C., and Van Zee, J. W. 2018.
"The Effect of Membrane Properties on Performance and Transports inside Polymer Electrolyte Membrane Fuel Cells". United States. https://doi.org/10.1149/2.0081813jes.
@article{osti_1469413,
title = {The Effect of Membrane Properties on Performance and Transports inside Polymer Electrolyte Membrane Fuel Cells},
author = {Shimpalee, S. and Lilavivat, V. and Xu, H. and Rowlett, J. R. and Mittelsteadt, C. and Van Zee, J. W.},
abstractNote = {The primary focus of this work is evaluation, modeling, and comparison of fuel cell properties for a sulfonated aromatic hydrocarbon polymer membrane under fuel cell operations against the standard commercial Nafion membrane. Membrane characterization of transport properties were reported. The fuel cell performance, current distribution mapping, and water balance measurements of both membrane were also examined at different humidity conditions. The studies show that at high RH, the hydrocarbon membrane gives better performance with less water flooding when compared with standard Nafion. However at low RH, where the membrane needs more hydration and conducting of the proton, the standard Nafion membrane shows higher performance than hydrocarbon membrane. Local distributions of current density, water content and liquid water in hydrocarbon membranes were simulated and compared with a Nafion 212 membrane. Both experimental data and model predictions show that the hydrocarbon membrane gives more uniform current distributions than that of the Nafion membrane. The computational model can predict water transport across the membrane and can be used to observe flooding in PEMFC.},
doi = {10.1149/2.0081813jes},
url = {https://www.osti.gov/biblio/1469413},
journal = {Journal of the Electrochemical Society},
issn = {0013-4651},
number = 11,
volume = 165,
place = {United States},
year = {Tue Sep 11 00:00:00 EDT 2018},
month = {Tue Sep 11 00:00:00 EDT 2018}
}
Web of Science
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