Photoelectron spectroscopy of anthracene and fluoranthene radical anions

Kregel, Steven J.; Thurston, Glen K.; Garand, Etienne

doi:10.1063/1.5036757

Title: Photoelectron spectroscopy of anthracene and fluoranthene radical anions

Journal Article · Thu Jun 21 00:00:00 EDT 2018 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.5036757· OSTI ID:1469198

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Univ. of Wisconsin, Madison, WI (United States). Dept. of Chemistry

Here, we report the slow electron velocity map imaging spectroscopy of cryogenically cooled anthracene and fluoranthene radical anions, two similarly sized polycyclic aromatic hydrocarbon molecules. The results allow us to examine the lowest energy singlet and triplet states in the neutral molecules on equal footing from the anionic ground state. The analysis of the experimental spectra is aided by harmonic calculations and Franck-Condon simulations, which generally show good agreement with experimental values and spectra. The electron affinity of fluoranthene is measured to be 0.757(2) eV, which is larger than that of anthracene at 0.532(3) eV. The lowest energy triplet state in anthracene is observed at 1.872(3) eV above the singlet ground state, while that of fluoranthene is observed at 2.321(2) eV above its singlet ground state. Comparisons of experimental and calculated spectra show that in addition to the Franck-Condon active modes, there is a clear presence of vibrational modes that gain intensity via vibronic coupling in both the singlet and triplet states in both molecules. In addition, the triplet state generally exhibits increased vibronic coupling compared to the singlet state, with the fluoranthene triplet state exhibiting evidence of distortion from C_2v symmetry.

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Research Organization:: Univ. of Wisconsin, Madison, WI (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: SC0010326; CHE-0840494

OSTI ID:: 1469198

Alternate ID(s):: OSTI ID: 1456264

Journal Information:: Journal of Chemical Physics, Vol. 148, Issue 23; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 11 works

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High-resolution photoelectron imaging and resonant photoelectron spectroscopy via noncovalently bound excited states of cryogenically cooled anions Zhu, Guo-Zhu; Wang, Lai-Sheng Chemical Science, Vol. 10, Issue 41 https://doi.org/10.1039/c9sc03861b	journal	January 2019
Vibrationally resolved photoelectron spectroscopy of oligothiophene radical anions Thurston, Glen K.; Sagan, Cole R.; Garand, Etienne The Journal of Chemical Physics, Vol. 151, Issue 16 https://doi.org/10.1063/1.5124925	journal	October 2019

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