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Title: Biexcitons in monolayer transition metal dichalcogenides tuned by magnetic fields

Abstract

We present time-integrated four-wave mixing measurements on monolayer MoSe 2 in magnetic fields up to 25 T. The experimental data together with time-dependent density function theory calculations provide interesting insights into the biexciton formation and dynamics. In the presence of magnetic fields the coherence at negative and positive time delays is dominated by intervalley biexcitons. We demonstrate that magnetic fields can serve as a control to enhance the biexciton formation and help search for more exotic states of matter, including the creation of multiple exciton complexes and excitonic condensates.

Authors:
; ; ; ORCiD logo; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Univ. of South Florida, Tampa, FL (United States)
Sponsoring Org.:
USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
OSTI Identifier:
1469033
Alternate Identifier(s):
OSTI ID: 1511452
Grant/Contract Number:  
SC0012635; DOE-DE-FG02-07ER46345; FG02-07ER46345
Resource Type:
Journal Article: Published Article
Journal Name:
Nature Communications
Additional Journal Information:
Journal Name: Nature Communications Journal Volume: 9 Journal Issue: 1; Journal ID: ISSN 2041-1723
Publisher:
Nature Publishing Group
Country of Publication:
United Kingdom
Language:
English
Subject:
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS

Citation Formats

Stevens, Christopher. E., Paul, Jagannath, Cox, Timothy, Sahoo, Prasana K., Gutiérrez, Humberto R., Turkowski, Volodymyr, Semenov, Dimitry, McGill, Steven A., Kapetanakis, Myron D., Perakis, Ilias E., Hilton, David J., and Karaiskaj, Denis. Biexcitons in monolayer transition metal dichalcogenides tuned by magnetic fields. United Kingdom: N. p., 2018. Web. doi:10.1038/s41467-018-05643-1.
Stevens, Christopher. E., Paul, Jagannath, Cox, Timothy, Sahoo, Prasana K., Gutiérrez, Humberto R., Turkowski, Volodymyr, Semenov, Dimitry, McGill, Steven A., Kapetanakis, Myron D., Perakis, Ilias E., Hilton, David J., & Karaiskaj, Denis. Biexcitons in monolayer transition metal dichalcogenides tuned by magnetic fields. United Kingdom. doi:10.1038/s41467-018-05643-1.
Stevens, Christopher. E., Paul, Jagannath, Cox, Timothy, Sahoo, Prasana K., Gutiérrez, Humberto R., Turkowski, Volodymyr, Semenov, Dimitry, McGill, Steven A., Kapetanakis, Myron D., Perakis, Ilias E., Hilton, David J., and Karaiskaj, Denis. Thu . "Biexcitons in monolayer transition metal dichalcogenides tuned by magnetic fields". United Kingdom. doi:10.1038/s41467-018-05643-1.
@article{osti_1469033,
title = {Biexcitons in monolayer transition metal dichalcogenides tuned by magnetic fields},
author = {Stevens, Christopher. E. and Paul, Jagannath and Cox, Timothy and Sahoo, Prasana K. and Gutiérrez, Humberto R. and Turkowski, Volodymyr and Semenov, Dimitry and McGill, Steven A. and Kapetanakis, Myron D. and Perakis, Ilias E. and Hilton, David J. and Karaiskaj, Denis},
abstractNote = {We present time-integrated four-wave mixing measurements on monolayer MoSe2 in magnetic fields up to 25 T. The experimental data together with time-dependent density function theory calculations provide interesting insights into the biexciton formation and dynamics. In the presence of magnetic fields the coherence at negative and positive time delays is dominated by intervalley biexcitons. We demonstrate that magnetic fields can serve as a control to enhance the biexciton formation and help search for more exotic states of matter, including the creation of multiple exciton complexes and excitonic condensates.},
doi = {10.1038/s41467-018-05643-1},
journal = {Nature Communications},
issn = {2041-1723},
number = 1,
volume = 9,
place = {United Kingdom},
year = {2018},
month = {9}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record at 10.1038/s41467-018-05643-1

Citation Metrics:
Cited by: 5 works
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Works referenced in this record:

Continuous-wave biexciton lasing at room temperature using solution-processed quantum wells
journal, October 2014

  • Grim, Joel Q.; Christodoulou, Sotirios; Di Stasio, Francesco
  • Nature Nanotechnology, Vol. 9, Issue 11
  • DOI: 10.1038/nnano.2014.213

One-pot growth of two-dimensional lateral heterostructures via sequential edge-epitaxy
journal, January 2018

  • Sahoo, Prasana K.; Memaran, Shahriar; Xin, Yan
  • Nature, Vol. 553, Issue 7686
  • DOI: 10.1038/nature25155

Many-body and correlation effects in semiconductors
journal, May 2001

  • Chemla, D. S.; Shah, Jagdeep
  • Nature, Vol. 411, Issue 6837
  • DOI: 10.1038/35079000

Breaking of Valley Degeneracy by Magnetic Field in Monolayer MoSe 2
journal, January 2015


Valley dynamics probed through charged and neutral exciton emission in monolayer WSe 2
journal, August 2014


Spin and pseudospins in layered transition metal dichalcogenides
journal, April 2014

  • Xu, Xiaodong; Yao, Wang; Xiao, Di
  • Nature Physics, Vol. 10, Issue 5
  • DOI: 10.1038/nphys2942

Observation of Excitonic Rydberg States in Monolayer MoS 2 and WS 2 by Photoluminescence Excitation Spectroscopy
journal, April 2015

  • Hill, Heather M.; Rigosi, Albert F.; Roquelet, Cyrielle
  • Nano Letters, Vol. 15, Issue 5
  • DOI: 10.1021/nl504868p

Continuously tunable optical multidimensional Fourier-transform spectrometer
journal, February 2013

  • Dey, P.; Paul, J.; Bylsma, J.
  • Review of Scientific Instruments, Vol. 84, Issue 2
  • DOI: 10.1063/1.4792378

Quasi-two-dimensional excitons in finite magnetic fields
journal, May 2002


An All-Optical Quantum Gate in a Semiconductor Quantum Dot
journal, August 2003


Many-body correlations and excitonic effects in semiconductor spectroscopy
journal, January 2006


Intervalley biexcitons and many-body effects in monolayer MoS 2
journal, September 2015


Atomically Thin MoS2 A New Direct-Gap Semiconductor
journal, September 2010


Strong Quantum Coherence between Fermi Liquid Mahan Excitons
journal, April 2016


The valley Hall effect in MoS2 transistors
journal, June 2014


Monolayer excitonic laser
journal, October 2015


Time-dependent density-functional theory of exciton-exciton correlations in the nonlinear optical response
journal, February 2014


Coherent measurements of high-order electronic correlations in quantum wells
journal, August 2010


Signatures of exciton condensation in a transition metal dichalcogenide
journal, December 2017


Two-Quantum 2D FT Electronic Spectroscopy of Biexcitons in GaAs Quantum Wells
journal, May 2009


Polarization dependence of semiconductor exciton and biexciton contributions to phase-resolved optical two-dimensional Fourier-transform spectra
journal, April 2009


Time-dependent density-functional theory for ultrafast interband excitations
journal, February 2008


Magnetooptics of Exciton Rydberg States in a Monolayer Semiconductor
journal, February 2018


Time-dependent density-matrix functional theory for trion excitations: Application to monolayer MoS 2 and other transition-metal dichalcogenides
journal, August 2014

  • Ramirez-Torres, Alfredo; Turkowski, Volodymyr; Rahman, Talat S.
  • Physical Review B, Vol. 90, Issue 8
  • DOI: 10.1103/PhysRevB.90.085419

Vertical field-effect transistor based on graphene–WS2 heterostructures for flexible and transparent electronics
journal, December 2012

  • Georgiou, Thanasis; Jalil, Rashid; Belle, Branson D.
  • Nature Nanotechnology, Vol. 8, Issue 2
  • DOI: 10.1038/nnano.2012.224

Biexciton lasing in CuCl quantum dots
journal, January 1993

  • Masumoto, Yasuaki; Kawamura, Tomohiro; Era, Koh
  • Applied Physics Letters, Vol. 62, Issue 3
  • DOI: 10.1063/1.109000

Optical generation of excitonic valley coherence in monolayer WSe2
journal, August 2013

  • Jones, Aaron M.; Yu, Hongyi; Ghimire, Nirmal J.
  • Nature Nanotechnology, Vol. 8, Issue 9
  • DOI: 10.1038/nnano.2013.151

Tightly Bound Excitons in Monolayer WSe 2
journal, July 2014


Strong Light-Matter Interactions in Heterostructures of Atomically Thin Films
journal, May 2013


Electrical tuning of valley magnetic moment through symmetry control in bilayer MoS2
journal, January 2013

  • Wu, Sanfeng; Ross, Jason S.; Liu, Gui-Bin
  • Nature Physics, Vol. 9, Issue 3
  • DOI: 10.1038/nphys2524

Coulomb-interaction induced coupling of Landau levels in intrinsic and modulation-doped quantum wells
journal, June 2017


Atomically thin optical lenses and gratings
journal, March 2016

  • Yang, Jiong; Wang, Zhu; Wang, Fan
  • Light: Science & Applications, Vol. 5, Issue 3
  • DOI: 10.1038/lsa.2016.46

χ ( 3 ) formalism in optically excited semiconductors and its applications in four-wave-mixing spectroscopy
journal, December 1994


Bose–Einstein condensation of exciton polaritons
journal, September 2006

  • Kasprzak, J.; Richard, M.; Kundermann, S.
  • Nature, Vol. 443, Issue 7110
  • DOI: 10.1038/nature05131

Semiconductor quantum light sources
journal, April 2007


Effect of magnetoexciton correlations on the coherent emission of semiconductors
journal, August 1999


Time-dependent density-functional approach for exciton binding energies
journal, June 2009


Strong light–matter coupling in two-dimensional atomic crystals
journal, December 2014


Tightly bound trions in monolayer MoS2
journal, December 2012

  • Mak, Kin Fai; He, Keliang; Lee, Changgu
  • Nature Materials, Vol. 12, Issue 3
  • DOI: 10.1038/nmat3505

Coherence of Four-Particle Correlations in Semiconductors
journal, December 1998


Magneto-optics in transition metal diselenide monolayers
journal, June 2015


Ultrasensitive photodetectors based on monolayer MoS2
journal, June 2013

  • Lopez-Sanchez, Oriol; Lembke, Dominik; Kayci, Metin
  • Nature Nanotechnology, Vol. 8, Issue 7
  • DOI: 10.1038/nnano.2013.100

Biexciton formation and exciton coherent coupling in layered GaSe
journal, April 2015

  • Dey, P.; Paul, J.; Moody, G.
  • The Journal of Chemical Physics, Vol. 142, Issue 21
  • DOI: 10.1063/1.4917169

Observation of biexcitons in monolayer WSe2
journal, May 2015

  • You, Yumeng; Zhang, Xiao-Xiao; Berkelbach, Timothy C.
  • Nature Physics, Vol. 11, Issue 6
  • DOI: 10.1038/nphys3324

Valley Zeeman effect in elementary optical excitations of monolayer WSe2
journal, January 2015

  • Srivastava, Ajit; Sidler, Meinrad; Allain, Adrien V.
  • Nature Physics, Vol. 11, Issue 2
  • DOI: 10.1038/nphys3203

Strongly enhanced photoluminescence in nanostructured monolayer MoS 2 by chemical vapor deposition
journal, February 2016


Exciton Binding Energy and Nonhydrogenic Rydberg Series in Monolayer WS 2
journal, August 2014


Magnetic control of valley pseudospin in monolayer WSe2
journal, January 2015

  • Aivazian, G.; Gong, Zhirui; Jones, Aaron M.
  • Nature Physics, Vol. 11, Issue 2
  • DOI: 10.1038/nphys3201

Orientation of luminescent excitons in layered nanomaterials
journal, March 2013

  • Schuller, Jon A.; Karaveli, Sinan; Schiros, Theanne
  • Nature Nanotechnology, Vol. 8, Issue 4
  • DOI: 10.1038/nnano.2013.20