Mn III -Peroxo adduct supported by a new tetradentate ligand shows acid-sensitive aldehyde deformylation reactivity

Denler, Melissa C.; Wijeratne, Gayan B.; Rice, Derek B.; Colmer, Hannah E.; Day, Victor W.; Jackson, Timothy A.

doi:10.1039/C8DT02300J

Title: Mn ^III -Peroxo adduct supported by a new tetradentate ligand shows acid-sensitive aldehyde deformylation reactivity

Journal Article · Mon Jan 01 00:00:00 EST 2018 · Dalton Transactions

DOI:https://doi.org/10.1039/C8DT02300J· OSTI ID:1468666

Denler, Melissa C. ^[1];

^[1]; Rice, Derek B. ^[1]; Colmer, Hannah E. ^[1]; Day, Victor W. ^[1];

^[1]

The University of Kansas, Department of Chemistry and Center for Environmentally Beneficial Catalysis, Lawrence, USA

The new tetradentate L ⁷ BQ ligand (L ⁷ BQ = 1,4-di(quinoline-8-yl)-1,4-diazepane) has been synthesized and shown to support Mn ^II and Mn ^III -peroxo complexes.

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1468666

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Vol. 47 Journal Issue: 38; ISSN 1477-9226

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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References (76)

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Structure and reactivity of a mononuclear non-haem iron(III)–peroxo complex Cho, Jaeheung; Jeon, Sujin; Wilson, Samuel A. Nature, Vol. 478, Issue 7370 https://doi.org/10.1038/nature10535	journal	October 2011
Catalytic Reaction Mechanism of Oxalate Oxidase (Germin). A Hybrid DFT Study Borowski, Tomasz; Bassan, Arianna; Richards, Nigel G. J. Journal of Chemical Theory and Computation, Vol. 1, Issue 4 https://doi.org/10.1021/ct050041r	journal	April 2005
Diamagnetic Corrections and Pascal's Constants Bain, Gordon A.; Berry, John F. Journal of Chemical Education, Vol. 85, Issue 4 https://doi.org/10.1021/ed085p532	journal	April 2008
C−H Activation by a Mononuclear Manganese(III) Hydroxide Complex: Synthesis and Characterization of a Manganese-Lipoxygenase Mimic? Goldsmith, Christian R.; Cole, Adam P.; Stack, T. Daniel P. Journal of the American Chemical Society, Vol. 127, Issue 27 https://doi.org/10.1021/ja039283w	journal	July 2005
Correlation Between Structural, Spectroscopic, and Reactivity Properties Within a Series of Structurally Analogous Metastable Manganese(III)–Alkylperoxo Complexes Coggins, Michael K.; Martin-Diaconescu, Vlad; DeBeer, Serena Journal of the American Chemical Society, Vol. 135, Issue 11 https://doi.org/10.1021/ja308915x	journal	March 2013
Second-Sphere Tuning of the Metal ion Reduction Potentials in iron and Manganese Superoxide Dismutases Grove, Laurie E.; Brunold, Thomas C. Comments on Inorganic Chemistry, Vol. 29, Issue 5-6 https://doi.org/10.1080/02603590802429529	journal	December 2008
Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions Marenich, Aleksandr V.; Cramer, Christopher J.; Truhlar, Donald G. The Journal of Physical Chemistry B, Vol. 113, Issue 18, p. 6378-6396 https://doi.org/10.1021/jp810292n	journal	May 2009
Bioinspired oxidations of aliphatic C–H groups with H2O2 in the presence of manganese complexes Talsi, Evgenii P.; Ottenbacher, Roman V.; Bryliakov, Konstantin P. Journal of Organometallic Chemistry, Vol. 793 https://doi.org/10.1016/j.jorganchem.2014.12.014	journal	September 2015
Hydrogen bonding interaction between imidazolyl N–H group and peroxide: Stabilization of Mn(III)-peroxo complex TpiPr2Mn(η2-O2)(imMeH) (imMeH=2-methylimidazole) Singh, Udai P.; Sharma, Asish K.; Hikichi, Shiro Inorganica Chimica Acta, Vol. 359, Issue 13 https://doi.org/10.1016/j.ica.2006.06.033	journal	October 2006
Time-dependent density functional theory for radicals Hirata, So; Head-Gordon, Martin Chemical Physics Letters, Vol. 302, Issue 5-6 https://doi.org/10.1016/S0009-2614(99)00137-2	journal	March 1999
Reaction landscape of a pentadentate N5-ligated MnII complex with O2˙− and H2O2 includes conversion of a peroxomanganese(iii) adduct to a bis(μ-oxo)dimanganese(iii,iv) species Leto, Domenick F.; Chattopadhyay, Swarup; Day, Victor W. Dalton Transactions, Vol. 42, Issue 36 https://doi.org/10.1039/c3dt51277k	journal	January 2013
Steric and Electronic Influences on the Structures of Peroxomanganese(III) Complexes Supported by Tetradentate Ligands Geiger, Robert A.; Wijeratne, Gayan B.; Day, Victor W. European Journal of Inorganic Chemistry, Vol. 2012, Issue 10 https://doi.org/10.1002/ejic.201101391	journal	February 2012
Resonance Raman evidence for the interconversion between an [FeIII–η1-OOH] 2+ and [FeIII–η2-O2]+ species and mechanistic implications thereof Ho, Raymond Y. N.; Jr., Lawrence Que; Roelfes, Gerard Chemical Communications, Issue 21 https://doi.org/10.1039/a905535e	journal	January 1999
Mononuclear Manganese-Peroxo and Bis(μ-oxo)dimanganese Complexes Bearing a Common N-Methylated Macrocyclic Ligand Kang, Hyeona; Cho, Jaeheung; Cho, Kyung-Bin Chemistry - A European Journal, Vol. 19, Issue 42 https://doi.org/10.1002/chem.201301641	journal	September 2013
Geometric and electronic structure of a peroxomanganese( iii ) complex supported by a scorpionate ligand Colmer, Hannah E.; Geiger, Robert A.; Leto, Domenick F. Dalton Trans., Vol. 43, Issue 48 https://doi.org/10.1039/C4DT02483D	journal	January 2014
Nucleophilic Reactivity of a Metal-Bound Superoxide Ligand Ure, Andrew; McDonald, Aidan Synlett, Vol. 26, Issue 15 https://doi.org/10.1055/s-0034-1381023	journal	July 2015
Formation, Characterization, and O–O Bond Activation of a Peroxomanganese(III) Complex Supported by a Cross-Clamped Cyclam Ligand Colmer, Hannah E.; Howcroft, Anthony W.; Jackson, Timothy A. Inorganic Chemistry, Vol. 55, Issue 5 https://doi.org/10.1021/acs.inorgchem.5b02398	journal	February 2016
Metallation and mismetallation of iron and manganese proteins in vitro and in vivo: the class I ribonucleotide reductases as a case study Cotruvo, Jr, Joseph A.; Stubbe, JoAnne Metallomics, Vol. 4, Issue 10 https://doi.org/10.1039/c2mt20142a	journal	January 2012
Electrochemical formation of MnIII-peroxo complexes supported by pentadentate amino pyridine and imidazole ligands El Ghachtouli, Sanae; Vincent Ching, H. Y.; Lassalle-Kaiser, Benedikt Chemical Communications, Vol. 49, Issue 50 https://doi.org/10.1039/c3cc41300d	journal	January 2013
Water-soluble hexadentate Schiff-base ligands as sequestrating agents for iron(III) and gallium(III) Evans, Dennis F.; Jakubovic, David A. Journal of the Chemical Society, Dalton Transactions, Issue 12 https://doi.org/10.1039/dt9880002927	journal	January 1988
THE HOMOGENEOUS BASE-CATALYZED DECOMPOSITION OF HYDROGEN PEROXIDE ¹ Duke, Frederick R.; Haas, Trice W. The Journal of Physical Chemistry, Vol. 65, Issue 2 https://doi.org/10.1021/j100820a028	journal	February 1961
Reactivity of Mn^II with Superoxide. Evidence for a [Mn^IIIOO]⁺ Unit by Low-Temperature Spectroscopies Groni, Sihem; Blain, Guillaume; Guillot, Régis Inorganic Chemistry, Vol. 46, Issue 6 https://doi.org/10.1021/ic062063+	journal	February 2007
Theoretical x-ray absorption fine structure standards Rehr, J. J.; Mustre de Leon, J.; Zabinsky, S. I. Journal of the American Chemical Society, Vol. 113, Issue 14 https://doi.org/10.1021/ja00014a001	journal	July 1991
Geometric and Electronic Structures of Peroxomanganese(III) Complexes Supported by Pentadentate Amino-Pyridine and -Imidazole Ligands Geiger, Robert A.; Leto, Domenick F.; Chattopadhyay, Swarup Inorganic Chemistry, Vol. 50, Issue 20 https://doi.org/10.1021/ic201168j	journal	October 2011
A mononuclear manganese( iii )–hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions Sankaralingam, Muniyandi; Lee, Yong-Min; Jeon, So Hyun Chemical Communications, Vol. 54, Issue 10 https://doi.org/10.1039/C7CC09492B	journal	January 2018
Accurate Coulomb-fitting basis sets for H to Rn Weigend, Florian Physical Chemistry Chemical Physics, Vol. 8, Issue 9 https://doi.org/10.1039/b515623h	journal	January 2006
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu Grimme, Stefan; Antony, Jens; Ehrlich, Stephan The Journal of Chemical Physics, Vol. 132, Issue 15 https://doi.org/10.1063/1.3382344	journal	April 2010
Superoxide dismutases: active sites that save, but a protein that kills Miller, Anne-Frances Current Opinion in Chemical Biology, Vol. 8, Issue 2 https://doi.org/10.1016/j.cbpa.2004.02.011	journal	April 2004
The application of manganese complexes of ligands derived from 1,4,7-triazacyclononane in oxidative catalysis Sibbons, Kevin F.; Shastri, Kirtida; Watkinson, Michael Dalton Trans., Issue 5 https://doi.org/10.1039/B511331H	journal	January 2006
Characterization of Metastable Intermediates Formed in the Reaction between a Mn(II) Complex and Dioxygen, Including a Crystallographic Structure of a Binuclear Mn(III)–Peroxo Species Coggins, Michael K.; Sun, Xianru; Kwak, Yeonju Journal of the American Chemical Society, Vol. 135, Issue 15 https://doi.org/10.1021/ja311166u	journal	April 2013
Enantioselective Epoxidations of Olefins with Various Oxidants on Bioinspired Mn Complexes: Evidence for Different Mechanisms and Chiral Additive Amplification Ottenbacher, Roman V.; Samsonenko, Denis G.; Talsi, Evgenii P. ACS Catalysis, Vol. 6, Issue 2 https://doi.org/10.1021/acscatal.5b02299	journal	January 2016
Structural and Spectroscopic Characterization of Metastable Thiolate-Ligated Manganese(III)–Alkylperoxo Species Coggins, Michael K.; Kovacs, Julie A. Journal of the American Chemical Society, Vol. 133, Issue 32 https://doi.org/10.1021/ja205520u	journal	August 2011
A Series of Peroxomanganese(III) Complexes Supported by Tetradentate Aminopyridyl Ligands: Detailed Spectroscopic and Computational Studies Geiger, Robert A.; Chattopadhyay, Swarup; Day, Victor W. Journal of the American Chemical Society, Vol. 132, Issue 8 https://doi.org/10.1021/ja910235g	journal	March 2010
Effect of the damping function in dispersion corrected density functional theory Grimme, Stefan; Ehrlich, Stephan; Goerigk, Lars Journal of Computational Chemistry, Vol. 32, Issue 7 https://doi.org/10.1002/jcc.21759	journal	March 2011
Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy Weigend, Florian; Ahlrichs, Reinhart Physical Chemistry Chemical Physics, Vol. 7, Issue 18, p. 3297-3305 https://doi.org/10.1039/b508541a	journal	January 2005
Density‐functional thermochemistry. III. The role of exact exchange Becke, Axel D. The Journal of Chemical Physics, Vol. 98, Issue 7, p. 5648-5652 https://doi.org/10.1063/1.464913	journal	April 1993
Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions Ruiz-Castillo, Paula; Buchwald, Stephen L. Chemical Reviews, Vol. 116, Issue 19 https://doi.org/10.1021/acs.chemrev.6b00512	journal	September 2016
O–H bond oxidation by a monomeric Mn ^III –OMe complex Wijeratne, Gayan B.; Day, Victor W.; Jackson, Timothy A. Dalton Transactions, Vol. 44, Issue 7 https://doi.org/10.1039/C4DT03546A	journal	January 2015
Electron Paramagnetic Resonance Detection of Intermediates in the Enzymatic Cycle of an Extradiol Dioxygenase Gunderson, William A.; Zatsman, Anna I.; Emerson, Joseph P. Journal of the American Chemical Society, Vol. 130, Issue 44 https://doi.org/10.1021/ja8052255	journal	November 2008
Saturation Kinetics in Phenolic O–H Bond Oxidation by a Mononuclear Mn(III)–OH Complex Derived from Dioxygen Wijeratne, Gayan B.; Corzine, Briana; Day, Victor W. Inorganic Chemistry, Vol. 53, Issue 14 https://doi.org/10.1021/ic500943k	journal	June 2014
pH-Dependent Structures of the Manganese Binding Sites in Oxalate Decarboxylase as Revealed by High-Field Electron Paramagnetic Resonance Tabares, Leandro C.; Gätjens, Jessica; Hureau, Christelle The Journal of Physical Chemistry B, Vol. 113, Issue 26 https://doi.org/10.1021/jp9021807	journal	July 2009
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density Lee, Chengteh; Yang, Weitao; Parr, Robert G. Physical Review B, Vol. 37, Issue 2 https://doi.org/10.1103/PhysRevB.37.785	journal	January 1988
Manganese K-Edge X-Ray Absorption Spectroscopy as a Probe of the Metal–Ligand Interactions in Coordination Compounds Roemelt, Michael; Beckwith, Martha A.; Duboc, Carole Inorganic Chemistry, Vol. 51, Issue 1 https://doi.org/10.1021/ic202229b	journal	December 2011
A Monomeric Mn ^III −Peroxo Complex Derived Directly from Dioxygen Shook, Ryan L.; Gunderson, William A.; Greaves, John Journal of the American Chemical Society, Vol. 130, Issue 28 https://doi.org/10.1021/ja802775e	journal	July 2008
Spectroscopic properties and reactivity of a mononuclear oxomanganese(iv) complex Leto, Domenick F.; Ingram, Rena; Day, Victor W. Chemical Communications, Vol. 49, Issue 47 https://doi.org/10.1039/c3cc00244f	journal	January 2013
Peroxo(tetraphenylporphinato)manganese(III) and chloro(tetraphenylporphinato)manganese(II) anions. Synthesis, crystal structures, and electronic structures. VanAtta, Reuel B.; Strouse, Charles E.; Hanson, Louise Karle Journal of the American Chemical Society, Vol. 109, Issue 5 https://doi.org/10.1021/ja00239a024	journal	March 1987
Reactivity of an Aminopyridine [LMn ^II ] ²⁺ Complex with H ₂ O ₂ . Detection of Intermediates at Low Temperature Groni, Sihem; Dorlet, Pierre; Blain, Guillaume Inorganic Chemistry, Vol. 47, Issue 8 https://doi.org/10.1021/ic702238z	journal	April 2008
Dialkylbiaryl phosphines in Pd-catalyzed amination: a user's guide Surry, David S.; Buchwald, Stephen L. Chem. Sci., Vol. 2, Issue 1 https://doi.org/10.1039/C0SC00331J	journal	January 2011
Mimicking Class I b Mn ₂ -Ribonucleotide Reductase: A Mn ^II ₂ Complex and Its Reaction with Superoxide Magherusan, Adriana M.; Zhou, Ang; Farquhar, Erik R. Angewandte Chemie International Edition, Vol. 57, Issue 4 https://doi.org/10.1002/anie.201709806	journal	December 2017
Structural Characterization and Remarkable Axial Ligand Effect on the Nucleophilic Reactivity of a Nonheme Manganese(III)-Peroxo Complex Annaraj, Jamespandi; Cho, Jaeheung; Lee, Yong-Min Angewandte Chemie International Edition, Vol. 48, Issue 23 https://doi.org/10.1002/anie.200900118	journal	May 2009
Structural, Spectroscopic, and Reactivity Models for the Manganese Catalases Wu, Amy J.; Penner-Hahn, James E.; Pecoraro, Vincent L. Chemical Reviews, Vol. 104, Issue 2 https://doi.org/10.1021/cr020627v	journal	February 2004
Peroxomanganese complexes as an aid to understanding redox-active manganese enzymes Leto, Domenick F.; Jackson, Timothy A. JBIC Journal of Biological Inorganic Chemistry, Vol. 19, Issue 1 https://doi.org/10.1007/s00775-013-1067-4	journal	November 2013
Nucleophilic reactivity of a series of peroxomanganese(iii) complexes supported by tetradentate aminopyridyl ligands Geiger, Robert A.; Chattopadhyay, Swarup; Day, Victor W. Dalton Transactions, Vol. 40, Issue 8 https://doi.org/10.1039/c0dt01570a	journal	January 2011
Interaction of Manganese with Dioxygen and Its Reduced Derivatives Pecoraro, Vincent L.; Baldwin, Michael J.; Gelasco, Andrew Chemical Reviews, Vol. 94, Issue 3 https://doi.org/10.1021/cr00027a012	journal	May 1994
A Monomeric Side-On Peroxo Manganese(III) Complex: Mn(O2)(3,5-iPr2pzH)(HB(3,5-iPr2pz)3) Kitajima, Nobumasa; Komatsuzaki, Hidehito; Hikichi, Shiro Journal of the American Chemical Society, Vol. 116, Issue 25 https://doi.org/10.1021/ja00104a061	journal	December 1994
The 2-His-1-carboxylate facial triad: a versatile platform for dioxygen activation by mononuclear non-heme iron(II) enzymes Koehntop, Kevin D.; Emerson, Joseph P.; Que, Lawrence JBIC Journal of Biological Inorganic Chemistry, Vol. 10, Issue 2 https://doi.org/10.1007/s00775-005-0624-x	journal	March 2005
Deformylation Reaction by a Nonheme Manganese(III)-Peroxo Complex via Initial Hydrogen-Atom Abstraction Barman, Prasenjit; Upadhyay, Pranav; Faponle, Abayomi S. Angewandte Chemie International Edition, Vol. 55, Issue 37 https://doi.org/10.1002/anie.201604412	journal	July 2016
Time-dependent density functional theory within the Tamm–Dancoff approximation Hirata, So; Head-Gordon, Martin Chemical Physics Letters, Vol. 314, Issue 3-4 https://doi.org/10.1016/S0009-2614(99)01149-5	journal	December 1999
Mn K-Edge X-ray Absorption Studies of Oxo- and Hydroxo-manganese(IV) Complexes: Experimental and Theoretical Insights into Pre-Edge Properties Leto, Domenick F.; Jackson, Timothy A. Inorganic Chemistry, Vol. 53, Issue 12 https://doi.org/10.1021/ic5006902	journal	May 2014
Catalytic Reduction of Dioxygen to Water with a Monomeric Manganese Complex at Room Temperature Shook, Ryan L.; Peterson, Sonja M.; Greaves, John Journal of the American Chemical Society, Vol. 133, Issue 15 https://doi.org/10.1021/ja106564a	journal	April 2011
Oxalate Decarboxylase Requires Manganese and Dioxygen for Activity: OVEREXPRESSION AND CHARACTERIZATION OF Tanner, Adam; Bowater, Laura; Fairhurst, Shirley A. Journal of Biological Chemistry, Vol. 276, Issue 47 https://doi.org/10.1074/jbc.M107202200	journal	August 2001
Mechanisms in manganese catalysed oxidation of alkenes with H ₂ O ₂ Saisaha, Pattama; de Boer, Johannes W.; Browne, Wesley R. Chem. Soc. Rev., Vol. 42, Issue 5 https://doi.org/10.1039/C2CS35443H	journal	January 2013
Dioxygen Activation by Nonheme Diiron Enzymes: Diverse Dioxygen Adducts, High-Valent Intermediates, and Related Model Complexes Jasniewski, Andrew J.; Que, Lawrence Chemical Reviews, Vol. 118, Issue 5 https://doi.org/10.1021/acs.chemrev.7b00457	journal	December 2017
Metalloporphyrin Peroxo Complexes of Iron(III), Manganese(III), and Titanium(IV). Comparative Studies Demonstrating That the Iron(III) Complex Is Extremely Nucleophilic Sisemore, Marlene F.; Selke, Matthias; Burstyn, Judith N. Inorganic Chemistry, Vol. 36, Issue 6 https://doi.org/10.1021/ic9612616	journal	March 1997
Direct Selective Oxidative Functionalization of C–H Bonds with H2O2: Mn-Aminopyridine Complexes Challenge the Dominance of Non-Heme Fe Catalysts Ottenbacher, Roman; Talsi, Evgenii; Bryliakov, Konstantin Molecules, Vol. 21, Issue 11 https://doi.org/10.3390/molecules21111454	journal	October 2016
[Mn(tmc)(O2)]+: A Side-On Peroxido Manganese(III) Complex Bearing a Non-Heme Ligand Seo, Mi Sook; Kim, Ja Young; Annaraj, Jamespandi Angewandte Chemie International Edition, Vol. 46, Issue 3 https://doi.org/10.1002/anie.200603414	journal	January 2007
Biomimetic Reactivity of Oxygen-Derived Manganese and Iron Porphyrinoid Complexes Baglia, Regina A.; Zaragoza, Jan Paulo T.; Goldberg, David P. Chemical Reviews, Vol. 117, Issue 21 https://doi.org/10.1021/acs.chemrev.7b00180	journal	October 2017
Bioinspired Hydrogen Bond Motifs in Ligand Design: The Role of Noncovalent Interactions in Metal Ion Mediated Activation of Dioxygen Borovik, A. S. Accounts of Chemical Research, Vol. 38, Issue 1 https://doi.org/10.1021/ar030160q	journal	January 2005
Role of the Secondary Coordination Sphere in Metal-Mediated Dioxygen Activation Shook, Ryan L.; Borovik, A. S. Inorganic Chemistry, Vol. 49, Issue 8 https://doi.org/10.1021/ic901550k	journal	April 2010
Relativistic regular two‐component Hamiltonians Lenthe, E. van; Baerends, E. J.; Snijders, J. G. The Journal of Chemical Physics, Vol. 99, Issue 6 https://doi.org/10.1063/1.466059	journal	September 1993
Spectroscopic Characterization and Reactivity Studies of a Mononuclear Nonheme Mn(III)–Hydroperoxo Complex So, Hee; Park, Young Jun; Cho, Kyung-Bin Journal of the American Chemical Society, Vol. 136, Issue 35 https://doi.org/10.1021/ja506275q	journal	August 2014
Fityk : a general-purpose peak fitting program Wojdyr, Marcin Journal of Applied Crystallography, Vol. 43, Issue 5 https://doi.org/10.1107/S0021889810030499	journal	September 2010
Molecular density functional calculations in the regular relativistic approximation: Method, application to coinage metal diatomics, hydrides, fluorides and chlorides, and comparison with first-order relativistic calculations van Wüllen, Christoph The Journal of Chemical Physics, Vol. 109, Issue 2 https://doi.org/10.1063/1.476576	journal	July 1998
The Synthesis and Biological Evaluation of Quinolyl-piperazinyl Piperidines as Potent Serotonin 5-HT _1A Antagonists Childers, Wayne E.; Havran, Lisa M.; Asselin, Magda Journal of Medicinal Chemistry, Vol. 53, Issue 10 https://doi.org/10.1021/jm1000908	journal	May 2010
Structural and Spectroscopic Studies Shed Light on the Mechanism of Oxalate Oxidase Opaleye, Olaniyi; Rose, Ruth-Sarah; Whittaker, Mei M. Journal of Biological Chemistry, Vol. 281, Issue 10 https://doi.org/10.1074/jbc.M510256200	journal	November 2005

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Title: Mn ^III -Peroxo adduct supported by a new tetradentate ligand shows acid-sensitive aldehyde deformylation reactivity