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Title: The quest for manganese-rich electrodes for lithium batteries: strategic design and electrochemical behavior

Abstract

Manganese oxides, notably γ-MnO2and modified derivatives, have played a major role in electrochemical energy storage for well over a century.

Authors:
 [1];  [1];  [1]; ORCiD logo [1];  [1];  [1];  [1];  [1];  [1];  [1];  [2];  [3]
  1. Electrochemical Energy Storage Department; Chemical Sciences and Engineering Division; Argonne National Laboratory; Lemont; USA
  2. Materials Engineering Research Facility; Energy Sciences Division; Argonne National Laboratory; Lemont; USA
  3. ISIS Neutron and Muon Source; Rutherford Appleton Laboratory; Harwell; UK; Inorganic Chemistry Laboratory
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
OSTI Identifier:
1468610
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article
Journal Name:
Sustainable Energy & Fuels
Additional Journal Information:
Journal Volume: 2; Journal Issue: 7; Journal ID: ISSN 2398-4902
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

Citation Formats

Thackeray, M.  M., Croy, J. R., Lee, Eungje, Gutierrez, A., He, Meinan, Park, Joong Sun, Yonemoto, B. T., Long, B. R., Blauwkamp, J. D., Johnson, C. S., Shin, Youngho, and David, W. I. F. The quest for manganese-rich electrodes for lithium batteries: strategic design and electrochemical behavior. United States: N. p., 2018. Web. doi:10.1039/c8se00157j.
Thackeray, M.  M., Croy, J. R., Lee, Eungje, Gutierrez, A., He, Meinan, Park, Joong Sun, Yonemoto, B. T., Long, B. R., Blauwkamp, J. D., Johnson, C. S., Shin, Youngho, & David, W. I. F. The quest for manganese-rich electrodes for lithium batteries: strategic design and electrochemical behavior. United States. https://doi.org/10.1039/c8se00157j
Thackeray, M.  M., Croy, J. R., Lee, Eungje, Gutierrez, A., He, Meinan, Park, Joong Sun, Yonemoto, B. T., Long, B. R., Blauwkamp, J. D., Johnson, C. S., Shin, Youngho, and David, W. I. F. 2018. "The quest for manganese-rich electrodes for lithium batteries: strategic design and electrochemical behavior". United States. https://doi.org/10.1039/c8se00157j.
@article{osti_1468610,
title = {The quest for manganese-rich electrodes for lithium batteries: strategic design and electrochemical behavior},
author = {Thackeray, M.  M. and Croy, J. R. and Lee, Eungje and Gutierrez, A. and He, Meinan and Park, Joong Sun and Yonemoto, B. T. and Long, B. R. and Blauwkamp, J. D. and Johnson, C. S. and Shin, Youngho and David, W. I. F.},
abstractNote = {Manganese oxides, notably γ-MnO2and modified derivatives, have played a major role in electrochemical energy storage for well over a century.},
doi = {10.1039/c8se00157j},
url = {https://www.osti.gov/biblio/1468610}, journal = {Sustainable Energy & Fuels},
issn = {2398-4902},
number = 7,
volume = 2,
place = {United States},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}

Works referenced in this record:

Improved capacity retention in rechargeable 4 V lithium/lithium-manganese oxide (spinel) cells
journal, April 1994


Rechargeability and economic aspects of alkaline zinc–manganese dioxide cells for electrical storage and load leveling
journal, February 2015


Reaction Energy for LiMn[sub 2]O[sub 4] Spinel Dissolution in Acid
journal, January 2006


Evidence for anionic redox activity in a tridimensional-ordered Li-rich positive electrode β-Li2IrO3
journal, February 2017


Lithium Batteries and Cathode Materials
journal, October 2004


Structural and electrochemical analysis of layered compounds from Li2MnO3
journal, September 1999


Synthesis and properties of lithium-graphite intercalation compounds
journal, June 1979


Material design of high-capacity Li-rich layered-oxide electrodes: Li 2 MnO 3 and beyond
journal, January 2017


A new variety of LiMnO2 with a layered structure
journal, August 1996


Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni0.2Li0.2Mn0.6]O2
journal, June 2006


Comments on the structural complexity of lithium-rich Li1+xM1−xO2 electrodes (M=Mn, Ni, Co) for lithium batteries
journal, September 2006


Anion Redox Chemistry in the Cobalt Free 3d Transition Metal Oxide Intercalation Electrode Li[Li 0.2 Ni 0.2 Mn 0.6 ]O 2
journal, August 2016


A reinvestigation of the structures of lithium-cobalt-oxides with neutron-diffraction data
journal, November 1993


Overcharging manganese oxides: Extracting lithium beyond Mn4+
journal, August 2005


Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteries
journal, March 2005

  • Thackeray, Michael M.; Johnson, Christopher S.; Vaughey, John T.
  • Journal of Materials Chemistry, Vol. 15, Issue 23, p. 2257-2267
  • https://doi.org/10.1039/b417616m

ZrO2- and Li2ZrO3-stabilized spinel and layered electrodes for lithium batteries
journal, September 2003


Structural aspects of lithium-manganese-oxide electrodes for rechargeable lithium batteries
journal, February 1990


CoO2, The End Member of the LixCoO2 Solid Solution
journal, January 1996


Composite ‘Layered-Layered-Spinel’ Cathode Structures for Lithium-Ion Batteries
journal, November 2012


Lithium insertion/extraction reactions with LiVO2 and LiV2O4
journal, January 1986


Li-ion battery materials: present and future
journal, June 2015


Layered-to-Spinel Phase Transition in Li[sub x]MnO[sub 2]
journal, January 2001


Synthesis of layered LiMnO2 as an electrode for rechargeable lithium batteries
journal, June 1996


Mechanism of Electrochemical Activity in Li 2 MnO 3
journal, May 2003


Intercalation compounds of graphite
journal, April 1981


High-voltage positive electrode materials for lithium-ion batteries
journal, January 2017


Exploring Lithium-Cobalt-Nickel Oxide Spinel Electrodes for ≥3.5 V Li-Ion Cells
journal, October 2016


Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries
journal, April 1997


Chemical and Magnetic Characterization of Spinel Materials in the LiMn2O4–Li2Mn4O9–Li4Mn5O12System
journal, May 1996


Review of the U.S. Department of Energy’s “Deep Dive” Effort to Understand Voltage Fade in Li- and Mn-Rich Cathodes
journal, October 2015


Structural and electrochemical characteristics of a hollandite-type ‘LiξMnO2’
journal, April 1993


Charge, Potential, and Phase Stability of Layered Li(Ni[sub 0.5]Mn[sub 0.5])O[sub 2]
journal, January 2002


Li‐ and Mn‐Rich Cathode Materials: Challenges to Commercialization
journal, December 2016


Correlating hysteresis and voltage fade in lithium- and manganese-rich layered transition-metal oxide electrodes
journal, August 2013


Manganese oxides for lithium batteries
journal, January 1997


Structural and electrochemical properties of the proton / γ-MnO2 system
journal, January 1995


Low-Zinc-Solubility Electrolytes for Use in Zinc/Nickel Oxide Cells
journal, January 1993


Vision for Designing High-Energy, Hybrid Li Ion/Li–O 2 Cells
journal, October 2013


Lithium–manganese–nickel-oxide electrodes with integrated layered–spinel structures for lithium batteries
journal, February 2007


The Electrochemical Stability of Spinel Electrodes Coated with ZrO2, Al2O3, and SiO2 from Colloidal Suspensions
journal, January 2004


Synthesis, Structure, and Electrochemical Behavior of Li[Ni[sub x]Li[sub 1/3−2x/3]Mn[sub 2/3−x/3]]O[sub 2]
journal, January 2002


Probing the Release and Uptake of Water in α-MnO 2 · x H 2 O
journal, February 2017


Examining Hysteresis in Composite x Li 2 MnO 3 ·(1– x )LiMO 2 Cathode Structures
journal, March 2013


Lithium- and Manganese-Rich Oxide Cathode Materials for High-Energy Lithium Ion Batteries
journal, August 2016


Primary Batteries 1951–1976
journal, January 1978


Electrical Energy Storage and Intercalation Chemistry
journal, June 1976


Lithium insertion into manganese spinels
journal, April 1983


The Secondary Alkaline Zinc Electrode
journal, January 1991


Rechargeable Cells with Modified MnO[sub 2] Cathodes
journal, January 1988


Structural and electrochemical studies of α-manganese dioxide (α-MnO2)
journal, October 1997


Structural and Electrochemical Studies of 3 V Li[sub x]MnO[sub 2] Cathodes for Rechargeable Li Batteries
journal, January 1997


Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries
journal, January 2007


Cathode materials modified by surface coating for lithium ion batteries
journal, May 2006


Li 2 O Removal from Li 5 FeO 4 : A Cathode Precursor for Lithium-Ion Batteries
journal, February 2010


Remarkably Improved Electrochemical Performance of Li- and Mn-Rich Cathodes upon Substitution of Mn with Ni
journal, September 2016


New intercalation compounds for lithium batteries: layered LiMnO2
journal, January 1999


Preparation of a new crystal form of manganese dioxide: λ-MnO2
journal, September 1981


α-MnO2 Nanowires: A Catalyst for the O2 Electrode in Rechargeable Lithium Batteries
journal, June 2008


Suppressing Manganese Dissolution from Lithium Manganese Oxide Spinel Cathodes with Single-Layer Graphene
journal, June 2015


Synthesis and characterization of lithium aluminum-doped spinel (LiAlxMn2−xO4) for lithium secondary battery
journal, June 2001


The cycling properties of the LixNi1−yCoyO2 electrode
journal, April 1993


Optimized 4-V Spinel Cathode Material with High Energy Density for Li-Ion Cells Operating at 60 °C
journal, August 2013


Reversible anionic redox chemistry in high-capacity layered-oxide electrodes
journal, July 2013


Advances in Stabilizing ‘Layered-Layered’ xLi2MnO3·(1-x)LiMO2(M=Mn, Ni, Co) Electrodes with a Spinel Component
journal, January 2014


Electrochemical extraction of lithium from LiMn2O4
journal, February 1984


Challenges for Rechargeable Li Batteries
journal, February 2010


First-principles calculation of atomic structure and electrochemical potential of Li1+xV3O8
journal, September 1999


Revealing the Intrinsic Li Mobility in the Li 2 MnO 3 Lithium-Excess Material
journal, March 2016


Structural characterization of Li1+xV3O8 insertion electrodes by single-crystal X-ray diffraction
journal, August 1993


Structural transformation on cycling layered Li(Mn1−yCoy)O2 cathode materials
journal, September 1999


Prospects for spinel-stabilized, high-capacity lithium-ion battery cathodes
journal, December 2016


Lithium-cobalt-nickel-oxide cathode materials prepared at 400°C for rechargeable lithium batteries
journal, July 1992


Mn(II) deposition on anodes and its effects on capacity fade in spinel lithium manganate–carbon systems
journal, September 2013


Al Doping for Mitigating the Capacity Fading and Voltage Decay of Layered Li and Mn-Rich Cathodes for Li-Ion Batteries
journal, February 2016


An overview of the Li(Ni,M)O2 systems: syntheses, structures and properties
journal, September 1999


Long-Range and Local Structure in the Layered Oxide Li 1.2 Co 0.4 Mn 0.4 O 2
journal, April 2011


Anionic redox processes for electrochemical devices
journal, January 2016


Spinel Electrodes from the Li-Mn-O System for Rechargeable Lithium Battery Applications
journal, January 1992


Characterization of Li1+yNixCo1−2xMnxO2 positive active materials for lithium ion batteries
journal, August 2005


High capacity double-layer surface modified Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode with improved rate capability
journal, January 2009


Surface modification of LiNi0.5Mn1.5O4 by ZrP2O7 and ZrO2 for lithium-ion batteries
journal, May 2010


Local Structure and First Cycle Redox Mechanism of Layered Li[sub 1.2]Cr[sub 0.4]Mn[sub 0.4]O[sub 2] Cathode Material
journal, January 2002


Stability of Li- and Mn-Rich Layered-Oxide Cathodes within the First-Charge Voltage Plateau
journal, January 2016


The significance of the Li2MnO3 component in ‘composite’ xLi2MnO3·(1−x)LiMn0.5Ni0.5O2 electrodes
journal, October 2004


Lithium insertion into βMnO2 and the rutile-spinel transformation
journal, January 1984


Manganese oxide minerals: Crystal structures and economic and environmental significance
journal, March 1999


Structure and electrochemistry of LixMnyNi1−yO2
journal, October 1992


Structure and electrochemistry of lithium cobalt oxide synthesised at 400°C
journal, March 1992


Effect of Structure on the Fe[sup 3+]∕Fe[sup 2+] Redox Couple in Iron Phosphates
journal, January 1997


Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries
journal, December 2015


The versatility of MnO2 for lithium battery applications
journal, March 1993


Electrochemical and In Situ X‐Ray Diffraction Studies of Lithium Intercalation in LixCoO2
journal, January 1992


Studies of Spinel-to-Layered Structural Transformations in LiMn 2 O 4 Electrodes Charged to High Voltages
journal, April 2017


Lithium metal rechargeable cells using Li2MnO3 as the positive electrode
journal, July 1999


Electrochemical characterization of a new high capacity cathode
journal, July 2001


The Manganese Dioxide Electrode
journal, January 1959


Lithium and Deuterium NMR Studies of Acid-Leached Layered Lithium Manganese Oxides
journal, December 2002


Enhancing the rate capability of high capacity xLi2MnO3 · (1−x)LiMO2 (M=Mn, Ni, Co) electrodes by Li–Ni–PO4 treatment
journal, April 2009


The rechargeability of manganese dioxide in alkaline electrolyte
journal, October 1981


Synthesis, Thermal, and Electrochemical Properties of AlPO[sub 4]-Coated LiNi[sub 0.8]Co[sub 0.1]Mn[sub 0.1]O[sub 2] Cathode Materials for a Li-Ion Cell
journal, January 2004


Physical and electrochemical properties of spherical Li1+x(Ni1/3Co1/3Mn1/3)1−xO2 cathode materials
journal, February 2008


Synthesis and electrochemistry of spinel LTLiCoO2
journal, July 1993


Nanostructured high-energy cathode materials for advanced lithium batteries
journal, October 2012


A New Three‐Volt Spinel Li1 + xMn1.5Ni0.5 O 4 for Secondary Lithium Batteries
journal, January 1996


Electrochemical and Structural Properties of xLi2M‘O3 ·(1− x )LiMn0.5Ni0.5O2 Electrodes for Lithium Batteries (M‘ = Ti, Mn, Zr; 0 ≤ x ⩽ 0.3)
journal, May 2004


Electrochemical characteristics of Al2O3-coated lithium manganese spinel as a cathode material for a lithium secondary battery
journal, February 2004


Chemistry of intercalation compounds: Metal guests in chalcogenide hosts
journal, January 1978


Layered Li x Mn 1- y Co y O 2 Intercalation ElectrodesInfluence of Ion Exchange on Capacity and Structure upon Cycling
journal, July 2001


Alpha manganese dioxide for lithium batteries: A structural and electrochemical study
journal, February 1992


Manganese oxides for a lithium secondary battery — composite dimensional manganese oxide (CDMO)
journal, May 1989


Lithium extraction from orthorhombic lithium manganese oxide and the phase transformation to spinel
journal, December 1993


A review of blended cathode materials for use in Li-ion batteries
journal, February 2014


The Spinel Phase of LiMn[sub 2]O[sub 4] as a Cathode in Secondary Lithium Cells
journal, January 1991


Anomalous capacity and cycling stability of xLi2MnO3·(1−x)LiMO2 electrodes (M=Mn, Ni, Co) in lithium batteries at 50°C
journal, April 2007


Functional surface modifications of a high capacity layered Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode
journal, January 2010


Effect of Cooling Rates on Phase Separation in 0.5Li 2 MnO 3 ·0.5LiCoO 2 Electrode Materials for Li-Ion Batteries
journal, May 2014


Spinel versus layered structures for lithium cobalt oxide synthesised at 400°C
journal, March 1993


Atomic Structure of a Lithium-Rich Layered Oxide Material for Lithium-Ion Batteries: Evidence of a Solid Solution
journal, August 2011


Electrical energy storage for transportation—approaching the limits of, and going beyond, lithium-ion batteries
journal, January 2012


Lithium manganese oxides from Li2MnO3 for rechargeable lithium battery applications
journal, June 1991


Electrochemistry of Manganese Dioxide in Lithium Nonaqueous Cell
journal, January 1990


LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density
journal, June 1980


A perspective on nickel-rich layered oxide cathodes for lithium-ion batteries
journal, January 2017


Review—SEI: Past, Present and Future
journal, January 2017


Understanding the Second Electron Discharge Plateau in MnO[sub 2]-Based Alkaline Cells
journal, January 2001


Preparation of Plate-Form Manganese Oxide by Selective Lithium Extraction from Monoclinic Li 2 MnO 3 under Hydrothermal Conditions
journal, November 2000