The quest for manganese-rich electrodes for lithium batteries: strategic design and electrochemical behavior
Abstract
Manganese oxides, notably γ-MnO2and modified derivatives, have played a major role in electrochemical energy storage for well over a century.
- Authors:
-
- Electrochemical Energy Storage Department; Chemical Sciences and Engineering Division; Argonne National Laboratory; Lemont; USA
- Materials Engineering Research Facility; Energy Sciences Division; Argonne National Laboratory; Lemont; USA
- ISIS Neutron and Muon Source; Rutherford Appleton Laboratory; Harwell; UK; Inorganic Chemistry Laboratory
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
- OSTI Identifier:
- 1468610
- DOE Contract Number:
- AC02-06CH11357
- Resource Type:
- Journal Article
- Journal Name:
- Sustainable Energy & Fuels
- Additional Journal Information:
- Journal Volume: 2; Journal Issue: 7; Journal ID: ISSN 2398-4902
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Thackeray, M. M., Croy, J. R., Lee, Eungje, Gutierrez, A., He, Meinan, Park, Joong Sun, Yonemoto, B. T., Long, B. R., Blauwkamp, J. D., Johnson, C. S., Shin, Youngho, and David, W. I. F. The quest for manganese-rich electrodes for lithium batteries: strategic design and electrochemical behavior. United States: N. p., 2018.
Web. doi:10.1039/c8se00157j.
Thackeray, M. M., Croy, J. R., Lee, Eungje, Gutierrez, A., He, Meinan, Park, Joong Sun, Yonemoto, B. T., Long, B. R., Blauwkamp, J. D., Johnson, C. S., Shin, Youngho, & David, W. I. F. The quest for manganese-rich electrodes for lithium batteries: strategic design and electrochemical behavior. United States. https://doi.org/10.1039/c8se00157j
Thackeray, M. M., Croy, J. R., Lee, Eungje, Gutierrez, A., He, Meinan, Park, Joong Sun, Yonemoto, B. T., Long, B. R., Blauwkamp, J. D., Johnson, C. S., Shin, Youngho, and David, W. I. F. 2018.
"The quest for manganese-rich electrodes for lithium batteries: strategic design and electrochemical behavior". United States. https://doi.org/10.1039/c8se00157j.
@article{osti_1468610,
title = {The quest for manganese-rich electrodes for lithium batteries: strategic design and electrochemical behavior},
author = {Thackeray, M. M. and Croy, J. R. and Lee, Eungje and Gutierrez, A. and He, Meinan and Park, Joong Sun and Yonemoto, B. T. and Long, B. R. and Blauwkamp, J. D. and Johnson, C. S. and Shin, Youngho and David, W. I. F.},
abstractNote = {Manganese oxides, notably γ-MnO2and modified derivatives, have played a major role in electrochemical energy storage for well over a century.},
doi = {10.1039/c8se00157j},
url = {https://www.osti.gov/biblio/1468610},
journal = {Sustainable Energy & Fuels},
issn = {2398-4902},
number = 7,
volume = 2,
place = {United States},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}
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Works referenced in this record:
The Manganese Dioxide Electrode in Alkaline Electrolyte; The Electron-Proton Mechanism for the Discharge Process from MnO[sub 2] to MnO[sub 1.5]
journal, January 1966
- Kozawa, A.; Powers, R. A.
- Journal of The Electrochemical Society, Vol. 113, Issue 9
Improved capacity retention in rechargeable 4 V lithium/lithium-manganese oxide (spinel) cells
journal, April 1994
- Gummow, R. J.; de Kock, A.; Thackeray, M. M.
- Solid State Ionics, Vol. 69, Issue 1, p. 59-67
Rechargeability and economic aspects of alkaline zinc–manganese dioxide cells for electrical storage and load leveling
journal, February 2015
- Ingale, Nilesh D.; Gallaway, Joshua W.; Nyce, Michael
- Journal of Power Sources, Vol. 276
Reaction Energy for LiMn[sub 2]O[sub 4] Spinel Dissolution in Acid
journal, January 2006
- Benedek, R.; Thackeray, M. M.
- Electrochemical and Solid-State Letters, Vol. 9, Issue 6
Evidence for anionic redox activity in a tridimensional-ordered Li-rich positive electrode β-Li2IrO3
journal, February 2017
- Pearce, Paul E.; Perez, Arnaud J.; Rousse, Gwenaelle
- Nature Materials, Vol. 16, Issue 5
Lithium Batteries and Cathode Materials
journal, October 2004
- Whittingham, M. Stanley
- Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302
Structural and electrochemical analysis of layered compounds from Li2MnO3
journal, September 1999
- Johnson, C. S.; Korte, S. D.; Vaughey, J. T.
- Journal of Power Sources, Vol. 81-82
Synthesis and properties of lithium-graphite intercalation compounds
journal, June 1979
- Basu, S.; Zeller, C.; Flanders, P. J.
- Materials Science and Engineering, Vol. 38, Issue 3
Material design of high-capacity Li-rich layered-oxide electrodes: Li 2 MnO 3 and beyond
journal, January 2017
- Kim, Soo; Aykol, Muratahan; Hegde, Vinay I.
- Energy & Environmental Science, Vol. 10, Issue 10
A new variety of LiMnO2 with a layered structure
journal, August 1996
- Capitaine, F.; Gravereau, P.; Delmas, C.
- Solid State Ionics, Vol. 89, Issue 3-4, p. 197-202
Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni0.2Li0.2Mn0.6]O2
journal, June 2006
- Armstrong, A. Robert; Holzapfel, Michael; Novák, Petr
- Journal of the American Chemical Society, Vol. 128, Issue 26
The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials
journal, May 2016
- Seo, Dong-Hwa; Lee, Jinhyuk; Urban, Alexander
- Nature Chemistry, Vol. 8, Issue 7
Layered xLiMO2·(1−x)Li2M′O3 electrodes for lithium batteries: a study of 0.95LiMn0.5Ni0.5O2·0.05Li2TiO3
journal, March 2002
- Kim, J.
- Electrochemistry Communications, Vol. 4, Issue 3
Lithium-containing manganese dioxide (composite dimensional manganese oxide: CDMO) as positive material for a lithium secondary battery
journal, October 1990
- Nohma, T.; Yamamoto, Y.; Nishio, K.
- Journal of Power Sources, Vol. 32, Issue 4
The Role of AlF3 Coatings in Improving Electrochemical Cycling of Li-Enriched Nickel-Manganese Oxide Electrodes for Li-Ion Batteries
journal, February 2012
- Sun, Yang-Kook; Lee, Min-Joon; Yoon, Chong S.
- Advanced Materials, Vol. 24, Issue 9
Comments on the structural complexity of lithium-rich Li1+xM1−xO2 electrodes (M=Mn, Ni, Co) for lithium batteries
journal, September 2006
- Thackeray, M. M.; Kang, S.-H.; Johnson, C. S.
- Electrochemistry Communications, Vol. 8, Issue 9, p. 1531-1538
Anion Redox Chemistry in the Cobalt Free 3d Transition Metal Oxide Intercalation Electrode Li[Li 0.2 Ni 0.2 Mn 0.6 ]O 2
journal, August 2016
- Luo, Kun; Roberts, Matthew R.; Guerrini, Niccoló
- Journal of the American Chemical Society, Vol. 138, Issue 35
A reinvestigation of the structures of lithium-cobalt-oxides with neutron-diffraction data
journal, November 1993
- Gummow, R. J.; Liles, D. C.; Thackeray, M. M.
- Materials Research Bulletin, Vol. 28, Issue 11, p. 1177-1184
Valence band of and its effects on the voltage profiles of /Li electrochemical cells
journal, December 1996
- Gao, Yuan; Myrtle, K.; Zhang, Meijie
- Physical Review B, Vol. 54, Issue 23
Overcharging manganese oxides: Extracting lithium beyond Mn4+
journal, August 2005
- Armstrong, A. R.; Robertson, A. D.; Bruce, P. G.
- Journal of Power Sources, Vol. 146, Issue 1-2
Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteries
journal, March 2005
- Thackeray, Michael M.; Johnson, Christopher S.; Vaughey, John T.
- Journal of Materials Chemistry, Vol. 15, Issue 23, p. 2257-2267
ZrO2- and Li2ZrO3-stabilized spinel and layered electrodes for lithium batteries
journal, September 2003
- Thackeray, M. M.; Johnson, C. S.; Kim, J. -S
- Electrochemistry Communications, Vol. 5, Issue 9
Comprehensive Enhancement of Nanostructured Lithium-Ion Battery Cathode Materials via Conformal Graphene Dispersion
journal, March 2017
- Chen, Kan-Sheng; Xu, Rui; Luu, Norman S.
- Nano Letters, Vol. 17, Issue 4
Structural aspects of lithium-manganese-oxide electrodes for rechargeable lithium batteries
journal, February 1990
- Rossouw, Mh; de Kock, A.; de Picciotto, La
- Materials Research Bulletin, Vol. 25, Issue 2
CoO2, The End Member of the LixCoO2 Solid Solution
journal, January 1996
- Amatucci, G. G.; Tarascon, J. M.; Klein, L. C.
- Journal of The Electrochemical Society, Vol. 143, Issue 3, p. 1114-1123
Composite ‘Layered-Layered-Spinel’ Cathode Structures for Lithium-Ion Batteries
journal, November 2012
- Kim, Donghan; Sandi, Giselle; Croy, Jason R.
- Journal of The Electrochemical Society, Vol. 160, Issue 1, p. A31-A38
Lithium insertion/extraction reactions with LiVO2 and LiV2O4
journal, January 1986
- Depicciotto, L.; Thackeray, M.
- Solid State Ionics, Vol. 18-19
Li-ion battery materials: present and future
journal, June 2015
- Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae
- Materials Today, Vol. 18, Issue 5
Layered-to-Spinel Phase Transition in Li[sub x]MnO[sub 2]
journal, January 2001
- Reed, J.; Ceder, G.; Van Der Ven, A.
- Electrochemical and Solid-State Letters, Vol. 4, Issue 6
Lithium–manganese oxide electrodes with layered–spinel composite structures xLi2MnO3·(1−x)Li1+yMn2−yO4 (0<x<1, 0⩽y⩽0.33) for lithium batteries
journal, May 2005
- Johnson, C. S.; Li, N.; Vaughey, J. T.
- Electrochemistry Communications, Vol. 7, Issue 5, p. 528-536
Synthesis of layered LiMnO2 as an electrode for rechargeable lithium batteries
journal, June 1996
- Armstrong, A. Robert; Bruce, Peter G.
- Nature, Vol. 381, Issue 6582
Mechanism of Electrochemical Activity in Li 2 MnO 3
journal, May 2003
- Robertson, Alastair D.; Bruce, Peter G.
- Chemistry of Materials, Vol. 15, Issue 10
Evidence of reversible oxygen participation in anomalously high capacity Li- and Mn-rich cathodes for Li-ion batteries
journal, March 2016
- Muhammad, Shoaib; Kim, Hyunchul; Kim, Yunok
- Nano Energy, Vol. 21
Intercalation compounds of graphite
journal, April 1981
- Dresselhaus, M. S.; Dresselhaus, G.
- Advances in Physics, Vol. 30, Issue 2
High-voltage positive electrode materials for lithium-ion batteries
journal, January 2017
- Li, Wangda; Song, Bohang; Manthiram, Arumugam
- Chemical Society Reviews, Vol. 46, Issue 10
Exploring Lithium-Cobalt-Nickel Oxide Spinel Electrodes for ≥3.5 V Li-Ion Cells
journal, October 2016
- Lee, Eungje; Blauwkamp, Joel; Castro, Fernando C.
- ACS Applied Materials & Interfaces, Vol. 8, Issue 41
Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries
journal, April 1997
- Padhi, A. K.
- Journal of The Electrochemical Society, Vol. 144, Issue 4, p. 1188-1194
Chemical and Magnetic Characterization of Spinel Materials in the LiMn2O4–Li2Mn4O9–Li4Mn5O12System
journal, May 1996
- Masquelier, Christian; Tabuchi, Mitsuharu; Ado, Kazuaki
- Journal of Solid State Chemistry, Vol. 123, Issue 2
Review of the U.S. Department of Energy’s “Deep Dive” Effort to Understand Voltage Fade in Li- and Mn-Rich Cathodes
journal, October 2015
- Croy, Jason R.; Balasubramanian, Mahalingam; Gallagher, Kevin G.
- Accounts of Chemical Research, Vol. 48, Issue 11
Structural and electrochemical characteristics of a hollandite-type ‘LiξMnO2’
journal, April 1993
- Botkovitz, Ph.; Deniard, Ph.; Tournoux, M.
- Journal of Power Sources, Vol. 44, Issue 1-3
Characterization of Layered Lithium Nickel Manganese Oxides Synthesized by a Novel Oxidative Coprecipitation Method and Their Electrochemical Performance as Lithium Insertion Electrode Materials
journal, January 1998
- Spahr, Michael E.
- Journal of The Electrochemical Society, Vol. 145, Issue 4
Charge, Potential, and Phase Stability of Layered Li(Ni[sub 0.5]Mn[sub 0.5])O[sub 2]
journal, January 2002
- Reed, J.; Ceder, G.
- Electrochemical and Solid-State Letters, Vol. 5, Issue 7
Understanding the Anomalous Capacity of Li / Li [ NixLi ( 1 / 3 − 2x / 3 ) Mn ( 2 / 3 − x / 3 ) ] O2 Cells Using In Situ X-Ray Diffraction and Electrochemical Studies
journal, January 2002
- Lu, Zhonghua; Dahn, J. R.
- Journal of The Electrochemical Society, Vol. 149, Issue 7, p. A815-A822
Li‐ and Mn‐Rich Cathode Materials: Challenges to Commercialization
journal, December 2016
- Zheng, Jianming; Myeong, Seungjun; Cho, Woongrae
- Advanced Energy Materials, Vol. 7, Issue 6
Correlating hysteresis and voltage fade in lithium- and manganese-rich layered transition-metal oxide electrodes
journal, August 2013
- Gallagher, Kevin G.; Croy, Jason R.; Balasubramanian, Mahalingam
- Electrochemistry Communications, Vol. 33
Manganese oxides for lithium batteries
journal, January 1997
- Thackeray, Michael M.
- Progress in Solid State Chemistry, Vol. 25, Issue 1-2
Structural and electrochemical properties of the proton / γ-MnO2 system
journal, January 1995
- Chabre, Y.; Pannetier, J.
- Progress in Solid State Chemistry, Vol. 23, Issue 1
Low-Zinc-Solubility Electrolytes for Use in Zinc/Nickel Oxide Cells
journal, January 1993
- Adler, T. C.
- Journal of The Electrochemical Society, Vol. 140, Issue 2
Vision for Designing High-Energy, Hybrid Li Ion/Li–O 2 Cells
journal, October 2013
- Thackeray, Michael M.; Chan, Maria K. Y.; Trahey, Lynn
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 21
Lithium–manganese–nickel-oxide electrodes with integrated layered–spinel structures for lithium batteries
journal, February 2007
- Park, S.; Kang, S.; Johnson, C.
- Electrochemistry Communications, Vol. 9, Issue 2, p. 262-268
The Electrochemical Stability of Spinel Electrodes Coated with ZrO2, Al2O3, and SiO2 from Colloidal Suspensions
journal, January 2004
- Kim, J.-S.; Johnson, C. S.; Vaughey, J. T.
- Journal of The Electrochemical Society, Vol. 151, Issue 10, p. A1755-A1761
Synthesis, Structure, and Electrochemical Behavior of Li[Ni[sub x]Li[sub 1/3−2x/3]Mn[sub 2/3−x/3]]O[sub 2]
journal, January 2002
- Lu, Zhonghua; Beaulieu, L. Y.; Donaberger, R. A.
- Journal of The Electrochemical Society, Vol. 149, Issue 6
Probing the Release and Uptake of Water in α-MnO 2 · x H 2 O
journal, February 2017
- Yang, Zhenzhen; Ford, Denise C.; Park, Joong Sun
- Chemistry of Materials, Vol. 29, Issue 4
Simulation of First-Charge Oxygen-Dimerization and Mn-Migration in Li-Rich Layered Oxides x Li 2 MnO 3 ·(1 – x )Li M O 2 and Implications for Voltage Fade
journal, March 2017
- Benedek, Roy; Iddir, Hakim
- The Journal of Physical Chemistry C, Vol. 121, Issue 12
Examining Hysteresis in Composite x Li 2 MnO 3 ·(1– x )LiMO 2 Cathode Structures
journal, March 2013
- Croy, Jason R.; Gallagher, Kevin G.; Balasubramanian, Mahalingam
- The Journal of Physical Chemistry C, Vol. 117, Issue 13
Lithium- and Manganese-Rich Oxide Cathode Materials for High-Energy Lithium Ion Batteries
journal, August 2016
- Wang, Jun; He, Xin; Paillard, Elie
- Advanced Energy Materials, Vol. 6, Issue 21
Primary Batteries 1951–1976
journal, January 1978
- Brodd, R. J.
- Journal of The Electrochemical Society, Vol. 125, Issue 7
Electrical Energy Storage and Intercalation Chemistry
journal, June 1976
- Whittingham, M. S.
- Science, Vol. 192, Issue 4244
Lithium insertion into manganese spinels
journal, April 1983
- Thackeray, M. M.; David, W. I. F.; Bruce, P. G.
- Materials Research Bulletin, Vol. 18, Issue 4, p. 461-472
The Secondary Alkaline Zinc Electrode
journal, January 1991
- McLarnon, Frank R.
- Journal of The Electrochemical Society, Vol. 138, Issue 2
Rechargeable Cells with Modified MnO[sub 2] Cathodes
journal, January 1988
- Dzieciuch, M. A.
- Journal of The Electrochemical Society, Vol. 135, Issue 10
Structural and electrochemical studies of α-manganese dioxide (α-MnO2)
journal, October 1997
- Johnson, C. S.; Dees, D. W.; Mansuetto, M. F.
- Journal of Power Sources, Vol. 68, Issue 2
Structural and Electrochemical Studies of 3 V Li[sub x]MnO[sub 2] Cathodes for Rechargeable Li Batteries
journal, January 1997
- Levi, E.
- Journal of The Electrochemical Society, Vol. 144, Issue 12
Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries
journal, January 2007
- Thackeray, Michael M.; Kang, Sun-Ho; Johnson, Christopher S.
- Journal of Materials Chemistry, Vol. 17, Issue 30, p. 3112-3125
Cathode materials modified by surface coating for lithium ion batteries
journal, May 2006
- Li, C.; Zhang, H. P.; Fu, L. J.
- Electrochimica Acta, Vol. 51, Issue 19
The electrochemical preparation and properties of ionic alkali metal-and NR4-graphite intercalation compounds in organic electrolytes
journal, January 1976
- Besenhard, J. O.
- Carbon, Vol. 14, Issue 2
Li 2 O Removal from Li 5 FeO 4 : A Cathode Precursor for Lithium-Ion Batteries †
journal, February 2010
- Johnson, C. S.; Kang, S. -H.; Vaughey, J. T.
- Chemistry of Materials, Vol. 22, Issue 3
Remarkably Improved Electrochemical Performance of Li- and Mn-Rich Cathodes upon Substitution of Mn with Ni
journal, September 2016
- Kumar Nayak, Prasant; Grinblat, Judith; Levi, Elena
- ACS Applied Materials & Interfaces, Vol. 9, Issue 5
New intercalation compounds for lithium batteries: layered LiMnO2
journal, January 1999
- Bruce, Peter G.; Armstrong, A. Robert; Gitzendanner, Robert L.
- Journal of Materials Chemistry, Vol. 9, Issue 1
Preparation of a new crystal form of manganese dioxide: λ-MnO2
journal, September 1981
- Hunter, James C.
- Journal of Solid State Chemistry, Vol. 39, Issue 2, p. 142-147
α-MnO2 Nanowires: A Catalyst for the O2 Electrode in Rechargeable Lithium Batteries
journal, June 2008
- Débart, Aurélie; Paterson, Allan J.; Bao, Jianli
- Angewandte Chemie International Edition, Vol. 47, Issue 24, p. 4521-4524
Suppressing Manganese Dissolution from Lithium Manganese Oxide Spinel Cathodes with Single-Layer Graphene
journal, June 2015
- Jaber-Ansari, Laila; Puntambekar, Kanan P.; Kim, Soo
- Advanced Energy Materials, Vol. 5, Issue 17
Synthesis and characterization of lithium aluminum-doped spinel (LiAlxMn2−xO4) for lithium secondary battery
journal, June 2001
- Lee, Yun-Sung; Kumada, Naoki; Yoshio, Masaki
- Journal of Power Sources, Vol. 96, Issue 2
High Performance Li 2 Ru 1– y Mn y O 3 (0.2 ≤ y ≤ 0.8) Cathode Materials for Rechargeable Lithium-Ion Batteries: Their Understanding
journal, March 2013
- Sathiya, M.; Ramesha, K.; Rousse, G.
- Chemistry of Materials, Vol. 25, Issue 7
The cycling properties of the LixNi1−yCoyO2 electrode
journal, April 1993
- Delmas, C.; Saadoune, I.; Rougier, A.
- Journal of Power Sources, Vol. 44, Issue 1-3
Optimized 4-V Spinel Cathode Material with High Energy Density for Li-Ion Cells Operating at 60 °C
journal, August 2013
- Lee, Sanghan; Jeong, Minseul; Cho, Jaephil
- Advanced Energy Materials, Vol. 3, Issue 12
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes
journal, July 2013
- Sathiya, M.; Rousse, G.; Ramesha, K.
- Nature Materials, Vol. 12, Issue 9
Synthesis and Structural Characterization of a Novel Layered Lithium Manganese Oxide, Li0.36Mn0.91O2, and Its Lithiated Derivative, Li1.09Mn0.91O2
journal, June 1993
- Rossouw, M. H.; Liles, D. C.; Thackeray, M. M.
- Journal of Solid State Chemistry, Vol. 104, Issue 2
Advances in Stabilizing ‘Layered-Layered’ xLi2MnO3·(1-x)LiMO2(M=Mn, Ni, Co) Electrodes with a Spinel Component
journal, January 2014
- Long, Brandon R.; Croy, Jason R.; Park, Joong Sun
- Journal of The Electrochemical Society, Vol. 161, Issue 14, p. A2160-A2167
Electrochemical extraction of lithium from LiMn2O4
journal, February 1984
- Thackeray, M. M.; Johnson, P. J.; de Picciotto, L. A.
- Materials Research Bulletin, Vol. 19, Issue 2
Challenges for Rechargeable Li Batteries
journal, February 2010
- Goodenough, John B.; Kim, Youngsik
- Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
First-principles calculation of atomic structure and electrochemical potential of Li1+xV3O8
journal, September 1999
- Benedek, R.; Thackeray, M. M.; Yang, L. H.
- Journal of Power Sources, Vol. 81-82
Revealing the Intrinsic Li Mobility in the Li 2 MnO 3 Lithium-Excess Material
journal, March 2016
- Shin, Yongwoo; Ding, Hong; Persson, Kristin A.
- Chemistry of Materials, Vol. 28, Issue 7
Structural characterization of Li1+xV3O8 insertion electrodes by single-crystal X-ray diffraction
journal, August 1993
- Depicciotto, L.; Adendorff, K.; Liles, D.
- Solid State Ionics, Vol. 62, Issue 3-4
Structural transformation on cycling layered Li(Mn1−yCoy)O2 cathode materials
journal, September 1999
- Armstrong, A. R.; Robertson, A. D.; Bruce, P. G.
- Electrochimica Acta, Vol. 45, Issue 1-2
Prospects for spinel-stabilized, high-capacity lithium-ion battery cathodes
journal, December 2016
- Croy, Jason R.; Park, Joong Sun; Shin, Youngho
- Journal of Power Sources, Vol. 334
Lithium-cobalt-nickel-oxide cathode materials prepared at 400°C for rechargeable lithium batteries
journal, July 1992
- Gummow, R. J.; Thackeray, M. M.
- Solid State Ionics, Vol. 53-56, p. 681-687
Mn(II) deposition on anodes and its effects on capacity fade in spinel lithium manganate–carbon systems
journal, September 2013
- Zhan, Chun; Lu, Jun; Jeremy Kropf, A.
- Nature Communications, Vol. 4, Issue 1
A review of recent developments in the surface modification of LiMn2O4 as cathode material of power lithium-ion battery
journal, August 2009
- Yi, Ting-Feng; Zhu, Yan-Rong; Zhu, Xiao-Dong
- Ionics, Vol. 15, Issue 6
Influence of Cation Ordering and Lattice Distortion on the Charge–Discharge Behavior of LiMn 1.5 Ni 0.5 O 4 Spinel between 5.0 and 2.0 V
journal, September 2012
- Lee, Eun-Sung; Nam, Kyung-Wan; Hu, Enyuan
- Chemistry of Materials, Vol. 24, Issue 18
Al Doping for Mitigating the Capacity Fading and Voltage Decay of Layered Li and Mn-Rich Cathodes for Li-Ion Batteries
journal, February 2016
- Nayak, Prasant Kumar; Grinblat, Judith; Levi, Mikhael
- Advanced Energy Materials, Vol. 6, Issue 8
An overview of the Li(Ni,M)O2 systems: syntheses, structures and properties
journal, September 1999
- Delmas, C.; Ménétrier, M.; Croguennec, L.
- Electrochimica Acta, Vol. 45, Issue 1-2
Long-Range and Local Structure in the Layered Oxide Li 1.2 Co 0.4 Mn 0.4 O 2
journal, April 2011
- Bareño, J.; Balasubramanian, M.; Kang, S. H.
- Chemistry of Materials, Vol. 23, Issue 8
Anionic redox processes for electrochemical devices
journal, January 2016
- Grimaud, A.; Hong, W. T.; Shao-Horn, Y.
- Nature Materials, Vol. 15, Issue 2
Spinel Electrodes from the Li-Mn-O System for Rechargeable Lithium Battery Applications
journal, January 1992
- Thackeray, M. M.
- Journal of The Electrochemical Society, Vol. 139, Issue 2
New Lithium Metal Polymer Solid State Battery for an Ultrahigh Energy: Nano C-LiFePO 4 versus Nano Li 1.2 V 3 O 8
journal, March 2015
- Hovington, P.; Lagacé, M.; Guerfi, A.
- Nano Letters, Vol. 15, Issue 4
Characterization of Li1+yNixCo1−2xMnxO2 positive active materials for lithium ion batteries
journal, August 2005
- Shizuka, Kenji; Kobayashi, Takako; Okahara, Kenji
- Journal of Power Sources, Vol. 146, Issue 1-2
High capacity double-layer surface modified Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode with improved rate capability
journal, January 2009
- Wang, Q. Y.; Liu, J.; Murugan, A. Vadivel
- Journal of Materials Chemistry, Vol. 19, Issue 28
Surface modification of LiNi0.5Mn1.5O4 by ZrP2O7 and ZrO2 for lithium-ion batteries
journal, May 2010
- Wu, H. M.; Belharouak, I.; Abouimrane, A.
- Journal of Power Sources, Vol. 195, Issue 9
Local Structure and First Cycle Redox Mechanism of Layered Li[sub 1.2]Cr[sub 0.4]Mn[sub 0.4]O[sub 2] Cathode Material
journal, January 2002
- Ammundsen, Brett; Paulsen, Jens; Davidson, Isobel
- Journal of The Electrochemical Society, Vol. 149, Issue 4
Stability of Li- and Mn-Rich Layered-Oxide Cathodes within the First-Charge Voltage Plateau
journal, January 2016
- Iddir, Hakim; Bareño, Javier; Benedek, Roy
- Journal of The Electrochemical Society, Vol. 163, Issue 8
The significance of the Li2MnO3 component in ‘composite’ xLi2MnO3·(1−x)LiMn0.5Ni0.5O2 electrodes
journal, October 2004
- Johnson, C. S.; Kim, J-S.; Lefief, C.
- Electrochemistry Communications, Vol. 6, Issue 10, p. 1085-1091
Lithium insertion into βMnO2 and the rutile-spinel transformation
journal, January 1984
- David, W. I. F.; Thackeray, M. M.; Bruce, P. G.
- Materials Research Bulletin, Vol. 19, Issue 1
Manganese oxide minerals: Crystal structures and economic and environmental significance
journal, March 1999
- Post, J. E.
- Proceedings of the National Academy of Sciences, Vol. 96, Issue 7
Structural and Chemical Evolution of the Layered Li-Excess Li x MnO 3 as a Function of Li Content from First-Principles Calculations
journal, June 2014
- Lee, Eunseok; Persson, Kristin A.
- Advanced Energy Materials, Vol. 4, Issue 15
Structure and electrochemistry of LixMnyNi1−yO2
journal, October 1992
- Rossen, E.; Jones, C.; Dahn, J.
- Solid State Ionics, Vol. 57, Issue 3-4
Structure and electrochemistry of lithium cobalt oxide synthesised at 400°C
journal, March 1992
- Gummow, R. J.; Thackeray, M. M.; David, W. I. F.
- Materials Research Bulletin, Vol. 27, Issue 3, p. 327-337
Effect of Structure on the Fe[sup 3+]∕Fe[sup 2+] Redox Couple in Iron Phosphates
journal, January 1997
- Padhi, A. K.
- Journal of The Electrochemical Society, Vol. 144, Issue 5
Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries
journal, December 2015
- McCalla, E.; Abakumov, A. M.; Saubanere, M.
- Science, Vol. 350, Issue 6267
The versatility of MnO2 for lithium battery applications
journal, March 1993
- Thackeray, M. M.; Rossouw, M. H.; de Kock, A.
- Journal of Power Sources, Vol. 43, Issue 1-3
Electrochemical and In Situ X‐Ray Diffraction Studies of Lithium Intercalation in LixCoO2
journal, January 1992
- Reimers, Jan N.; Dahn, J. R.
- Journal of The Electrochemical Society, Vol. 139, Issue 8, p. 2091-2097
Studies of Spinel-to-Layered Structural Transformations in LiMn 2 O 4 Electrodes Charged to High Voltages
journal, April 2017
- Leifer, Nicole; Schipper, Florian; Erickson, Evan M.
- The Journal of Physical Chemistry C, Vol. 121, Issue 17
Lithium metal rechargeable cells using Li2MnO3 as the positive electrode
journal, July 1999
- Kalyani, P.; Chitra, S.; Mohan, T.
- Journal of Power Sources, Vol. 80, Issue 1-2
Alternate synthesis and reflectivity spectrum of stage 1 lithium—graphite intercalation compound
journal, January 1978
- Zanini, M.; Basu, S.; Fischer, J. E.
- Carbon, Vol. 16, Issue 3
Solid solutions Li1+xV3O8 as cathodes for high rate secondary Li batteries
journal, August 1984
- Pistoia, G.
- Solid State Ionics, Vol. 13, Issue 4
Electrochemical characterization of a new high capacity cathode
journal, July 2001
- Storey, C.; Kargina, I.; Grincourt, Y.
- Journal of Power Sources, Vol. 97-98
The Manganese Dioxide Electrode
journal, January 1959
- Vosburgh, W. C.
- Journal of The Electrochemical Society, Vol. 106, Issue 9
Lithium and Deuterium NMR Studies of Acid-Leached Layered Lithium Manganese Oxides
journal, December 2002
- Paik, Younkee; Grey, Clare P.; Johnson, Christopher S.
- Chemistry of Materials, Vol. 14, Issue 12
Enhancing the rate capability of high capacity xLi2MnO3 · (1−x)LiMO2 (M=Mn, Ni, Co) electrodes by Li–Ni–PO4 treatment
journal, April 2009
- Kang, Sun-Ho; Thackeray, Michael M.
- Electrochemistry Communications, Vol. 11, Issue 4, p. 748-751
The rechargeability of manganese dioxide in alkaline electrolyte
journal, October 1981
- Kordesch, K.; Gsellmann, J.; Peri, M.
- Electrochimica Acta, Vol. 26, Issue 10
Synthesis, Thermal, and Electrochemical Properties of AlPO[sub 4]-Coated LiNi[sub 0.8]Co[sub 0.1]Mn[sub 0.1]O[sub 2] Cathode Materials for a Li-Ion Cell
journal, January 2004
- Cho, Jaephil; Kim, Tae-Joon; Kim, Jisuk
- Journal of The Electrochemical Society, Vol. 151, Issue 11
Physical and electrochemical properties of spherical Li1+x(Ni1/3Co1/3Mn1/3)1−xO2 cathode materials
journal, February 2008
- Park, S. -H.; Kang, S. -H.; Belharouak, I.
- Journal of Power Sources, Vol. 177, Issue 1
Synthesis and electrochemistry of spinel LTLiCoO2
journal, July 1993
- Rossen, E.; Reimers, J.; Dahn, J.
- Solid State Ionics, Vol. 62, Issue 1-2
Nanostructured high-energy cathode materials for advanced lithium batteries
journal, October 2012
- Sun, Yang-Kook; Chen, Zonghai; Noh, Hyung-Joo
- Nature Materials, Vol. 11, Issue 11
A New Three‐Volt Spinel Li1 + xMn1.5Ni0.5 O 4 for Secondary Lithium Batteries
journal, January 1996
- Amine, K.; Tukamoto, H.; Yasuda, H.
- Journal of The Electrochemical Society, Vol. 143, Issue 5, p. 1607-1613
Electrochemical and Structural Properties of xLi2M‘O3 ·(1− x )LiMn0.5Ni0.5O2 Electrodes for Lithium Batteries (M‘ = Ti, Mn, Zr; 0 ≤ x ⩽ 0.3)
journal, May 2004
- Kim, Jeom-Soo; Johnson, Christopher S.; Vaughey, John T.
- Chemistry of Materials, Vol. 16, Issue 10, p. 1996-2006
First-Principles Analysis of Phase Stability in Layered–Layered Composite Cathodes for Lithium-Ion Batteries
journal, March 2014
- Iddir, Hakim; Benedek, Roy
- Chemistry of Materials, Vol. 26, Issue 7
Electrochemical characteristics of Al2O3-coated lithium manganese spinel as a cathode material for a lithium secondary battery
journal, February 2004
- Lee, Seung-Won; Kim, Kwang-Soo; Moon, Hee-Soo
- Journal of Power Sources, Vol. 126, Issue 1-2
Chemistry of intercalation compounds: Metal guests in chalcogenide hosts
journal, January 1978
- Whittingham, M. Stanley
- Progress in Solid State Chemistry, Vol. 12, Issue 1
Layered Li x Mn 1- y Co y O 2 Intercalation ElectrodesInfluence of Ion Exchange on Capacity and Structure upon Cycling
journal, July 2001
- Robertson, Alastair D.; Armstrong, A. Robert; Bruce, Peter G.
- Chemistry of Materials, Vol. 13, Issue 7
Alpha manganese dioxide for lithium batteries: A structural and electrochemical study
journal, February 1992
- Rossouw, M. H.; Liles, D. C.; Thackeray, Mm
- Materials Research Bulletin, Vol. 27, Issue 2
Manganese oxides for a lithium secondary battery — composite dimensional manganese oxide (CDMO)
journal, May 1989
- Nohma, T.; Saito, T.; Furukawa, N.
- Journal of Power Sources, Vol. 26, Issue 3-4
Lithium extraction from orthorhombic lithium manganese oxide and the phase transformation to spinel
journal, December 1993
- Gummow, R. J.; Liles, Dc; Thackeray, Mm
- Materials Research Bulletin, Vol. 28, Issue 12
A review of blended cathode materials for use in Li-ion batteries
journal, February 2014
- Chikkannanavar, Satishkumar B.; Bernardi, Dawn M.; Liu, Lingyun
- Journal of Power Sources, Vol. 248
The Spinel Phase of LiMn[sub 2]O[sub 4] as a Cathode in Secondary Lithium Cells
journal, January 1991
- Tarascon, J. M.
- Journal of The Electrochemical Society, Vol. 138, Issue 10
Li Metal-Free Rechargeable Batteries Based on Li[sub 1+x]Mn[sub 2]O[sub 4] Cathodes (0 ≤ x ≤ 1) and Carbon Anodes
journal, January 1991
- Tarascon, J. M.
- Journal of The Electrochemical Society, Vol. 138, Issue 10
Anomalous capacity and cycling stability of xLi2MnO3·(1−x)LiMO2 electrodes (M=Mn, Ni, Co) in lithium batteries at 50°C
journal, April 2007
- Johnson, Christopher S.; Li, Naichao; Lefief, Christina
- Electrochemistry Communications, Vol. 9, Issue 4, p. 787-795
Role of Chemical and Structural Stabilities on the Electrochemical Properties of Layered LiNi[sub 1∕3]Mn[sub 1∕3]Co[sub 1∕3]O[sub 2] Cathodes
journal, January 2005
- Choi, J.; Manthiram, A.
- Journal of The Electrochemical Society, Vol. 152, Issue 9
Role of Electronic Structure in the Susceptibility of Metastable Transition-Metal Oxide Structures to Transformation
journal, October 2004
- Reed, John; Ceder, Gerbrand
- Chemical Reviews, Vol. 104, Issue 10
Functional surface modifications of a high capacity layered Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode
journal, January 2010
- Liu, Jun; Manthiram, Arumugam
- Journal of Materials Chemistry, Vol. 20, Issue 19
Effect of Cooling Rates on Phase Separation in 0.5Li 2 MnO 3 ·0.5LiCoO 2 Electrode Materials for Li-Ion Batteries
journal, May 2014
- Long, Brandon R.; Croy, Jason R.; Dogan, Fulya
- Chemistry of Materials, Vol. 26, Issue 11
Spinel versus layered structures for lithium cobalt oxide synthesised at 400°C
journal, March 1993
- Gummow, R. J.; Liles, D. C.; Thackeray, M. M.
- Materials Research Bulletin, Vol. 28, Issue 3, p. 235-246
Atomic Structure of a Lithium-Rich Layered Oxide Material for Lithium-Ion Batteries: Evidence of a Solid Solution
journal, August 2011
- Jarvis, Karalee A.; Deng, Zengqiang; Allard, Lawrence F.
- Chemistry of Materials, Vol. 23, Issue 16
Electrical energy storage for transportation—approaching the limits of, and going beyond, lithium-ion batteries
journal, January 2012
- Thackeray, Michael M.; Wolverton, Christopher; Isaacs, Eric D.
- Energy & Environmental Science, Vol. 5, Issue 7
Lithium manganese oxides from Li2MnO3 for rechargeable lithium battery applications
journal, June 1991
- Rossouw, Mh; Thackeray, Mm
- Materials Research Bulletin, Vol. 26, Issue 6
In situ high-energy synchrotron X-ray diffraction studies and first principles modeling of α-MnO 2 electrodes in Li–O 2 and Li-ion coin cells
journal, January 2015
- Yang, Zhenzhen; Trahey, Lynn; Ren, Yang
- Journal of Materials Chemistry A, Vol. 3, Issue 14
Electrochemistry of Manganese Dioxide in Lithium Nonaqueous Cell
journal, January 1990
- Ohzuku, Tsutomu
- Journal of The Electrochemical Society, Vol. 137, Issue 3
Enabling the high capacity of lithium-rich anti-fluorite lithium iron oxide by simultaneous anionic and cationic redox
journal, December 2017
- Zhan, Chun; Yao, Zhenpeng; Lu, Jun
- Nature Energy, Vol. 2, Issue 12
LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density
journal, June 1980
- Mizushima, K.; Jones, P. C.; Wiseman, P. J.
- Materials Research Bulletin, Vol. 15, Issue 6
A perspective on nickel-rich layered oxide cathodes for lithium-ion batteries
journal, January 2017
- Manthiram, Arumugam; Song, Bohang; Li, Wangda
- Energy Storage Materials, Vol. 6
Review—SEI: Past, Present and Future
journal, January 2017
- Peled, E.; Menkin, S.
- Journal of The Electrochemical Society, Vol. 164, Issue 7
Understanding the Second Electron Discharge Plateau in MnO[sub 2]-Based Alkaline Cells
journal, January 2001
- Patrice, R.; Gérand, B.; Leriche, J. B.
- Journal of The Electrochemical Society, Vol. 148, Issue 5
Preparation of Plate-Form Manganese Oxide by Selective Lithium Extraction from Monoclinic Li 2 MnO 3 under Hydrothermal Conditions
journal, November 2000
- Tang, Weiping; Kanoh, Hirofumi; Yang, Xiaojing
- Chemistry of Materials, Vol. 12, Issue 11