Sequential Transformation of Zirconium(IV)‐MOFs into Heterobimetallic MOFs Bearing Magnetic Anisotropic Cobalt(II) Centers

Yuan, Shuai; Qin, Jun‐Sheng; Su, Jian; Li, Bao; Li, Jialuo; Chen, Wenmiao; Drake, Hannah F.; Zhang, Peng; Yuan, Daqiang; Zuo, Jinglin; Zhou, Hong‐Cai

doi:10.1002/anie.201808568

Title: Sequential Transformation of Zirconium(IV)‐MOFs into Heterobimetallic MOFs Bearing Magnetic Anisotropic Cobalt(II) Centers

Journal Article · Mon Aug 27 00:00:00 EDT 2018 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201808568· OSTI ID:1467128

Yuan, Shuai ^[1]; Qin, Jun‐Sheng ^[1]; Su, Jian ^[2]; Li, Bao ^[1]; Li, Jialuo ^[1]; Chen, Wenmiao ^[1]; Drake, Hannah F. ^[1]; Zhang, Peng ^[1]; Yuan, Daqiang ^[3]; Zuo, Jinglin ^[2];

^[4]

Department of Chemistry Texas A&,M University College Station TX 77843 USA
State Key Laboratory of Coordination Chemistry School of Chemistry and Chemical Engineering Collaborative Innovation Center of Advanced Microstructures Nanjing University Nanjing 210093 P. R. China
State Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou Fujian 350002 P. R. China
Department of Chemistry Texas A&,M University College Station TX 77843 USA, Department of Materials Science and Engineering Texas A&,M University College Station TX 77840 USA

Abstract Heterometallic metal–organic frameworks (MOFs) allow the precise placement of various metals at atomic precision within a porous framework. This new level of control by MOFs promises fascinating advances in basic science and application. However, the rational design and synthesis of heterometallic MOFs remains a challenge due to the complexity of the heterometallic systems. Herein, we show that bimetallic MOFs with MX ₂ (INA) ₄ moieties (INA=isonicotinate; M=Co ²⁺ or Fe ²⁺ ; X=OH ⁻ , Cl ⁻ , Br ⁻ , I ⁻ , NCS ⁻ , or NCSe ⁻ ) can be generated by the sequential modification of a Zr‐based MOF. This multi‐step modification not only replaced the linear organic linker with a square planar MX ₂ (INA) ₄ unit, but also altered the symmetry, unit cell, and topology of the parent structure. Single‐crystal to single‐crystal transformation is realized so that snapshots for transition process were captured by successive single‐crystal X‐ray diffraction. Furthermore, the installation of Co(NCS) ₂ (INA) ₄ endows field‐induced slow magnetic relaxation property to the diamagnetic Zr‐MOF.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0001015; FE0026472

OSTI ID:: 1467128

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Vol. 57 Journal Issue: 38; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 61 works

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