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Title: Calendar and Cycle Life of Lithium-Ion Batteries Containing Silicon Monoxide Anode

Abstract

The capacity fading phenomenon of high energy lithium-ion batteries (LIBs) using a silicon monoxide (SiO) anode and a nickel-rich transition metal oxide cathode were investigated during life test. The capacity loss of this electrode couple was found to increase not only with cycles (cycle life), but also with rest time (calendar life). The capacity fading rate for this type of LIB using SiO as the anode is found to be time-dependent, rather than cycle-count-dependent. Further detailed investigation reveals that the capacity loss of this electrode couple during rest was caused by the parasitic reactions on the anode, which consumed the lithium ions and lead to less cyclable lithium in the battery system.

Authors:
ORCiD logo; ORCiD logo; ; ORCiD logo
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE) - Office of Vehicle Technology
OSTI Identifier:
1466680
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article
Journal Name:
Journal of the Electrochemical Society
Additional Journal Information:
Journal Volume: 165; Journal Issue: 10; Journal ID: ISSN 0013-4651
Publisher:
The Electrochemical Society
Country of Publication:
United States
Language:
English
Subject:
calendar life; cycle life; lithium nickel cobalt manganese oxide; lithium-ion battery; silicon monoxide

Citation Formats

Lu, Wenquan, Zhang, Linghong, Qin, Yan, and Jansen, Andrew. Calendar and Cycle Life of Lithium-Ion Batteries Containing Silicon Monoxide Anode. United States: N. p., 2018. Web. doi:10.1149/2.0631810jes.
Lu, Wenquan, Zhang, Linghong, Qin, Yan, & Jansen, Andrew. Calendar and Cycle Life of Lithium-Ion Batteries Containing Silicon Monoxide Anode. United States. doi:10.1149/2.0631810jes.
Lu, Wenquan, Zhang, Linghong, Qin, Yan, and Jansen, Andrew. Mon . "Calendar and Cycle Life of Lithium-Ion Batteries Containing Silicon Monoxide Anode". United States. doi:10.1149/2.0631810jes.
@article{osti_1466680,
title = {Calendar and Cycle Life of Lithium-Ion Batteries Containing Silicon Monoxide Anode},
author = {Lu, Wenquan and Zhang, Linghong and Qin, Yan and Jansen, Andrew},
abstractNote = {The capacity fading phenomenon of high energy lithium-ion batteries (LIBs) using a silicon monoxide (SiO) anode and a nickel-rich transition metal oxide cathode were investigated during life test. The capacity loss of this electrode couple was found to increase not only with cycles (cycle life), but also with rest time (calendar life). The capacity fading rate for this type of LIB using SiO as the anode is found to be time-dependent, rather than cycle-count-dependent. Further detailed investigation reveals that the capacity loss of this electrode couple during rest was caused by the parasitic reactions on the anode, which consumed the lithium ions and lead to less cyclable lithium in the battery system.},
doi = {10.1149/2.0631810jes},
journal = {Journal of the Electrochemical Society},
issn = {0013-4651},
number = 10,
volume = 165,
place = {United States},
year = {2018},
month = {1}
}

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