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Title: Hydrodeoxygenation of biomass-derived oxygenates over metal carbides: from model surfaces to powder catalysts

Abstract

The hydrodeoxygenation (HDO) reaction is critical to the upgrading of lignocellulosic biomass into valuable fuels and chemicals. Many transition metal carbide (TMC) catalysts have been shown to be highly selective toward the C-O/C=O bond scission, which makes them promising catalysts for the HDO reaction. This review summarizes the reaction pathways of linear and ring-containing biomass-derived oxygenates over TMC model surfaces and powder catalysts, followed by a discussion on the effect of reaction conditions on reaction pathways. The combination of first principle calculations, model surface experiments, and parallel reactor studies demonstrates the feasibility of using model surface science studies to guide the rational design of efficient catalysts for the upgrading of lignocellulosic biomass derivatives. General trends and future research directions of using TMC catalysts for HDO are also discussed.

Authors:
 [1];  [2];  [3]; ORCiD logo [4]
  1. Columbia Univ., New York, NY (United States)
  2. Columbia Univ., New York, NY (United States); Nankai Univ., Tianjin (China)
  3. Columbia Univ., New York, NY (United States); Dalian Univ. of Technology, Dalian (China)
  4. Brookhaven National Lab. (BNL), Upton, NY (United States); Columbia Univ., New York, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1466618
Alternate Identifier(s):
OSTI ID: 1439121
Report Number(s):
BNL-207968-2018-JAAM
Journal ID: ISSN 1463-9262; GRCHFJ
Grant/Contract Number:  
SC0012704; SC0001004
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Green Chemistry
Additional Journal Information:
Journal Volume: 20; Journal Issue: 12; Journal ID: ISSN 1463-9262
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY

Citation Formats

Lin, Zhexi, Chen, Rui, Qu, Zhenping, and Chen, Jingguang G. Hydrodeoxygenation of biomass-derived oxygenates over metal carbides: from model surfaces to powder catalysts. United States: N. p., 2018. Web. doi:10.1039/C8GC00239H.
Lin, Zhexi, Chen, Rui, Qu, Zhenping, & Chen, Jingguang G. Hydrodeoxygenation of biomass-derived oxygenates over metal carbides: from model surfaces to powder catalysts. United States. doi:10.1039/C8GC00239H.
Lin, Zhexi, Chen, Rui, Qu, Zhenping, and Chen, Jingguang G. Wed . "Hydrodeoxygenation of biomass-derived oxygenates over metal carbides: from model surfaces to powder catalysts". United States. doi:10.1039/C8GC00239H.
@article{osti_1466618,
title = {Hydrodeoxygenation of biomass-derived oxygenates over metal carbides: from model surfaces to powder catalysts},
author = {Lin, Zhexi and Chen, Rui and Qu, Zhenping and Chen, Jingguang G.},
abstractNote = {The hydrodeoxygenation (HDO) reaction is critical to the upgrading of lignocellulosic biomass into valuable fuels and chemicals. Many transition metal carbide (TMC) catalysts have been shown to be highly selective toward the C-O/C=O bond scission, which makes them promising catalysts for the HDO reaction. This review summarizes the reaction pathways of linear and ring-containing biomass-derived oxygenates over TMC model surfaces and powder catalysts, followed by a discussion on the effect of reaction conditions on reaction pathways. The combination of first principle calculations, model surface experiments, and parallel reactor studies demonstrates the feasibility of using model surface science studies to guide the rational design of efficient catalysts for the upgrading of lignocellulosic biomass derivatives. General trends and future research directions of using TMC catalysts for HDO are also discussed.},
doi = {10.1039/C8GC00239H},
journal = {Green Chemistry},
number = 12,
volume = 20,
place = {United States},
year = {Wed May 16 00:00:00 EDT 2018},
month = {Wed May 16 00:00:00 EDT 2018}
}

Journal Article:
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Works referenced in this record:

Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering
journal, September 2006

  • Huber, George W.; Iborra, Sara; Corma, Avelino
  • Chemical Reviews, Vol. 106, Issue 9, p. 4044-4098
  • DOI: 10.1021/cr068360d

Catalytic Activities of NiMo Carbide Supported on SiO2 for the Hydrodeoxygenation of Ethyl Benzoate, Acetone, and Acetaldehyde
journal, March 2010

  • Zhang, Wei; Zhang, Ye; Zhao, Liangfu
  • Energy & Fuels, Vol. 24, Issue 3, p. 2052-2059
  • DOI: 10.1021/ef901222z

Synergies between Bio- and Oil Refineries for the Production of Fuels from Biomass
journal, September 2007

  • Huber, George W.; Corma, Avelino
  • Angewandte Chemie International Edition, Vol. 46, Issue 38, p. 7184-7201
  • DOI: 10.1002/anie.200604504

Liquid-Phase Catalytic Processing of Biomass-Derived Oxygenated Hydrocarbons to Fuels and Chemicals
journal, September 2007

  • Chheda, Juben N.; Huber, George W.; Dumesic, James A.
  • Angewandte Chemie International Edition, Vol. 46, Issue 38, p. 7164-7183
  • DOI: 10.1002/anie.200604274

Carbon-Supported Molybdenum Carbide Catalysts for the Conversion of Vegetable Oils
journal, February 2012

  • Han, Junxing; Duan, Jinzhao; Chen, Ping
  • ChemSusChem, Vol. 5, Issue 4, p. 727-733
  • DOI: 10.1002/cssc.201100476

Preparation and olefin-metathesis activity of cyclopentylidene-oxo initiator sites on a molybdenum carbide surface
journal, December 2006

  • Siaj, Mohamed; Temprano, Israel; Dubuc, Nathalie
  • Journal of Organometallic Chemistry, Vol. 691, Issue 24-25, p. 5497-5504
  • DOI: 10.1016/j.jorganchem.2006.09.033