Stability of Fe,Al-bearing bridgmanite in the lower mantle and synthesis of pure Fe-bridgmanite

Ismailova, Leyla; Bykova, Elena; Bykov, Maxim; Cerantola, Valerio; McCammon, Catherine; Ballaran, Tiziana Boffa; Bobrov, Andrei; Sinmyo, Ryosuke; Dubrovinskaia, Natalia; Glazyrin, Konstantin; Liermann, Hanns-Peter; Kupenko, Ilya; Hanfland, Michael; Prescher, Clemens; Prakapenka, Vitali; Svitlyk, Volodymyr; Dubrovinsky, Leonid

doi:10.1126/sciadv.1600427

Title: Stability of Fe,Al-bearing bridgmanite in the lower mantle and synthesis of pure Fe-bridgmanite

Journal Article · Fri Jul 15 00:00:00 EDT 2016 · Science Advances

DOI:https://doi.org/10.1126/sciadv.1600427· OSTI ID:1466581

Ismailova, Leyla ^[1]; Bykova, Elena ^[2]; Bykov, Maxim ^[2]; Cerantola, Valerio ^[3]; McCammon, Catherine ^[2]; Ballaran, Tiziana Boffa ^[2]; Bobrov, Andrei ^[4]; Sinmyo, Ryosuke ^[2]; Dubrovinskaia, Natalia ^[5]; Glazyrin, Konstantin ^[6]; Liermann, Hanns-Peter ^[6]; Kupenko, Ilya ^[7]; Hanfland, Michael ^[8]; Prescher, Clemens ^[9]; Prakapenka, Vitali ^[9]; Svitlyk, Volodymyr ^[8]; Dubrovinsky, Leonid ^[2]

Univ. of Bayreuth (Germany). Bayerisches Geoinstitut, and Lab. of Crystallography
Univ. of Bayreuth (Germany). Bayerisches Geoinstitut
Univ. of Bayreuth (Germany). Bayerisches Geoinstitut; European Synchrotron Radiation Facility (ESRF), Grenoble (France)
Moscow State Univ., Moscow (Russian Federation). Dept. of Petrology, Geological Faculty
Univ. of Bayreuth (Germany). Lab. of Crystallography
Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany). Photon Science
Univ. of Bayreuth (Germany). Bayerisches Geoinstitut; European Synchrotron Radiation Facility (ESRF), Grenoble (France); Univ. of Munster, Munster (Germany). Institut für Mineralogie
Univ. of Munster, Munster (Germany). Institut für Mineralogie
Univ. of Chicago, IL (United States). Center for Advanced Radiation Sources

The physical and chemical properties of Earth’s mantle, as well as its dynamics and evolution, heavily depend on the phase composition of the region. Here, on the basis of experiments in laser-heated diamond anvil cells, we demonstrate that Fe,Al-bearing bridgmanite (magnesium silicate perovskite) is stable to pressures over 120 GPa and temperatures above 3000 K. Ferric iron stabilizes Fe-rich bridgmanite such that we were able to synthesize pure iron bridgmanite at pressures between ~45 and 110 GPa. The compressibility of ferric iron–bearing bridgmanite is significantly different from any known bridgmanite, which has direct implications for the interpretation of seismic tomography data.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Univ. of Chicago, IL (United States)

Sponsoring Organization:: USDOE; Federal Ministry of Education and Research (BMBF) Germany; German Research Foundation (DFG)

Grant/Contract Number:: FG02-94ER14466; AC02-06CH11357

OSTI ID:: 1466581

Journal Information:: Science Advances, Vol. 2, Issue 7; ISSN 2375-2548

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 24 works

Citation information provided by
Web of Science

References (43)

Discovery of bridgmanite, the most abundant mineral in Earth, in a shocked meteorite Tschauner, Oliver; Ma, Chi; Beckett, John R. Science, Vol. 346, Issue 6213 https://doi.org/10.1126/science.1259369	journal	November 2014
A perovskitic lower mantle inferred from high-pressure, high-temperature sound velocity data Murakami, Motohiko; Ohishi, Yasuo; Hirao, Naohisa Nature, Vol. 485, Issue 7396 https://doi.org/10.1038/nature11004	journal	May 2012
Post-oxide phases of olivine and pyroxene and mineralogy of the mantle Liu, Lin-Gun Nature, Vol. 258, Issue 5535 https://doi.org/10.1038/258510a0	journal	December 1975
Stability and Structure of MgSiO3 Perovskite to 2300-Kilometer Depth in Earth's Mantle Shim, S. -H. Science, Vol. 293, Issue 5539 https://doi.org/10.1126/science.1061235	journal	September 2001
Post-Perovskite Phase Transition in MgSiO3 Murakami, M. Science, Vol. 304, Issue 5672 https://doi.org/10.1126/science.1095932	journal	May 2004
Stability of Perovskite (MgSiO3) in the Earth's Mantle Saxena, S. K.; Dubrovinsky, L. S.; Lazor, P. Science, Vol. 274, Issue 5291 https://doi.org/10.1126/science.274.5291.1357	journal	November 1996
Disproportionation of (Mg,Fe)SiO3 perovskite in Earth's deep lower mantle Zhang, L.; Meng, Y.; Yang, W. Science, Vol. 344, Issue 6186 https://doi.org/10.1126/science.1250274	journal	May 2014
Synchrotron radiation and laser heating in a diamond anvil cell Andrault, Denis; Fiquet, Guillaume Review of Scientific Instruments, Vol. 72, Issue 2 https://doi.org/10.1063/1.1343866	journal	January 2001
Synthesis and equation of state of perovskites in the (Mg, Fe)3Al2Si3O12 system to 177GPa Dorfman, Susannah M.; Shieh, Sean R.; Meng, Yue Earth and Planetary Science Letters, Vol. 357-358 https://doi.org/10.1016/j.epsl.2012.09.024	journal	December 2012
Magnesium silicate perovskite and effect of iron oxidation state on its bulk sound velocity at the conditions of the lower mantle Glazyrin, K.; Boffa Ballaran, T.; Frost, D. J. Earth and Planetary Science Letters, Vol. 393 https://doi.org/10.1016/j.epsl.2014.01.056	journal	May 2014
The thermal equation of state of (Mg, Fe)SiO ₃ bridgmanite (perovskite) and implications for lower mantle structures : FE BRIDGMANITE EOS AND MANTLE STRUCTURES Wolf, Aaron S.; Jackson, Jennifer M.; Dera, Przemeslaw Journal of Geophysical Research: Solid Earth, Vol. 120, Issue 11 https://doi.org/10.1002/2015JB012108	journal	November 2015
Prediction of a potential high-pressure structure of ${FeSiO}_{3}$ Cohen, R. E.; Lin, Yangzheng Physical Review B, Vol. 90, Issue 14 https://doi.org/10.1103/PhysRevB.90.140102	journal	October 2014
Electronic spin state of Fe,Al-containing MgSiO3 perovskite at lower mantle conditions Kupenko, I.; McCammon, C.; Sinmyo, R. Lithos, Vol. 189 https://doi.org/10.1016/j.lithos.2013.10.022	journal	February 2014
High-brilliance X-ray system for high-pressure in-house research: applications for studies of superhard materials Dubrovinsky, L.; Dubrovinskaia, N.; Kantor, I. High Pressure Research, Vol. 26, Issue 2 https://doi.org/10.1080/08957950600765301	journal	June 2006
Maximum solubility of FeO in (Mg, Fe)SiO ₃ -perovskite as a function of temperature at 26 GPa: Implication for FeO content in the lower mantle Fei, Yingwei; Wang, Yanbin; Finger, Larry W. Journal of Geophysical Research: Solid Earth, Vol. 101, Issue B5 https://doi.org/10.1029/96JB00408	journal	May 1996
Multivariable Dependence of Fe-Mg Partitioning in the Lower Mantle Mao, H. Science, Vol. 278, Issue 5346 https://doi.org/10.1126/science.278.5346.2098	journal	December 1997
Phase relations in the system MgO-FeO-SiO ₂ to 50 GPa and 2000°C: An application of experimental techniques using multianvil apparatus with sintered diamond anvils Tange, Yoshinori; Takahashi, Eiichi; Nishihara, Yu Journal of Geophysical Research, Vol. 114, Issue B2 https://doi.org/10.1029/2008JB005891	journal	January 2009
Effects of Fe-enrichment on the equation of state and stability of (Mg,Fe)SiO3 perovskite Dorfman, Susannah M.; Meng, Yue; Prakapenka, Vitali B. Earth and Planetary Science Letters, Vol. 361 https://doi.org/10.1016/j.epsl.2012.10.033	journal	January 2013
Decomposition of FeSiO3 into FeO + SiO2 under very high pressure and high temperature Ming, L. C.; Bassett, W. A. Earth and Planetary Science Letters, Vol. 25, Issue 1 https://doi.org/10.1016/0012-821X(75)90211-3	journal	January 1975
Stability of the perovskite structure and possibility of the transition to the post-perovskite structure in CaSiO3, FeSiO3, MnSiO3 and CoSiO3 Fujino, Kiyoshi; Nishio-Hamane, Daisuke; Suzuki, Keisuke Physics of the Earth and Planetary Interiors, Vol. 177, Issue 3-4 https://doi.org/10.1016/j.pepi.2009.08.009	journal	December 2009
Oxidation state of the lower mantle: In situ observations of the iron electronic configuration in bridgmanite at extreme conditions Kupenko, I.; McCammon, C.; Sinmyo, R. Earth and Planetary Science Letters, Vol. 423 https://doi.org/10.1016/j.epsl.2015.04.027	journal	August 2015
High-pressure synthesis of skiagite-majorite garnet and investigation of its crystal structure Ismailova, Leyla; Bobrov, Andrey; Bykov, Maxim American Mineralogist, Vol. 100, Issue 11-12 https://doi.org/10.2138/am-2015-5278	journal	November 2015
Discovery of the recoverable high-pressure iron oxide Fe4O5 Lavina, B.; Dera, P.; Kim, E. Proceedings of the National Academy of Sciences, Vol. 108, Issue 42 https://doi.org/10.1073/pnas.1107573108	journal	October 2011
The structure of the metallic high-pressure Fe ₃ O ₄ polymorph: experimental and theoretical study Dubrovinsky, L. S.; Dubrovinskaia, N. A.; McCammon, C. Journal of Physics: Condensed Matter, Vol. 15, Issue 45 https://doi.org/10.1088/0953-8984/15/45/009	journal	October 2003
Structural complexity of simple Fe2O3 at high pressures and temperatures Bykova, E.; Dubrovinsky, L.; Dubrovinskaia, N. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10661	journal	February 2016
Pressure-induced changes in the compression mechanism of aluminous perovskite in the Earth's mantle Brodholt, John P. Nature, Vol. 407, Issue 6804 https://doi.org/10.1038/35036565	journal	October 2000
Origin of Fe 3+ in Fe-containing, Al-free mantle silicate perovskite Xu, Shenzhen; Shim, Sang-Heon; Morgan, Dane Earth and Planetary Science Letters, Vol. 409 https://doi.org/10.1016/j.epsl.2014.11.006	journal	January 2015
Recoil-free fractions of iron in aluminous bridgmanite from temperature-dependent Mössbauer spectra Liu, Jiachao; Mysen, Bjorn; Fei, Yingwei American Mineralogist, Vol. 100, Issue 8-9 https://doi.org/10.2138/am-2015-5245	journal	August 2015
Effect of chemistry on the compressibility of silicate perovskite in the lower mantle Ballaran, Tiziana Boffa; Kurnosov, Alexander; Glazyrin, Konstantin Earth and Planetary Science Letters, Vol. 333-334 https://doi.org/10.1016/j.epsl.2012.03.029	journal	June 2012
The effect of Fe and Al substitution on the compressibility of MgSiO3-perovskite determined through single-crystal X-ray diffraction Saikia, Ashima; Ballaran, Tiziana Boffa; Frost, Daniel J. Physics of the Earth and Planetary Interiors, Vol. 173, Issue 1-2 https://doi.org/10.1016/j.pepi.2008.11.006	journal	March 2009
Effect of Fe-enrichment on seismic properties of perovskite and post-perovskite in the deep lower mantle Dorfman, S. M.; Duffy, T. S. Geophysical Journal International, Vol. 197, Issue 2 https://doi.org/10.1093/gji/ggu045	journal	February 2014
Probabilistic Tomography Maps Chemical Heterogeneities Throughout the Lower Mantle Trampert, J. Science, Vol. 306, Issue 5697 https://doi.org/10.1126/science.1101996	journal	October 2004
Single-crystal X-ray diffraction at megabar pressures and temperatures of thousands of degrees Dubrovinsky, L.; Boffa-Ballaran, T.; Glazyrin, K. High Pressure Research, Vol. 30, Issue 4 https://doi.org/10.1080/08957959.2010.534092	journal	December 2010
BX90: A new diamond anvil cell design for X-ray diffraction and optical measurements Kantor, I.; Prakapenka, V.; Kantor, A. Review of Scientific Instruments, Vol. 83, Issue 12, Article No. 125102 https://doi.org/10.1063/1.4768541	journal	December 2012
Advanced flat top laser heating system for high pressure research at GSECARS: application to the melting behavior of germanium Prakapenka, V. B.; Kubo, A.; Kuznetsov, A. High Pressure Research, Vol. 28, Issue 3 https://doi.org/10.1080/08957950802050718	journal	September 2008
Toward an internally consistent pressure scale Fei, Y.; Ricolleau, A.; Frank, M. Proceedings of the National Academy of Sciences, Vol. 104, Issue 22 https://doi.org/10.1073/pnas.0609013104	journal	May 2007
DIOPTAS : a program for reduction of two-dimensional X-ray diffraction data and data exploration Prescher, Clemens; Prakapenka, Vitali B. High Pressure Research, Vol. 35, Issue 3 https://doi.org/10.1080/08957959.2015.1059835	journal	May 2015
A short history of SHELX Sheldrick, George M. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122 https://doi.org/10.1107/S0108767307043930	journal	December 2007
X-Seed — A Software Tool for Supramolecular Crystallography Barbour, Leonard J. Journal of Supramolecular Chemistry, Vol. 1, Issue 4-6 https://doi.org/10.1016/S1472-7862(02)00030-8	journal	July 2001
EXPGUI , a graphical user interface for GSAS Toby, Brian H. Journal of Applied Crystallography, Vol. 34, Issue 2 https://doi.org/10.1107/S0021889801002242	journal	April 2001
Adiabatic temperature profile in the mantle Katsura, Tomoo; Yoneda, Akira; Yamazaki, Daisuke Physics of the Earth and Planetary Interiors, Vol. 183, Issue 1-2 https://doi.org/10.1016/j.pepi.2010.07.001	journal	November 2010
Reinvestigation of the MgSiO3 perovskite structure at high pressure Sugahara, M.; Yoshiasa, A.; Komatsu, Y. American Mineralogist, Vol. 91, Issue 4 https://doi.org/10.2138/am.2006.1980	journal	April 2006
Evaluation of (Mg,Fe) partitioning between silicate perovskite and magnesiowustite up to 120 GPa and 2300 K Andrault, Denis Journal of Geophysical Research: Solid Earth, Vol. 106, Issue B2 https://doi.org/10.1029/2000jb900362	journal	February 2001

Cited By (3)

Valence and spin states of iron are invisible in Earth’s lower mantle Liu, Jiachao; Dorfman, Susannah M.; Zhu, Feng Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03671-5	journal	March 2018
Implementation and application of the peak scaling method for temperature measurement in the laser heated diamond anvil cell Kunz, Martin; Yan, Jinyuan; Cornell, Earl Review of Scientific Instruments, Vol. 89, Issue 8 https://doi.org/10.1063/1.5028276	journal	August 2018
High-pressure single-crystal X-ray diffraction and synchrotron Mössbauer study of monoclinic ferrosilite Solomatova, Natalia V.; Alieva, Ayya; Finkelstein, Gregory J. Comptes Rendus Geoscience, Vol. 351, Issue 2-3 https://doi.org/10.1016/j.crte.2018.06.012	journal	February 2019

Similar Records

The thermal equation of state of (Mg, Fe)SiO₃ bridgmanite (perovskite) and implications for lower mantle structures

Journal Article · Tue Sep 29 00:00:00 EDT 2015 · Journal of Geophysical Research. Solid Earth · OSTI ID:1466581

Wolf, Aaron S.; Jackson, Jennifer M.; Dera, Przemeslaw; +1 more

Abnormal Elasticity of Fe-Bearing Bridgmanite in the Earth's Lower Mantle

Journal Article · Tue May 08 00:00:00 EDT 2018 · Geophysical Research Letters · OSTI ID:1466581

Fu, Suyu; Yang, Jing; Zhang, Yanyao; +5 more

The Role of Redox on Bridgmanite Crystal Chemistry and Calcium Speciation in the Lower Mantle

Journal Article · Wed Sep 30 00:00:00 EDT 2020 · Journal of Geophysical Research. Solid Earth · OSTI ID:1466581

Creasy, Neala; Girard, Jennifer; Eckert, James O.; +1 more

Related Subjects

58 GEOSCIENCES

Title: Stability of Fe,Al-bearing bridgmanite in the lower mantle and synthesis of pure Fe-bridgmanite

Citation Formats

References (43)

Cited By (3)

Similar Records

Related Subjects