A molecular basis to rare earth separations for recycling: tuning the TriNOx ligand properties for improved performance

Cole, Bren E.; Falcones, Ingemar B.; Cheisson, Thibault; Manor, Brian C.; Carroll, Patrick J.; Schelter, Eric J.

doi:10.1039/C8CC04409K

Title: A molecular basis to rare earth separations for recycling: tuning the TriNOx ligand properties for improved performance

Journal Article · Mon Jan 01 00:00:00 EST 2018 · ChemComm

DOI:https://doi.org/10.1039/C8CC04409K· OSTI ID:1466425

^[1]; Falcones, Ingemar B. ^[1];

^[1]; Manor, Brian C. ^[1]; Carroll, Patrick J. ^[1];

^[1]

P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, USA

A methoxy-substituted tripodal hydroxylamine ligand, H ₃ TriNOx ^OMe , was synthesized and coordinated to rare earth cations for separation purposes.

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0017259

OSTI ID:: 1466425

Journal Information:: ChemComm, Journal Name: ChemComm Vol. 54 Journal Issue: 73; ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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Cited by: 22 works

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References (30)

Preparation of a novel macroporous silica-based 2,6-bis(5,6-diisobutyl-1,2,4-triazine-3-yl)pyridine impregnated polymeric composite and its application in the adsorption for trivalent rare earths Zhang, Anyun; Kuraoka, E.; Kumagai, M. Journal of Radioanalytical and Nuclear Chemistry, Vol. 274, Issue 3 https://doi.org/10.1007/s10967-006-6923-z	journal	August 2007
Rare-Earth Separation Using Bacteria Bonificio, William D.; Clarke, David R. Environmental Science & Technology Letters, Vol. 3, Issue 4 https://doi.org/10.1021/acs.estlett.6b00064	journal	March 2016
The Exchange Adsorption of Ions from Aqueous Solutions by Organic Zeolites. IV. The Separation of the Yttrium Group Rare Earths ¹ Ketelle, B. H.; Boyd, G. E. Journal of the American Chemical Society, Vol. 69, Issue 11 https://doi.org/10.1021/ja01203a062	journal	November 1947
A Ligand Field Series for the 4f-Block from Experimental and DFT Computed Ce(IV/III) Electrochemical Potentials Bogart, Justin A.; Lewis, Andrew J.; Boreen, Michael A. Inorganic Chemistry, Vol. 54, Issue 6 https://doi.org/10.1021/ic503000z	journal	February 2015
Lanthanide and Actinide Chemistry Cotton, Simon Wiley https://doi.org/10.1002/0470010088	book	January 2006
A survey of solvent selection guides Prat, Denis; Hayler, John; Wells, Andy Green Chem., Vol. 16, Issue 10 https://doi.org/10.1039/C4GC01149J	journal	January 2014
Photochemical recovery of europium from non-aqueous solutions Van den Bogaert, Bart; Gheeraert, Lore; Leblebici, Mumin Enis Physical Chemistry Chemical Physics, Vol. 18, Issue 43 https://doi.org/10.1039/C6CP06329B	journal	January 2016
Replacement of benzene as a solvent for aflatoxin standards Velasco, J. Journal of the American Oil Chemists' Society, Vol. 58, Issue 12 https://doi.org/10.1007/BF02679294	journal	December 1981
Lutetium and Ytterbium Separation by Ion-Exchange Chromatography Kosynkin, V. D.; Molchanova, T. V.; Zharova, E. V. Atomic Energy, Vol. 121, Issue 6 https://doi.org/10.1007/s10512-017-0225-0	journal	April 2017
Synthesis and structural studies of tris-2-chlorobenzylamine and tris-2-bromobenzylamine Chen, Qing; Buss, Carrie E.; Young, Victor G. Journal of Chemical Crystallography, Vol. 35, Issue 3 https://doi.org/10.1007/s10870-005-2954-5	journal	March 2005
CHEM21 selection guide of classical- and less classical-solvents Prat, Denis; Wells, Andy; Hayler, John Green Chemistry, Vol. 18, Issue 1 https://doi.org/10.1039/C5GC01008J	journal	January 2016
Rare earth separations by selective borate crystallization Yin, Xuemiao; Wang, Yaxing; Bai, Xiaojing Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14438	journal	March 2017
Photochemical recycling of europium from Eu/Y mixtures in red lamp phosphor waste streams Van den Bogaert, Bart; Havaux, Daphné; Binnemans, Koen Green Chemistry, Vol. 17, Issue 4 https://doi.org/10.1039/C4GC02140A	journal	January 2015
Preparation of Enhanced Extraction Resin by BPO for the Separation of Rare Earth Elements (Gd, Tb, Dy, Ho) Bae, Jong-Soo; Lee, Jin-Young; Kim, Joon-Soo Separation Science and Technology, Vol. 48, Issue 11 https://doi.org/10.1080/01496395.2012.753904	journal	June 2013
Electro-kinetic Separation of Rare Earth Elements Using a Redox-Active Ligand Fang, Huayi; Cole, Bren E.; Qiao, Yusen Angewandte Chemie International Edition, Vol. 56, Issue 43 https://doi.org/10.1002/anie.201706894	journal	September 2017
A critical review on solvent extraction of rare earths from aqueous solutions Xie, Feng; Zhang, Ting An; Dreisinger, David Minerals Engineering, Vol. 56 https://doi.org/10.1016/j.mineng.2013.10.021	journal	February 2014
Samb V ca: A Web Application for the Calculation of the Buried Volume of N-Heterocyclic Carbene Ligands Poater, Albert; Cosenza, Biagio; Correa, Andrea European Journal of Inorganic Chemistry, Vol. 2009, Issue 13 https://doi.org/10.1002/ejic.200801160	journal	May 2009
Assessing Safety, Health, and Environmental Impact Early during Process Development Koller, Guntram; Fischer, Ulrich; Hungerbühler, Konrad Industrial & Engineering Chemistry Research, Vol. 39, Issue 4 https://doi.org/10.1021/ie990669i	journal	April 2000
Adsorption and chromatographic separation of rare earths with EDTA- and DTPA-functionalized chitosan biopolymers Roosen, Joris; Binnemans, Koen J. Mater. Chem. A, Vol. 2, Issue 5 https://doi.org/10.1039/C3TA14622G	journal	January 2014
An Operationally Simple Method for Separating the Rare-Earth Elements Neodymium and Dysprosium Bogart, Justin A.; Lippincott, Connor A.; Carroll, Patrick J. Angewandte Chemie International Edition, Vol. 54, Issue 28 https://doi.org/10.1002/anie.201501659	journal	May 2015
Interaction of a symmetrical α,α′,δ,δ′-tetramethyl-cucurbit[6]uril with Ln ³⁺ : potential applications for isolation of lanthanides Yang, Bo; Gao, Zhong-Zheng; Lu, Ji-Hong CrystEngComm, Vol. 18, Issue 26 https://doi.org/10.1039/C6CE00134C	journal	January 2016
Efficient adsorption and separation of dysprosium from NdFeB magnets in an acidic system by ion imprinted mesoporous silica sealed in a dialysis bag Zheng, Xudong; Liu, Enli; Zhang, Fusheng Green Chemistry, Vol. 18, Issue 18 https://doi.org/10.1039/C6GC01426G	journal	January 2016
Rationally designed mineralization for selective recovery of the rare earth elements Hatanaka, Takaaki; Matsugami, Akimasa; Nonaka, Takamasa Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15670	journal	May 2017
Nanostructured Hybrid Materials for the Selective Recovery and Enrichment of Rare Earth Elements Florek, Justyna; Chalifour, François; Bilodeau, François Advanced Functional Materials, Vol. 24, Issue 18 https://doi.org/10.1002/adfm.201303602	journal	January 2014
Bioadsorption of Rare Earth Elements through Cell Surface Display of Lanthanide Binding Tags Park, Dan M.; Reed, David W.; Yung, Mimi C. Environmental Science & Technology, Vol. 50, Issue 5 https://doi.org/10.1021/acs.est.5b06129	journal	February 2016
Size-Selective Crystallization of Homochiral Camphorate Metal–Organic Frameworks for Lanthanide Separation Zhao, Xiang; Wong, Matthew; Mao, Chengyu Journal of the American Chemical Society, Vol. 136, Issue 36 https://doi.org/10.1021/ja5067306	journal	August 2014
Green chemistry tools to influence a medicinal chemistry and research chemistry based organisation Alfonsi, Kim; Colberg, Juan; Dunn, Peter J. Green Chem., Vol. 10, Issue 1 https://doi.org/10.1039/B711717E	journal	January 2008
Accomplishing simple, solubility-based separations of rare earth elements with complexes bearing size-sensitive molecular apertures Bogart, Justin A.; Cole, Bren E.; Boreen, Michael A. Proceedings of the National Academy of Sciences, Vol. 113, Issue 52 https://doi.org/10.1073/pnas.1612628113	journal	December 2016
The Separation of Rare Earths by Ion Exchange. V. Investigations with One-tenth Per Cent. Citric Acid-Ammonium Citrate Solutions ¹ Spedding, F. H.; Fulmer, E. I.; Powell, J. E. Journal of the American Chemical Society, Vol. 72, Issue 6 https://doi.org/10.1021/ja01162a004	journal	June 1950
What is a green solvent? A comprehensive framework for the environmental assessment of solvents Capello, Christian; Fischer, Ulrich; Hungerbühler, Konrad Green Chemistry, Vol. 9, Issue 9 https://doi.org/10.1039/b617536h	journal	January 2007

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