Boosting Sodium Storage in TiO2 Nanotube Arrays through Surface Phosphorylation

Ni, Jiangfeng; Fu, Shidong; Yuan, Yifei; Ma, Lu; Jiang, Yu; Li, Liang; Lu, Jun

doi:10.1002/adma.201704337

Title: Boosting Sodium Storage in TiO₂ Nanotube Arrays through Surface Phosphorylation

Journal Article · Wed Jan 03 00:00:00 EST 2018 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201704337· OSTI ID:1466313

Ni, Jiangfeng ^[1]; Fu, Shidong ^[1]; Yuan, Yifei ^[2]; Ma, Lu ^[2]; Jiang, Yu ^[1]; Li, Liang ^[1]; Lu, Jun ^[2]

Soochow Univ., Suzhou (People's Republic of China)
Argonne National Lab. (ANL), Lemont, IL (United States)

Abstract Sodium‐ion batteries (SIBs) offer a promise of a scalable, low‐cost, and environmentally benign means of renewable energy storage. However, the low capacity and poor rate capability of anode materials present an unavoidable challenge. In this work, it is demonstrated that surface phosphorylated TiO ₂ nanotube arrays grown on Ti substrate can be efficient anode materials for SIBs. Fabrication of the phosphorylated nanoarray film is based on the electrochemical anodization of Ti metal in NH ₄ F solution and subsequent phosphorylation using sodium hypophosphite. The phosphorylated TiO ₂ nanotube arrays afford a reversible capacity of 334 mA h g ⁻¹ at 67 mA g ⁻¹ , a superior rate capability of 147 mA h g ⁻¹ at 3350 mA g ⁻¹ , and a stable cycle performance up to 1000 cycles. In situ X‐ray diffraction and transmission electron microscopy reveal the near‐zero strain response and robust mechanical behavior of the TiO ₂ host upon (de)sodiation, suggesting its excellent structural stability in the Na ⁺ storage application.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); National Natural Science Foundation of Jiangsu Province; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE

Grant/Contract Number:: AC02-06CH11357; DE‐AC02‐06CH11357

OSTI ID:: 1466313

Alternate ID(s):: OSTI ID: 1415500

Journal Information:: Advanced Materials, Vol. 30, Issue 6; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 193 works

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References (42)

Amorphous TiO ₂ Nanotube Anode for Rechargeable Sodium Ion Batteries Xiong, Hui; Slater, Michael D.; Balasubramanian, Mahalingam The Journal of Physical Chemistry Letters, Vol. 2, Issue 20 https://doi.org/10.1021/jz2012066	journal	September 2011
Burning lithium in CS2 for high-performing compact Li2S–graphene nanocapsules for Li–S batteries Tan, Guoqiang; Xu, Rui; Xing, Zhenyu Nature Energy, Vol. 2, Issue 7 https://doi.org/10.1038/nenergy.2017.90	journal	June 2017
Dynamic study of (De)sodiation in alpha-MnO2 nanowires Yuan, Yifei; Ma, Lu; He, Kun Nano Energy, Vol. 19 https://doi.org/10.1016/j.nanoen.2015.11.028	journal	January 2016
Anatase Titania Nanorods as an Intercalation Anode Material for Rechargeable Sodium Batteries Kim, Ki-Tae; Ali, Ghulam; Chung, Kyung Yoon Nano Letters, Vol. 14, Issue 2 https://doi.org/10.1021/nl402747x	journal	January 2014
Lithium Insertion in Nanostructured TiO ₂ (B) Architectures Dylla, Anthony G.; Henkelman, Graeme; Stevenson, Keith J. Accounts of Chemical Research, Vol. 46, Issue 5 https://doi.org/10.1021/ar300176y	journal	June 2012
Microstructure of the epitaxial film of anatase nanotubes obtained at high voltage and the mechanism of its electrochemical reaction with sodium González, José R.; Alcántara, Ricardo; Nacimiento, Francisco CrystEngComm, Vol. 16, Issue 21 https://doi.org/10.1039/C4CE00272E	journal	January 2014
State-of-the-art characterization techniques for advanced lithium-ion batteries Lu, Jun; Wu, Tianpin; Amine, Khalil Nature Energy, Vol. 2, Issue 3 https://doi.org/10.1038/nenergy.2017.11	journal	March 2017
Tin Nanodots Encapsulated in Porous Nitrogen-Doped Carbon Nanofibers as a Free-Standing Anode for Advanced Sodium-Ion Batteries Liu, Yongchang; Zhang, Ning; Jiao, Lifang Advanced Materials, Vol. 27, Issue 42 https://doi.org/10.1002/adma.201503015	journal	September 2015
Equilibrium lithium transport between nanocrystalline phases in intercalated TiO2 anatase Wagemaker, M.; Kentgens, A. P. M.; Mulder, F. M. Nature, Vol. 418, Issue 6896 https://doi.org/10.1038/nature00901	journal	July 2002
Boosted Charge Transfer in SnS/SnO ₂ Heterostructures: Toward High Rate Capability for Sodium-Ion Batteries Zheng, Yang; Zhou, Tengfei; Zhang, Chaofeng Angewandte Chemie International Edition, Vol. 55, Issue 10 https://doi.org/10.1002/anie.201510978	journal	February 2016
Effect of the P/Ti Ratio on the Visible-Light Photocatalytic Activity of P-Doped TiO ₂ Li, Fangfei; Jiang, Yinshan; Xia, Maosheng The Journal of Physical Chemistry C, Vol. 113, Issue 42 https://doi.org/10.1021/jp902558z	journal	September 2009
Self-organized amorphous TiO2 nanotube arrays on porous Ti foam for rechargeable lithium and sodium ion batteries Bi, Zhonghe; Paranthaman, M. Parans; Menchhofer, Paul A. Journal of Power Sources, Vol. 222 https://doi.org/10.1016/j.jpowsour.2012.09.019	journal	January 2013
High-rate lithium storage of anatase TiO2 crystals doped with both nitrogen and sulfur Jiao, Wei; Li, Na; Wang, Lianzhou Chemical Communications, Vol. 49, Issue 33 https://doi.org/10.1039/c3cc40568k	journal	January 2013
Surface Engineering and Design Strategy for Surface-Amorphized TiO ₂ @Graphene Hybrids for High Power Li-Ion Battery Electrodes Zhou, Tengfei; Zheng, Yang; Gao, Hong Advanced Science, Vol. 2, Issue 9 https://doi.org/10.1002/advs.201500027	journal	May 2015
Nanoarchitectured Array Electrodes for Rechargeable Lithium- and Sodium-Ion Batteries Xu, Yang; Zhou, Min; Lei, Yong Advanced Energy Materials, Vol. 6, Issue 10 https://doi.org/10.1002/aenm.201502514	journal	March 2016
Highly Reversible and Durable Na Storage in Niobium Pentoxide through Optimizing Structure, Composition, and Nanoarchitecture Ni, Jiangfeng; Wang, Wencong; Wu, Chao Advanced Materials, Vol. 29, Issue 9 https://doi.org/10.1002/adma.201605607	journal	December 2016
Highly Ordered Three-Dimensional Ni-TiO ₂ Nanoarrays as Sodium Ion Battery Anodes Xu, Yang; Zhou, Min; Wen, Liaoyong Chemistry of Materials, Vol. 27, Issue 12 https://doi.org/10.1021/acs.chemmater.5b00633	journal	June 2015
Unfolding the Mechanism of Sodium Insertion in Anatase TiO ₂ Nanoparticles Wu, Liming; Bresser, Dominic; Buchholz, Daniel Advanced Energy Materials, Vol. 5, Issue 2 https://doi.org/10.1002/aenm.201401142	journal	August 2014
High Electrochemical Performances of Microsphere C-TiO ₂ Anode for Sodium-Ion Battery Oh, Seung-Min; Hwang, Jang-Yeon; Yoon, C. S. ACS Applied Materials & Interfaces, Vol. 6, Issue 14 https://doi.org/10.1021/am501772a	journal	June 2014
Dual-Doped Molybdenum Trioxide Nanowires: A Bifunctional Anode for Fiber-Shaped Asymmetric Supercapacitors and Microbial Fuel Cells Yu, Minghao; Cheng, Xinyu; Zeng, Yinxiang Angewandte Chemie International Edition, Vol. 55, Issue 23 https://doi.org/10.1002/anie.201602631	journal	April 2016
Synthesis and Characterization of Phosphated Mesoporous Titanium Dioxide with High Photocatalytic Activity Yu, Jimmy C.; Zhang, Lizhi; Zheng, Zhi Chemistry of Materials, Vol. 15, Issue 11 https://doi.org/10.1021/cm0340781	journal	June 2003
Superior Electrochemical Performance and Storage Mechanism of Na ₃ V ₂ (PO ₄ ) ₃ Cathode for Room-Temperature Sodium-Ion Batteries Jian, Zelang; Han, Wenze; Lu, Xia Advanced Energy Materials, Vol. 3, Issue 2 https://doi.org/10.1002/aenm.201200558	journal	October 2012
Multifunctional P-Doped TiO ₂ Films: A New Approach to Self-Cleaning, Transparent Conducting Oxide Materials Sotelo-Vazquez, Carlos; Noor, Nuruzzaman; Kafizas, Andreas Chemistry of Materials, Vol. 27, Issue 9 https://doi.org/10.1021/cm504734a	journal	April 2015
Phosphate Ion Functionalized Co ₃ O ₄ Ultrathin Nanosheets with Greatly Improved Surface Reactivity for High Performance Pseudocapacitors Zhai, Teng; Wan, Liming; Sun, Shuo Advanced Materials, Vol. 29, Issue 7 https://doi.org/10.1002/adma.201604167	journal	December 2016
Hydrogenation Driven Conductive Na ₂ Ti ₃ O ₇ Nanoarrays as Robust Binder-Free Anodes for Sodium-Ion Batteries Fu, Shidong; Ni, Jiangfeng; Xu, Yong Nano Letters, Vol. 16, Issue 7 https://doi.org/10.1021/acs.nanolett.6b01805	journal	June 2016
Sodium-Ion Batteries Slater, Michael D.; Kim, Donghan; Lee, Eungje Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958 https://doi.org/10.1002/adfm.201200691	journal	May 2012
A Size-Dependent Sodium Storage Mechanism in Li ₄ Ti ₅ O ₁₂ Investigated by a Novel Characterization Technique Combining in Situ X-ray Diffraction and Chemical Sodiation Yu, Xiqian; Pan, Huilin; Wan, Wang Nano Letters, Vol. 13, Issue 10 https://doi.org/10.1021/nl402263g	journal	September 2013
Na+ intercalation pseudocapacitance in graphene-coupled titanium oxide enabling ultra-fast sodium storage and long-term cycling Chen, Chaoji; Wen, Yanwei; Hu, Xianluo Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7929	journal	April 2015
Probing the Failure Mechanism of SnO ₂ Nanowires for Sodium-Ion Batteries Gu, Meng; Kushima, Akihiro; Shao, Yuyan Nano Letters, Vol. 13, Issue 11 https://doi.org/10.1021/nl402633n	journal	October 2013
Self-Supported Nanotube Arrays of Sulfur-Doped TiO ₂ Enabling Ultrastable and Robust Sodium Storage Ni, Jiangfeng; Fu, Shidong; Wu, Chao Advanced Materials, Vol. 28, Issue 11 https://doi.org/10.1002/adma.201504412	journal	January 2016
Direct atomic-scale confirmation of three-phase storage mechanism in Li4Ti5O12 anodes for room-temperature sodium-ion batteries Sun, Yang; Zhao, Liang; Pan, Huilin Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2878	journal	May 2013
High-capacity antimony sulphide nanoparticle-decorated graphene composite as anode for sodium-ion batteries Yu, Denis Y. W.; Prikhodchenko, Petr V.; Mason, Chad W. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3922	journal	December 2013
High Power-High Energy Sodium Battery Based on Threefold Interpenetrating Network Zhu, Changbao; Kopold, Peter; van Aken, Peter A. Advanced Materials, Vol. 28, Issue 12 https://doi.org/10.1002/adma.201505943	journal	January 2016
Nanocrystalline anatase TiO2: a new anode material for rechargeable sodium ion batteries Xu, Yang; Memarzadeh Lotfabad, Elmira; Wang, Huanlei Chemical Communications, Vol. 49, Issue 79 https://doi.org/10.1039/c3cc45254a	journal	January 2013
In situ transmission electron microscopy study of the electrochemical sodiation process for a single CuO nanowire electrode Zhang, Liqiang; Wang, Yuecun; Xie, Degang RSC Advances, Vol. 6, Issue 14 https://doi.org/10.1039/C5RA24086G	journal	January 2016
A zero-strain layered metal oxide as the negative electrode for long-life sodium-ion batteries Wang, Yuesheng; Yu, Xiqian; Xu, Shuyin Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3365	journal	August 2013
Ultrafast sodium storage in anatase TiO2 nanoparticles embedded on carbon nanotubes Hwang, Jang-Yeon; Myung, Seung-Taek; Lee, Joo-Hyeong Nano Energy, Vol. 16 https://doi.org/10.1016/j.nanoen.2015.06.017	journal	September 2015
Superior Sodium Storage in Na ₂ Ti ₃ O ₇ Nanotube Arrays through Surface Engineering Ni, Jiangfeng; Fu, Shidong; Wu, Chao Advanced Energy Materials, Vol. 6, Issue 11 https://doi.org/10.1002/aenm.201502568	journal	March 2016
Research Development on Sodium-Ion Batteries Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500192f	journal	October 2014
Sodium-Ion Batteries Rojo, Teofilo; Hu, Yong-Sheng; Forsyth, Maria Advanced Energy Materials, Vol. 8, Issue 17 https://doi.org/10.1002/aenm.201800880	journal	June 2018
Dual-Doped Molybdenum Trioxide Nanowires: A Bifunctional Anode for Fiber-Shaped Asymmetric Supercapacitors and Microbial Fuel Cells Yu, Minghao; Cheng, Xinyu; Zeng, Yinxiang Angewandte Chemie, Vol. 128, Issue 23 https://doi.org/10.1002/ange.201602631	journal	April 2016
Boosted Charge Transfer in SnS/SnO ₂ Heterostructures: Toward High Rate Capability for Sodium-Ion Batteries Zheng, Yang; Zhou, Tengfei; Zhang, Chaofeng Angewandte Chemie, Vol. 128, Issue 10 https://doi.org/10.1002/ange.201510978	journal	February 2016

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Title: Boosting Sodium Storage in TiO2 Nanotube Arrays through Surface Phosphorylation

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