L-edge sum rule analysis on 3d transition metal sites: from d10 to d0 and towards application to extremely dilute metallo-enzymes
Abstract
According to L-edge sum rules, the number of 3d vacancies at a transition metal site is directly proportional to the integrated intensity of the L-edge X-ray absorption spectrum (XAS) for the corresponding metal complex.
- Authors:
-
- Univ. of California, Davis, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- Univ. of Hyogo, Tatsuno (Japan)
- Univ. of California, Davis, CA (United States)
- Univ. of Illinois, Urbana, IL (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States); Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Biological and Environmental Research (BER)
- OSTI Identifier:
- 1434331
- Alternate Identifier(s):
- OSTI ID: 1465312
- Report Number(s):
- LLNL-JRNL-746682
Journal ID: ISSN 1463-9076; PPCPFQ; 142189; TRN: US1802684
- Grant/Contract Number:
- AC02-06CH11357; AC52-07NA27344
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Physical Chemistry Chemical Physics. PCCP (Print)
- Additional Journal Information:
- Journal Volume: 20; Journal Issue: 12; Journal ID: ISSN 1463-9076
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Wang, Hongxin, Friedrich, Stephan, Li, Lei, Mao, Ziliang, Ge, Pinghua, Balasubramanian, Mahalingam, and Patil, Daulat S. L-edge sum rule analysis on 3d transition metal sites: from d10 to d0 and towards application to extremely dilute metallo-enzymes. United States: N. p., 2018.
Web. doi:10.1039/c7cp06624d.
Wang, Hongxin, Friedrich, Stephan, Li, Lei, Mao, Ziliang, Ge, Pinghua, Balasubramanian, Mahalingam, & Patil, Daulat S. L-edge sum rule analysis on 3d transition metal sites: from d10 to d0 and towards application to extremely dilute metallo-enzymes. United States. https://doi.org/10.1039/c7cp06624d
Wang, Hongxin, Friedrich, Stephan, Li, Lei, Mao, Ziliang, Ge, Pinghua, Balasubramanian, Mahalingam, and Patil, Daulat S. 2018.
"L-edge sum rule analysis on 3d transition metal sites: from d10 to d0 and towards application to extremely dilute metallo-enzymes". United States. https://doi.org/10.1039/c7cp06624d. https://www.osti.gov/servlets/purl/1434331.
@article{osti_1434331,
title = {L-edge sum rule analysis on 3d transition metal sites: from d10 to d0 and towards application to extremely dilute metallo-enzymes},
author = {Wang, Hongxin and Friedrich, Stephan and Li, Lei and Mao, Ziliang and Ge, Pinghua and Balasubramanian, Mahalingam and Patil, Daulat S.},
abstractNote = {According to L-edge sum rules, the number of 3d vacancies at a transition metal site is directly proportional to the integrated intensity of the L-edge X-ray absorption spectrum (XAS) for the corresponding metal complex.},
doi = {10.1039/c7cp06624d},
url = {https://www.osti.gov/biblio/1434331},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
issn = {1463-9076},
number = 12,
volume = 20,
place = {United States},
year = {Tue Feb 13 00:00:00 EST 2018},
month = {Tue Feb 13 00:00:00 EST 2018}
}
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Cited by: 13 works
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Figures / Tables:
Table 1.: The integrated and normalized L intensities (IL), edge jumps (J), L intensity derived number of 3d holes (H3d) and their corresponding errors (δα and δH3d) for a series of Ni and Mn complexes with different ligand types.
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