Unexpected high binding energy of CO 2 on CH 3 NH 3 PbI 3 lead-halide organic–inorganic perovskites via bicarbonate formation

Nayakasinghe, M. T.; Han, Yulun; Sivapragasam, N.; Kilin, Dmitri S.; Burghaus, U.

doi:10.1039/C8CC04749A

Title: Unexpected high binding energy of CO ₂ on CH ₃ NH ₃ PbI ₃ lead-halide organic–inorganic perovskites via bicarbonate formation

Journal Article · Mon Jan 01 00:00:00 EST 2018 · ChemComm

DOI:https://doi.org/10.1039/C8CC04749A· OSTI ID:1464968

Nayakasinghe, M. T. ^[1];

^[1]; Sivapragasam, N. ^[1];

^[1];

^[1]

Department of Chemistry and Biochemistry, North Dakota State University (NDSU), Fargo, USA

The adsorption kinetics of CO ₂ was experimentally characterized in ultra-high vacuum (UHV). In addition, density functional theory (DFT) calculations were included.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC-00001717; AC02-05CH11231

OSTI ID:: 1464968

Journal Information:: ChemComm, Journal Name: ChemComm Vol. 54 Journal Issue: 71; ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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Cited by: 15 works

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Title: Unexpected high binding energy of CO ₂ on CH ₃ NH ₃ PbI ₃ lead-halide organic–inorganic perovskites via bicarbonate formation