Influence of potassium oxide on the kinetic characteristics of olefin formation during the hydrogenation of CO over metals
Journal Article
·
· Theoretical and Experimental Chemistry
- L.V. Pisarzhevskii Inst. of Physical Chemistry, Kiev (Ukraine)
The effect of added potassium on the catalytic properties of an Fe/ZrO{sub 2} catalyst in the hydrogenation of CO have been studied. A kinetic criterion is proposed for the participation of the basic centers in the catalyst in the olefin formation step. Use of this criterion indicates that the basic centres of the catalyst considerably accelerate the conversion of surface alkyl groups to olefins during the hydrogenation of CO.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 146488
- Journal Information:
- Theoretical and Experimental Chemistry, Vol. 30, Issue 4; Other Information: PBD: Jan 1995; TN: Translated from Teoreticheskaya i Eksperimental`naya Khimiya; 30: No. 4, 192-196(Jul-Aug 1994)
- Country of Publication:
- United States
- Language:
- English
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