skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: High electrical conductivity and high porosity in a Guest@MOF material: evidence of TCNQ ordering within Cu 3 BTC 2 micropores

Abstract

The host–guest system TCNQ@Cu 3 BTC 2 is a striking example of how semiconductivity can be introduced by guest incorporation in an otherwise insulating parent material.

Authors:
ORCiD logo [1]; ORCiD logo [1];  [2];  [3]; ORCiD logo [1]; ORCiD logo [4]; ORCiD logo [5]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [1]
  1. Department of Chemistry, Technical University Munich, 85748 Garching, Germany
  2. Institute of Physical Chemistry, Center for Materials Research (ZFM), Justus-Liebig-University Giessen, 35392 Giessen, Germany
  3. Sandia National Laboratories, Livermore, USA
  4. Laboratory of Organic Chemistry, Wageningen University & Research, 6708 WE Wageningen, The Netherlands
  5. Laboratory of Organic Chemistry, Wageningen University & Research, 6708 WE Wageningen, The Netherlands, School of Pharmaceutical Sciences and Technology
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1464563
Resource Type:
Journal Article: Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 9 Journal Issue: 37; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Schneider, Christian, Ukaj, Dardan, Koerver, Raimund, Talin, A. Alec, Kieslich, Gregor, Pujari, Sidharam P., Zuilhof, Han, Janek, Jürgen, Allendorf, Mark D., and Fischer, Roland A.. High electrical conductivity and high porosity in a Guest@MOF material: evidence of TCNQ ordering within Cu 3 BTC 2 micropores. United Kingdom: N. p., 2018. Web. doi:10.1039/C8SC02471E.
Schneider, Christian, Ukaj, Dardan, Koerver, Raimund, Talin, A. Alec, Kieslich, Gregor, Pujari, Sidharam P., Zuilhof, Han, Janek, Jürgen, Allendorf, Mark D., & Fischer, Roland A.. High electrical conductivity and high porosity in a Guest@MOF material: evidence of TCNQ ordering within Cu 3 BTC 2 micropores. United Kingdom. doi:10.1039/C8SC02471E.
Schneider, Christian, Ukaj, Dardan, Koerver, Raimund, Talin, A. Alec, Kieslich, Gregor, Pujari, Sidharam P., Zuilhof, Han, Janek, Jürgen, Allendorf, Mark D., and Fischer, Roland A.. Mon . "High electrical conductivity and high porosity in a Guest@MOF material: evidence of TCNQ ordering within Cu 3 BTC 2 micropores". United Kingdom. doi:10.1039/C8SC02471E.
@article{osti_1464563,
title = {High electrical conductivity and high porosity in a Guest@MOF material: evidence of TCNQ ordering within Cu 3 BTC 2 micropores},
author = {Schneider, Christian and Ukaj, Dardan and Koerver, Raimund and Talin, A. Alec and Kieslich, Gregor and Pujari, Sidharam P. and Zuilhof, Han and Janek, Jürgen and Allendorf, Mark D. and Fischer, Roland A.},
abstractNote = {The host–guest system TCNQ@Cu 3 BTC 2 is a striking example of how semiconductivity can be introduced by guest incorporation in an otherwise insulating parent material.},
doi = {10.1039/C8SC02471E},
journal = {Chemical Science},
number = 37,
volume = 9,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record at 10.1039/C8SC02471E

Save / Share:

Works referenced in this record:

Degree of charge transfer in organic conductors by infrared absorption spectroscopy
journal, May 1981

  • Chappell, J. S.; Bloch, A. N.; Bryden, W. A.
  • Journal of the American Chemical Society, Vol. 103, Issue 9, p. 2442-2443
  • DOI: 10.1021/ja00399a066

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002

  • Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
  • Science, Vol. 295, Issue 5554, p. 469-472
  • DOI: 10.1126/science.1067208

Reticular synthesis and the design of new materials
journal, June 2003

  • Yaghi, Omar M.; O'Keeffe, Michael; Ockwig, Nathan W.
  • Nature, Vol. 423, Issue 6941, p. 705-714
  • DOI: 10.1038/nature01650

Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices
journal, December 2013

  • Talin, A. Alec; Centrone, Andrea; Ford, Alexandra C.
  • Science, Vol. 343, Issue 6166, p. 66-69
  • DOI: 10.1126/science.1246738