Distinct exciton dissociation behavior of organolead trihalide perovskite and excitonic semiconductors studied in a same device

Hu, Miao; Bi, Cheng; Yuan, Yongbo; Xiao, Zhengguo; Dong, Qingfeng; Shao, Yuchuan; Huang, Jinsong

doi:10.1002/smll.201402905

Title: Distinct exciton dissociation behavior of organolead trihalide perovskite and excitonic semiconductors studied in a same device

Journal Article · Thu Jan 15 00:00:00 EST 2015 · Small

DOI:https://doi.org/10.1002/smll.201402905· OSTI ID:1237992

Hu, Miao ^[1]; Bi, Cheng ^[1]; Yuan, Yongbo ^[1]; Xiao, Zhengguo ^[1]; Dong, Qingfeng ^[1]; Shao, Yuchuan ^[1]; Huang, Jinsong ^[1]

Univ. of Nebraska, Lincoln, NE (United States)

The nonexcitonic character for organometal trihalide perovskites is demonstrated by examining the field-dependent exciton dissociation behavior. Moreover, it is found that photogenerated excitons can be effectively dissociated into free charges inside perovskite without the assistance of charge extraction layer or external field, which is a stark contrast to the charge-separation behavior in excitonic materials in the same photovoltaic operation system.

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Research Organization:: Univ. of Nebraska, Lincoln, NE (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: EE0006709; DE‐EE0006709

OSTI ID:: 1237992

Alternate ID(s):: OSTI ID: 1464328

Journal Information:: Small, Vol. 11, Issue 18; ISSN 1613-6810

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 69 works

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References (36)

Recombination Study of Combined Halides (Cl, Br, I) Perovskite Solar Cells Suarez, Belen; Gonzalez-Pedro, Victoria; Ripolles, Teresa S. The Journal of Physical Chemistry Letters, Vol. 5, Issue 10 https://doi.org/10.1021/jz5006797	journal	April 2014
Chloride Inclusion and Hole Transport Material Doping to Improve Methyl Ammonium Lead Bromide Perovskite-Based High Open-Circuit Voltage Solar Cells Edri, Eran; Kirmayer, Saar; Kulbak, Michael The Journal of Physical Chemistry Letters, Vol. 5, Issue 3, p. 429-433 https://doi.org/10.1021/jz402706q	journal	January 2014
A photophysical study of PCBM thin films Cook, Steffan; Ohkita, Hideo; Kim, Youngkyoo Chemical Physics Letters, Vol. 445, Issue 4-6 https://doi.org/10.1016/j.cplett.2007.08.005	journal	September 2007
Electric field assisted dissociation of charge transfer states as a mechanism of photocarrier production Braun, Charles L. The Journal of Chemical Physics, Vol. 80, Issue 9 https://doi.org/10.1063/1.447243	journal	May 1984
Efficient, high yield perovskite photovoltaic devices grown by interdiffusion of solution-processed precursor stacking layers Xiao, Zhengguo; Bi, Cheng; Shao, Yuchuan Energy Environ. Sci., Vol. 7, Issue 8 https://doi.org/10.1039/C4EE01138D	journal	January 2014
Hole-conductor-free perovskite organic lead iodide heterojunction thin-film solar cells: High efficiency and junction property Shi, Jiangjian; Dong, Juan; Lv, Songtao Applied Physics Letters, Vol. 104, Issue 6 https://doi.org/10.1063/1.4864638	journal	February 2014
Harvesting Triplet Excitons from Fluorescent Blue Emitters in White Organic Light-Emitting Diodes Schwartz, G.; Pfeiffer, M.; Reineke, S. Advanced Materials, Vol. 19, Issue 21 https://doi.org/10.1002/adma.200700641	journal	November 2007
Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells Shao, Yuchuan; Xiao, Zhengguo; Bi, Cheng Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6784	journal	December 2014
CH ₃ NH ₃ PbI ₃ Perovskite/Fullerene Planar-Heterojunction Hybrid Solar Cells Jeng, Jun-Yuan; Chiang, Yi-Fang; Lee, Mu-Huan Advanced Materials, Vol. 25, Issue 27 https://doi.org/10.1002/adma.201301327	journal	June 2013
Mesoscopic CH₃NH₃PbI₃/TiO₂ Heterojunction Solar Cells Etgar, Lioz; Gao, Peng; Xue, Zhaosheng Journal of the American Chemical Society, Vol. 134, Issue 42, p. 17396-17399 https://doi.org/10.1021/ja307789s	journal	October 2012
Efficiency enhancement in organic solar cells with ferroelectric polymers Yuan, Yongbo; Reece, Timothy J.; Sharma, Pankaj Nature Materials, Vol. 10, Issue 4 https://doi.org/10.1038/nmat2951	journal	February 2011
25th Anniversary Article: A Decade of Organic/Polymeric Photovoltaic Research Dou, Letian; You, Jingbi; Hong, Ziruo Advanced Materials, Vol. 25, Issue 46 https://doi.org/10.1002/adma.201302563	journal	September 2013
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells Jeon, Nam Joong; Noh, Jun Hong; Kim, Young Chan Nature Materials, Vol. 13, Issue 9, p. 897-903 https://doi.org/10.1038/nmat4014	journal	July 2014
MAPbI_3-xCl_x Mixed Halide Perovskite for Hybrid Solar Cells: The Role of Chloride as Dopant on the Transport and Structural Properties Colella, Silvia; Mosconi, Edoardo; Fedeli, Paolo Chemistry of Materials, Vol. 25, Issue 22, p. 4613-4618 https://doi.org/10.1021/cm402919x	journal	November 2013
Optical properties of PbI-based perovskite structures Ishihara, Teruya Journal of Luminescence, Vol. 60-61 https://doi.org/10.1016/0022-2313(94)90145-7	journal	April 1994
Solvent Annealing of Perovskite-Induced Crystal Growth for Photovoltaic-Device Efficiency Enhancement Xiao, Zhengguo; Dong, Qingfeng; Bi, Cheng Advanced Materials, Vol. 26, Issue 37 https://doi.org/10.1002/adma.201401685	journal	August 2014
Solution-Processed Fullerene-Based Organic Schottky Junction Devices for Large-Open-Circuit-Voltage Organic Solar Cells Yang, Bin; Guo, Fawen; Yuan, Yongbo Advanced Materials, Vol. 25, Issue 4 https://doi.org/10.1002/adma.201203080	journal	November 2012
Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% Kim, Hui-Seon; Lee, Chang-Ryul; Im, Jeong-Hyeok Scientific Reports, Vol. 2, Issue 1 https://doi.org/10.1038/srep00591	journal	August 2012
Low-temperature solution-processed wavelength-tunable perovskites for lasing Xing, Guichuan; Mathews, Nripan; Lim, Swee Sien Nature Materials, Vol. 13, Issue 5 https://doi.org/10.1038/nmat3911	journal	March 2014
Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter‐wave spectroscopy Poglitsch, A.; Weber, D. The Journal of Chemical Physics, Vol. 87, Issue 11, p. 6373-6378 https://doi.org/10.1063/1.453467	journal	December 1987
On the origin of the open-circuit voltage of polymer–fullerene solar cells Vandewal, Koen; Tvingstedt, Kristofer; Gadisa, Abay Nature Materials, Vol. 8, Issue 11, p. 904-909 https://doi.org/10.1038/nmat2548	journal	October 2009
Compositional and Electric Field Dependence of the Dissociation of Charge Transfer Excitons in Alternating Polyfluorene Copolymer/Fullerene Blends Veldman, Dirk; İpek, Özlem; Meskers, Stefan C. J. Journal of the American Chemical Society, Vol. 130, Issue 24 https://doi.org/10.1021/ja8012598	journal	May 2008
Dual Plasmonic Nanostructures for High Performance Inverted Organic Solar Cells Li, Xuanhua; Choy, Wallace C. H.; Huo, Lijun Advanced Materials, Vol. 24, Issue 22 https://doi.org/10.1002/adma.201200120	journal	May 2012
Charge-transfer-induced Frenkel exciton splitting in crystalline fullerene Munn, R. W.; Pac, Barbara; Petelenz, Piotr Physical Review B, Vol. 57, Issue 3 https://doi.org/10.1103/PhysRevB.57.1328	journal	January 1998
Comparative study on the excitons in lead-halide-based perovskite-type crystals CH₃NH₃PbBr₃ CH₃NH₃PbI₃ Tanaka, Kenichiro; Takahashi, Takayuki; Ban, Takuma Solid State Communications, Vol. 127, Issue 9-10, p. 619-623 https://doi.org/10.1016/S0038-1098(03)00566-0	journal	September 2003
Open‐circuit voltage of induced‐junction solar cells Alam, M. K.; Yeow, Y. T. Applied Physics Letters, Vol. 37, Issue 5 https://doi.org/10.1063/1.91968	journal	September 1980
Excitons versus free charges in organo-lead tri-halide perovskites D’Innocenzo, Valerio; Grancini, Giulia; Alcocer, Marcelo J. P. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4586	journal	April 2014
The origin of high efficiency in low-temperature solution-processable bilayer organometal halide hybrid solar cells Sun, Shuangyong; Salim, Teddy; Mathews, Nripan Energy Environ. Sci., Vol. 7, Issue 1 https://doi.org/10.1039/C3EE43161D	journal	January 2014
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Lee, M. M.; Teuscher, J.; Miyasaka, T. Science, Vol. 338, Issue 6107, p. 643-647 https://doi.org/10.1126/science.1228604	journal	October 2012
Large fill-factor bilayer iodine perovskite solar cells fabricated by a low-temperature solution-process Wang, Qi; Shao, Yuchuan; Dong, Qingfeng Energy Environ. Sci., Vol. 7, Issue 7 https://doi.org/10.1039/C4EE00233D	journal	January 2014
Thermodynamic efficiency limit of excitonic solar cells Giebink, Noel C.; Wiederrecht, Gary P.; Wasielewski, Michael R. Physical Review B, Vol. 83, Issue 19 https://doi.org/10.1103/PhysRevB.83.195326	journal	May 2011
Mechanism of carrier accumulation in perovskite thin-absorber solar cells Kim, Hui-Seon; Mora-Sero, Ivan; Gonzalez-Pedro, Victoria Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3242	journal	July 2013
Photoinduced Giant Dielectric Constant in Lead Halide Perovskite Solar Cells Juarez-Perez, Emilio J.; Sanchez, Rafael S.; Badia, Laura The Journal of Physical Chemistry Letters, Vol. 5, Issue 13 https://doi.org/10.1021/jz5011169	journal	June 2014
Singlet exciton binding energy in poly(phenylene vinylene) Moses, D.; Wang, J.; Heeger, A. J. Proceedings of the National Academy of Sciences, Vol. 98, Issue 24 https://doi.org/10.1073/pnas.241497098	journal	November 2001
Hydrogen-Induced Morphotropic Phase Transformation of Single-Crystalline Vanadium Dioxide Nanobeams Hong, Woong-Ki; Park, Jong Bae; Yoon, Jongwon Nano Letters, Vol. 13, Issue 4 https://doi.org/10.1021/nl400511x	journal	March 2013
Chemical Management for Colorful, Efficient, and Stable Inorganic–Organic Hybrid Nanostructured Solar Cells Noh, Jun Hong; Im, Sang Hyuk; Heo, Jin Hyuck Nano Letters, Vol. 13, Issue 4, p. 1764-1769 https://doi.org/10.1021/nl400349b	journal	March 2013

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Light-Induced Self-Poling Effect on Organometal Trihalide Perovskite Solar Cells for Increased Device Efficiency and Stability Deng, Yehao; Xiao, Zhengguo; Huang, Jinsong Advanced Energy Materials, Vol. 5, Issue 20 https://doi.org/10.1002/aenm.201500721	journal	August 2015
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Solution Processable Inorganic-Organic Double-Layered Hole Transport Layer for Highly Stable Planar Perovskite Solar Cells Kim, Guan-Woo; Kang, Gyeongho; Choi, Kyoungwon Advanced Energy Materials, Vol. 8, Issue 26 https://doi.org/10.1002/aenm.201801386	journal	August 2018
Understanding the physical properties of hybrid perovskites for photovoltaic applications Huang, Jinsong; Yuan, Yongbo; Shao, Yuchuan Nature Reviews Materials, Vol. 2, Issue 7 https://doi.org/10.1038/natrevmats.2017.42	journal	July 2017
Monolithic integration of hybrid perovskite single crystals with heterogenous substrate for highly sensitive X-ray imaging Wei, Wei; Zhang, Yang; Xu, Qiang Nature Photonics, Vol. 11, Issue 5 https://doi.org/10.1038/nphoton.2017.43	journal	April 2017
Properties of Excitons and Photogenerated Charge Carriers in Metal Halide Perovskites Jiang, Ying; Wang, Xiao; Pan, Anlian Advanced Materials, Vol. 31, Issue 47 https://doi.org/10.1002/adma.201806671	journal	September 2018
Constructing CsPbBr ₃ Cluster Passivated‐Triple Cation Perovskite for Highly Efficient and Operationally Stable Solar Cells Zhou, Wenke; Chen, Shulin; Zhao, Yicheng Advanced Functional Materials, Vol. 29, Issue 14 https://doi.org/10.1002/adfm.201809180	journal	February 2019
Stabilized Wide Bandgap MAPbBr _x I _{3- x} Perovskite by Enhanced Grain Size and Improved Crystallinity Hu, Miao; Bi, Cheng; Yuan, Yongbo Advanced Science, Vol. 3, Issue 6 https://doi.org/10.1002/advs.201500301	journal	December 2015
Photophysics of Methylammonium Lead Tribromide Perovskite: Free Carriers, Excitons, and Sub‐Bandgap States Droseros, Nikolaos; Tsokkou, Demetra; Banerji, Natalie Advanced Energy Materials, Vol. 10, Issue 13 https://doi.org/10.1002/aenm.201903258	journal	April 2020
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Correlation of energy disorder and open-circuit voltage in hybrid perovskite solar cells Shao, Yuchuan; Yuan, Yongbo; Huang, Jinsong Nature Energy, Vol. 1, Issue 1 https://doi.org/10.1038/nenergy.2015.1	journal	January 2016
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