Resonance signatures in the body-frame valence photoionization of CF4
Journal Article
·
· Physical Chemistry Chemical Physics. PCCP
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- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division; Univ. of California, Berkeley, CA (United States). Graduate Group in Applied Science and Technology
- California State Univ. Maritime Academy (CalState), Vallejo, CA (United States). Dept. of Sciences and Mathematics
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division; Max-Planck-Institut für Kernphysik, Heidelberg (Germany); J.W. Goethe Univ., Frankfurt (Germany).Inst. für Kernphysik
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division; Auburn Univ., Auburn, AL (United States). Dept. of Physics
- Max-Planck-Institut für Kernphysik, Heidelberg (Germany)
- Auburn Univ., Auburn, AL (United States). Dept. of Physics
- Kansas State Univ., Manhattan, KS (United States).J.R. Macdonald Lab.
- Univ. of Nevada, Reno, NV (United States). Dept. of Physics
- J.W. Goethe Univ., Frankfurt (Germany).Inst. für Kernphysik
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division; Univ. of California, Davis, CA (United States). Dept. of Chemistry
Here, we present a combined experimental and theoretical investigation of the electron dynamics and body-frame angular dependence of valence photo-single ionization of CF4 and subsequent dissociation into CF3+ and F. Ionization from a valence t2 orbital shows overlapping shape resonances close to threshold that couple to the same total symmetry, leading to striking changes in the photoelectron angular distributions when viewed in the body-frame.
- Research Organization:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Organization:
- SC-22.1 USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division; Deutsche Akademische Austausch Dienst (DAAD); USDOE
- Grant/Contract Number:
- AC02-05CH11231; FG02-86ER13491
- OSTI ID:
- 1464171
- Alternate ID(s):
- OSTI ID: 1462770
- Journal Information:
- Physical Chemistry Chemical Physics. PCCP, Vol. 20, Issue 32; ISSN 1463-9076
- Publisher:
- Royal Society of ChemistryCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Cited by: 10 works
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