Insight into Ca-Substitution Effects on O3-Type NaNi1/3Fe1/3Mn1/3O2 Cathode Materials for Sodium-Ion Batteries Application

Sun, Liqi; Xie, Yingying; Liao, Xiao-Zhen; Wang, Hong; Tan, Guoqiang; Chen, Zonghai; Ren, Yang; Gim, Jihyeon; Tang, Wan; He, Yu-Shi; Amine, Khalil; Ma, Zi-Feng

doi:10.1002/smll.201704523

Title: Insight into Ca-Substitution Effects on O3-Type NaNi_1/3Fe_1/3Mn_1/3O₂ Cathode Materials for Sodium-Ion Batteries Application

Journal Article · Wed Apr 18 00:00:00 EDT 2018 · Small

DOI:https://doi.org/10.1002/smll.201704523· OSTI ID:1463686

Sun, Liqi ^[1]; Xie, Yingying ^[1]; Liao, Xiao-Zhen ^[1]; Wang, Hong ^[1]; Tan, Guoqiang ^[2]; Chen, Zonghai ^[2]; Ren, Yang ^[2]; Gim, Jihyeon ^[2]; Tang, Wan ^[1]; He, Yu-Shi ^[1]; Amine, Khalil ^[2]; Ma, Zi-Feng ^[1]

Shanghai Jiao Tong Univ. (China)
Argonne National Lab. (ANL), Argonne, IL (United States)

O3-type NaNi_1/3Fe_1/3Mn_1/3O₂ (NaNFM) is well investigated as a promising cathode material for sodium-ion batteries (SIBs), but the cycling stability of NaNFM still needs to be improved by using novel electrolytes or optimizing their structure with the substitution of different elements sites. To enlarge the alkali-layer distance inside the layer structure of NaNFM may benefit Na⁺ diffusion. Herein, the effect of Ca-substitution is reported in Na sites on the structural and electrochemical properties of Na_1-xCa_x/2NFM (x=0, 0.05, 0.1). X-ray diffraction (XRD) patterns of the prepared Na_1-xCa_x/2NFM samples show single alpha-NaFeO₂ type phase with slightly increased alkali-layer distance as Ca content increases. The cycling stabilities of Ca-substituted samples are remarkably improved. The Na_0.9Ca_0.05Ni_1/3Fe_1/3Mn_1/3O₂ (Na_0.9Ca_0.05NFM) cathode delivers a capacity of 116.3 mAh g^-1 with capacity retention of 92% after 200 cycles at 1C rate. In operando XRD indicates a reversible structural evolution through an O3-P3-P3-O3 sequence of Na_0.9Ca_0.05NFM cathode during cycling. Compared to NaNMF, the Na_0.9Ca_0.05NFM cathode shows a wider voltage range in pure P3 phase state during the charge/discharge process and exhibits better structure recoverability after cycling. The superior cycling stability of Na_0.9Ca_0.05NFM makes it a promising material for practical applications in sodium-ion batteries.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); National Key Research and Development Program of China; USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1463686

Journal Information:: Small, Vol. 14, Issue 21; ISSN 1613-6810

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 58 works

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Realizing a High‐Performance Na‐Storage Cathode by Tailoring Ultrasmall Na ₂ FePO ₄ F Nanoparticles with Facilitated Reaction Kinetics Wang, Fanfan; Zhang, Ning; Zhao, Xudong Advanced Science https://doi.org/10.1002/advs.201900649	journal	May 2019
High‐Abundance and Low‐Cost Metal‐Based Cathode Materials for Sodium‐Ion Batteries: Problems, Progress, and Key Technologies Chen, Mingzhe; Liu, Qiannan; Wang, Shi‐Wen Advanced Energy Materials, Vol. 9, Issue 14 https://doi.org/10.1002/aenm.201803609	journal	February 2019
Synthesis and characterization of Ru doped NaNi0.5Mn0.3Ti0.2O2 cathode material with improved electrochemical performance for sodium-ion batteries Leng, Mingzhe; Bi, Jianqiang; Wang, Weili Ionics, Vol. 25, Issue 3 https://doi.org/10.1007/s11581-018-2830-x	journal	January 2019
Ni- and/or Mn-based layered transition metal oxides as cathode materials for sodium ion batteries: status, challenges and countermeasures Wang, Shenghan; Sun, Chenglin; Wang, Ning Journal of Materials Chemistry A, Vol. 7, Issue 17 https://doi.org/10.1039/c8ta12441h	journal	January 2019

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Title: Insight into Ca-Substitution Effects on O3-Type NaNi1/3Fe1/3Mn1/3O2 Cathode Materials for Sodium-Ion Batteries Application

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Title: Insight into Ca-Substitution Effects on O3-Type NaNi_1/3Fe_1/3Mn_1/3O₂ Cathode Materials for Sodium-Ion Batteries Application