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Title: Amino-fulleropyrrolidines as electrotropic additives to enhance organic photovoltaics

Abstract

The synthesis, device fabrication, and electric poling of novel amino-functionalized fulleropyrrolidines in polymer solar cells is reported. Significantly improved device performances and retention stability were achieved with systematic variation in tether length, reaching PCE values in excess of 10%.

Authors:
 [1]; ORCiD logo [1];  [2];  [3]; ORCiD logo [3];  [1]; ORCiD logo [1]
  1. Department of Polymer Science and Engineering, University of Massachusetts, Amherst, USA
  2. Materials Research Lab, University of California, Santa Barbara, USA
  3. Department of Chemistry, University of Massachusetts, Amherst, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1463363
Grant/Contract Number:  
SC0001087
Resource Type:
Journal Article: Publisher's Accepted Manuscript
Journal Name:
Sustainable Energy & Fuels
Additional Journal Information:
Journal Name: Sustainable Energy & Fuels Journal Volume: 2 Journal Issue: 10; Journal ID: ISSN 2398-4902
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Karak, Supravat, Page, Zachariah A., Li, Shaoguang, Tinkham, Jonathan S., Lahti, Paul M., Duzhko, Volodimyr V., and Emrick, Todd. Amino-fulleropyrrolidines as electrotropic additives to enhance organic photovoltaics. United Kingdom: N. p., 2018. Web. doi:10.1039/C8SE00294K.
Karak, Supravat, Page, Zachariah A., Li, Shaoguang, Tinkham, Jonathan S., Lahti, Paul M., Duzhko, Volodimyr V., & Emrick, Todd. Amino-fulleropyrrolidines as electrotropic additives to enhance organic photovoltaics. United Kingdom. doi:10.1039/C8SE00294K.
Karak, Supravat, Page, Zachariah A., Li, Shaoguang, Tinkham, Jonathan S., Lahti, Paul M., Duzhko, Volodimyr V., and Emrick, Todd. Mon . "Amino-fulleropyrrolidines as electrotropic additives to enhance organic photovoltaics". United Kingdom. doi:10.1039/C8SE00294K.
@article{osti_1463363,
title = {Amino-fulleropyrrolidines as electrotropic additives to enhance organic photovoltaics},
author = {Karak, Supravat and Page, Zachariah A. and Li, Shaoguang and Tinkham, Jonathan S. and Lahti, Paul M. and Duzhko, Volodimyr V. and Emrick, Todd},
abstractNote = {The synthesis, device fabrication, and electric poling of novel amino-functionalized fulleropyrrolidines in polymer solar cells is reported. Significantly improved device performances and retention stability were achieved with systematic variation in tether length, reaching PCE values in excess of 10%.},
doi = {10.1039/C8SE00294K},
journal = {Sustainable Energy & Fuels},
number = 10,
volume = 2,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on August 8, 2019
Publisher's Accepted Manuscript

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Works referenced in this record:

Density‐functional thermochemistry. III. The role of exact exchange
journal, April 1993

  • Becke, Axel D.
  • The Journal of Chemical Physics, Vol. 98, Issue 7, p. 5648-5652
  • DOI: 10.1063/1.464913