skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Surface Engineering of Nanostructured Energy Materials

Journal Article · · Advanced Materials

Abstract All nanostructures share a common feature of large surface‐to‐volume ratio, which makes surface engineering a vital tool for exploring their new and important applications in many different areas. Particularly, inorganic nanostructures represent a class of intriguing catalysts that can find wide uses in energy conversion, energy storage, and environmental remediation. Here, a number of surface engineering strategies, including morphology control, defect incorporation, and interface manipulation for tailoring the shape, facet, defect, interfacial property, and composition of nanostructures, aiming at controlling the chemical and physical properties such as energy bandgap and surface energy toward great enhancement in catalytic performance, are discussed.

Research Organization:
Univ. of California, Riverside, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC); Research Corporation for Science Advancement; DuPont; American Chemical Society
Grant/Contract Number:
SC0002247; DE‐SC0002247
OSTI ID:
1610680
Alternate ID(s):
OSTI ID: 1461355
Journal Information:
Advanced Materials, Vol. 30, Issue 48; ISSN 0935-9648
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 48 works
Citation information provided by
Web of Science

References (70)

A Highly Active Titanium Dioxide Based Visible-Light Photocatalyst with Nonmetal Doping and Plasmonic Metal Decoration journal June 2011
Heterogeneous photocatalyst materials for water splitting journal January 2009
Ligand-Exchange Assisted Formation of Au/TiO 2 Schottky Contact for Visible-Light Photocatalysis journal October 2014
Tailored synthesis of mesoporous TiO2 hollow nanostructures for catalytic applications journal January 2013
Creating coordinatively unsaturated metal sites in metal-organic-frameworks as efficient electrocatalysts for the oxygen evolution reaction: Insights into the active centers journal November 2017
Ca 2 Mn 2 O 5 as Oxygen-Deficient Perovskite Electrocatalyst for Oxygen Evolution Reaction journal October 2014
Plasma-Engraved Co 3 O 4 Nanosheets with Oxygen Vacancies and High Surface Area for the Oxygen Evolution Reaction journal March 2016
Photocatalytic Synthesis and Photovoltaic Application of Ag-TiO 2 Nanorod Composites journal October 2013
Solid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nanorods of CeO2 journal May 2017
Ultrathin Iron-Cobalt Oxide Nanosheets with Abundant Oxygen Vacancies for the Oxygen Evolution Reaction journal February 2017
Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides journal July 2001
Porous cobalt oxide nanoplates enriched with oxygen vacancies for oxygen evolution reaction journal January 2018
Hollow Micro-/Nanostructures: Synthesis and Applications journal November 2008
Ultrathin Spinel-Structured Nanosheets Rich in Oxygen Deficiencies for Enhanced Electrocatalytic Water Oxidation journal May 2015
Visible Light Activity and Photoelectrochemical Properties of Nitrogen-Doped TiO 2 journal December 2004
Self-Templated Fabrication of CoO-MoO 2 Nanocages for Enhanced Oxygen Evolution journal July 2017
The teraton challenge. A review of fixation and transformation of carbon dioxide journal January 2010
Defect science and engineering of liquid crystals under geometrical frustration journal January 2013
On the Origin of the Spectral Bands in the Visible Absorption Spectra of Visible-Light-Active TiO 2 Specimens Analysis and Assignments journal June 2009
Photocatalytic Color Switching of Transition Metal Hexacyanometalate Nanoparticles for High-Performance Light-Printable Rewritable Paper journal January 2017
Solar Water Splitting Cells journal November 2010
Synthesis and Assembly of Magnetite Nanocubes into Flux-Closure Rings journal May 2007
Epitaxial growth of hybrid nanostructures journal January 2018
Templated synthesis of nanostructured materials journal January 2013
Designed Formation of Co 3 O 4 /NiCo 2 O 4 Double-Shelled Nanocages with Enhanced Pseudocapacitive and Electrocatalytic Properties journal April 2015
Crystallinity control of TiO 2 hollow shells through resin-protected calcination for enhanced photocatalytic activity journal January 2015
Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics? journal December 2008
Increasing Solar Absorption for Photocatalysis with Black Hydrogenated Titanium Dioxide Nanocrystals journal January 2011
Efficient Photochemical Water Splitting by a Chemically Modified n-TiO2 journal September 2002
Environmental Applications of Semiconductor Photocatalysis journal January 1995
Seeded growth route to noble metal nanostructures journal January 2013
Origin of the different photoactivity of N -doped anatase and rutile TiO 2 journal August 2004
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results journal May 1995
Mesoporous Anatase Titania Hollow Nanostructures though Silica-Protected Calcination journal October 2011
Controllable Disorder Engineering in Oxygen-Incorporated MoS 2 Ultrathin Nanosheets for Efficient Hydrogen Evolution journal November 2013
Pits confined in ultrathin cerium(IV) oxide for studying catalytic centers in carbon monoxide oxidation journal November 2013
Chemical Transformation of Colloidal Nanostructures with Morphological Preservation by Surface-Protection with Capping Ligands journal March 2017
Enhanced Photoreversible Color Switching of Redox Dyes Catalyzed by Barium-Doped TiO 2 Nanocrystals journal January 2015
Self-Assembled Au/CdSe Nanocrystal Clusters for Plasmon-Mediated Photocatalytic Hydrogen Evolution journal May 2017
Shape control of CdSe nanocrystals journal March 2000
Synthesis, Properties, and Applications of Hollow Micro-/Nanostructures journal May 2016
Colloidal nanocrystal synthesis and the organic–inorganic interface journal September 2005
Is the Band Gap of Pristine TiO 2 Narrowed by Anion- and Cation-Doping of Titanium Dioxide in Second-Generation Photocatalysts? journal December 2006
Seed-Mediated Growth of Anatase TiO 2 Nanocrystals with Core–Antenna Structures for Enhanced Photocatalytic Activity journal August 2015
Enhancing Perovskite Electrocatalysis through Strain Tuning of the Oxygen Deficiency journal June 2016
Gold Nanocages: Synthesis, Properties, and Applications journal December 2008
Shape-Controlled Synthesis of Gold and Silver Nanoparticles journal December 2002
Toward Solar Fuels: Photocatalytic Conversion of Carbon Dioxide to Hydrocarbons journal February 2010
Control of the nanoscale crystallinity in mesoporous TiO 2 shells for enhanced photocatalytic activity journal January 2012
Controllable Synthesis of Mesoporous TiO 2 Hollow Shells: Toward an Efficient Photocatalyst journal March 2013
An autonomous photosynthetic device in which all charge carriers derive from surface plasmons journal February 2013
Selectivity on Etching: Creation of High-Energy Facets on Copper Nanocrystals for CO 2 Electrochemical Reduction journal March 2016
Edge Epitaxy of Two-Dimensional MoSe 2 and MoS 2 Nanosheets on One-Dimensional Nanowires journal June 2017
Heterogeneous photocatalysis journal January 1993
Electrocatalytic and homogeneous approaches to conversion of CO 2 to liquid fuels journal January 2009
Photocatalytic Self-Doped SnO 2− x Nanocrystals Drive Visible-Light-Responsive Color Switching journal June 2017
Controlled growth of high-density CdS and CdSe nanorod arrays on selective facets of two-dimensional semiconductor nanoplates journal March 2016
A Sulfated ZrO 2 Hollow Nanostructure as an Acid Catalyst in the Dehydration of Fructose to 5-Hydroxymethylfurfural journal September 2013
Construction of Evolutionary Tree for Morphological Engineering of Nanoparticles journal July 2009
Synergistic Effect between Metal-Nitrogen-Carbon Sheets and NiO Nanoparticles for Enhanced Electrochemical Water-Oxidation Performance journal July 2015
Gold nanorods and their plasmonic properties journal January 2013
Controllable Fabrication of Au Nanocups by Confined-Space Thermal Dewetting for OCT Imaging journal May 2017
Direct splitting of water under visible light irradiation with an oxide semiconductor photocatalyst journal December 2001
Additive-Free, Robust H 2 Production from H 2 O and DMF by Dehydrogenation Catalyzed by Cu/Cu 2 O Formed In Situ journal June 2017
Plasmonic-metal nanostructures for efficient conversion of solar to chemical energy journal November 2011
Ultrathin Spinel-Structured Nanosheets Rich in Oxygen Deficiencies for Enhanced Electrocatalytic Water Oxidation journal May 2015
Synergistic Effect between Metal-Nitrogen-Carbon Sheets and NiO Nanoparticles for Enhanced Electrochemical Water-Oxidation Performance journal July 2015
A Highly Active Titanium Dioxide Based Visible-Light Photocatalyst with Nonmetal Doping and Plasmonic Metal Decoration journal June 2011
Efficient Photochemical Water Splitting by a Chemically Modified n-TiO2. journal January 2003
Shape-Controlled Synthesis of Gold and Silver Nanoparticles. journal March 2003

Cited By (6)

Controlling Cell Behavior through the Design of Biomaterial Surfaces: A Focus on Surface Modification Techniques journal April 2019
Tuning Interfacial Structures for Better Catalysis of Water Electrolysis journal May 2019
Surface and Interface Engineering: Molybdenum Carbide–Based Nanomaterials for Electrochemical Energy Conversion journal September 2019
Development of biomineralization-inspired hybrids based on β-chitin and zinc hydroxide carbonate and their conversion into zinc oxide thin films journal January 2019
Mesoporous hollow black TiO 2 with controlled lattice disorder degrees for highly efficient visible-light-driven photocatalysis journal January 2019
Interfacial effects in supported catalysts for electrocatalysis journal January 2019