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Title: Chain Breakage in the Supercooled Liquid - Liquid Transition and Re-entry of the λ-transition in Sulfur

Journal Article · · Scientific Reports
ORCiD logo [1];  [2];  [3];  [4];  [5];  [3];  [3];  [3];  [3];  [4]
  1. Southwest Jiaotong Univ., Chengdu (China); Center for High Pressure and Technology Advanced Research, Shanghai (China)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
  3. Southwest Jiaotong Univ., Chengdu (China)
  4. Center for High Pressure and Technology Advanced Research, Shanghai (China); Carnegie Inst. of Washington, Argonne, IL (United States); Florida Intl Univ., Miami, FL (United States)
  5. Brookhaven National Lab. (BNL), Upton, NY (United States)

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
National Science Foundation of China; Fundamental Research Funds for the Central Universities; USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-06CH11357; SC0012704
OSTI ID:
1461349
Alternate ID(s):
OSTI ID: 1483746
Report Number(s):
BNL-209509-2018-JAAM; 142941
Journal Information:
Scientific Reports, Vol. 8, Issue 1; ISSN 2045-2322
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 16 works
Citation information provided by
Web of Science

References (35)

Polymer content of sulfur quenched rapidly from the melt journal November 1970
Elemental sulfur journal June 1976
Understanding exceptional thermodynamic and kinetic stability of amorphous sulfur obtained by rapid compression journal January 2009
Two-dimensional detector software: From real detector to idealised image or two-theta scan journal January 1996
The glassy and supercooled state of elemental sulfur: Vibrational modes, structure metastability, and polymer content journal September 2013
Structure and function of a novel antioxidant peptide from the skin of tropical frogs journal February 2018
Beating Crystallization in Glass-Forming Metals by Millisecond Heating and Processing journal May 2011
Structure and dynamics of liquid sulphur journal January 1999
Structural Transition in Compressed Amorphous Sulfur journal February 2008
Deformation-Induced Linear Chain−Ring Transition and Crystallization of Living Polymer Sulfur journal December 2007
The structural properties of liquid and quenched sulphur II journal May 1994
The Nature of the Glassy State and the Behavior of Liquids at Low Temperatures. journal October 1948
The Viscosity of Sulfur 1 journal April 1943
Pressure-induced solidifications of liquid sulfur below and above λ-transition journal April 2016
PDFgetX2: a GUI-driven program to obtain the pair distribution function from X-ray powder diffraction data journal July 2004
The structural properties of liquid and quenched sulfur journal December 1988
The glass transition temperature of polymeric sulphur journal January 1963
The density of liquid sulfur near the polymerization temperature journal February 1992
X‐Ray Diffraction in Crystals, Imperfect Crystals, and Amorphous Bodies journal April 1964
Liquid sulfur: Local-order evidence of a polymerization transition journal February 1990
High pressure jump apparatus for measuring Grűneisen parameter of NaCl and studying metastable amorphous phase of poly (ethylene terephthalate) journal May 2005
Density‐functional thermochemistry. III. The role of exact exchange journal April 1993
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density text January 1988
Origin of the λ Transition in Liquid Sulfur journal July 2007
Probing the sulfur polymerization transition in situ with Raman spectroscopy journal May 2003
Chain-ring transition during exothermic "melting" in amorphous sulfur journal December 2014
Pressure and Time Dependences of the Supercooled Liquid-to-Liquid Transition in Sulfur journal February 2016
Vibrational dynamics and stability of the high-pressure chain and ring phases in S and Se journal February 2007
Optical absorption spectra of liquid sulphur over a wide absorption range journal July 1994
Raman spectroscopy of sulfur, sulfur-selenium, and sulfur-arsenic mixtures journal November 1968
Chain breakage in liquid sulfur at high pressures and high temperatures journal May 2014
Power-law scaling and fractal nature of medium-range order in metallic glasses journal December 2008
Universal Fractional Noncubic Power Law for Density of Metallic Glasses journal May 2014
Novel chain structures in group VI elements journal January 2005
X-Ray Diffraction in Crystals, Imperfect Crystals, and Amorphous Bodies. journal January 1965

Cited By (5)

A Study of the Pressure-Induced Solidification of Polymers journal August 2018
Structural change in liquid sulphur from chain polymeric liquid to atomic simple liquid under high pressure journal March 2019
Broadband, high-resolution Raman observations from a double-echelle spatial heterodyne Raman spectrometer journal January 2018
Development of a spatial heterodyne Raman spectrometer with echelle-mirror structure journal January 2018
Low frequency Raman Spectroscopy for micron-scale and in vivo characterization of elemental sulfur in microbial samples journal May 2019

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