YCrWO6: Polar and Magnetic Oxide with CaTa2O6-Related Structure

Kim, Sun Woo; Emge, Thomas J.; Deng, Zheng; Uppuluri, Ritesh; Collins, Liam; Lapidus, Saul H.; Segre, Carlo U.; Croft, Mark; Jin, Changqing; Gopalan, Venkatraman; Kalinin, Sergei V.; Greenblatt, Martha

doi:10.1021/acs.chemmater.7b04941

Title: YCrWO₆: Polar and Magnetic Oxide with CaTa₂O₆-Related Structure

Journal Article · Fri Jan 05 00:00:00 EST 2018 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.7b04941· OSTI ID:1422536

^[1]; Emge, Thomas J. ^[1]; Deng, Zheng ^[2]; Uppuluri, Ritesh ^[3];

^[4]; Lapidus, Saul H. ^[5];

^[6]; Croft, Mark ^[7]; Jin, Changqing ^[2]; Gopalan, Venkatraman ^[8];

^[4];

^[1]

Rutgers Univ., Piscataway, NJ (United States). Dept. of Chemistry and Chemical Biology
Chinese Academy of Sciences (CAS), Beijing (China). Inst. of Physics. Beijing National Lab. for Condensed Matter Physics (BNLCP-CAS)
Pennsylvania State Univ., University Park, PA (United States). Dept. of Chemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS), Inst. for Functional Imaging Materials
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Illinois Inst. of Technology, Chicago, IL (United States). Center for Synchrotron Radiation Research and Instrumentation, Dept. of Physics
Rutgers Univ., Piscataway, NJ (United States). Dept. of Physics and Astronomy
Pennsylvania State Univ., University Park, PA (United States). Dept. of Material Sciences and Engineering

A new polar and magnetic oxide, YCrWO6, was successfully synthesized and characterized. YCrWO6 crystallizes in polar orthorhombic space group Pna2(1) (no. 33) of edge-sharing dimers of CrO6 and WO6 octahedra, which are connected by corner-sharing to form a three-dimensional framework structure with Y3+ cations located in the channels. The structure of YCrWO6 is related to that of CaTa2O6; however, the ordering of Cr3+ and W6+ in the octahedral sites breaks the inversion symmetry of the parent CaTa2O6 structure. X-ray absorption near edge spectroscopy of YCrWO6 confirmed the oxidation state of Cr3+ and W6+. Temperature-dependent optical second harmonic generation measurements on YCrWO6 confirmed the noncentrosymmetric character and evidenced a noncentrosymmetric-to-centrosymmetric phase transition above 800 degrees C. Piezoresponse force microscopy measurements on YCrWO6 at room temperature show strong piezoelectric domains. Magnetic measurements of YCrWO6 indicate antiferromagnetic order at TN of similar to 22 K with Weiss temperature of -34.66 K.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Argonne National Lab. (ANL), Argonne, IL (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Contributing Organization:: Columbia Univ., New York, NY (United States)

Grant/Contract Number:: AC05-00OR22725; AC02-06CH11357; DMR-1420620; DMR-1507252; SC0012704

OSTI ID:: 1422536

Alternate ID(s):: OSTI ID: 1461302

Journal Information:: Chemistry of Materials, Vol. 30, Issue 3; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 17 works

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