Nanoparticle Assembly at Liquid–Liquid Interfaces: From the Nanoscale to Mesoscale

Shi, Shaowei; Russell, Thomas P.

doi:10.1002/adma.201800714

Title: Nanoparticle Assembly at Liquid–Liquid Interfaces: From the Nanoscale to Mesoscale

Abstract

Abstract In the past few decades, novel syntheses of a wide range of nanoparticles (NPs) with well‐defined chemical composition and structure have opened tremendous opportunities in areas ranging from optical and electronic devices to biomedical markers. Controlling the assembly of such well‐defined NPs is important to effectively harness their unique properties. The assembly of NPs at liquid–liquid interfaces is becoming a central topic both in surface and colloid science. Hierarchical structures, including 2D films, 3D capsules, and structured liquids, have been generating significant interest and are showing promise for physical, chemical, and biological applications. Here, a brief overview of the development of the self‐assembly of NPs at liquid–liquid interfaces is provided, from theory to experiment, from synthetic NPs to bio‐nanoparticles, from water–oil to water–water, and from “liquid‐like” to “solid‐like” assemblies.

Authors:

Shi, Shaowei ^[1];

^[2]

Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical Technology Beijing 100029 China
Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical Technology Beijing 100029 China, Department of Polymer Science and Engineering University of Massachusetts Amherst MA 01003 USA, Materials Sciences Division Lawrence Berkeley National Laboratory 1 Cyclotron Road Berkeley CA 94720 USA

Publication Date:: Mon Jul 23 00:00:00 EDT 2018

Sponsoring Org.:: USDOE

OSTI Identifier:: 1461222

Grant/Contract Number:: DE‐AC02‐05‐CH11231

Resource Type:: Journal Article: Publisher's Accepted Manuscript

Journal Name:: Advanced Materials

Additional Journal Information:: Journal Name: Advanced Materials Journal Volume: 30 Journal Issue: 44; Journal ID: ISSN 0935-9648

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Shi, Shaowei, and Russell, Thomas P. Nanoparticle Assembly at Liquid–Liquid Interfaces: From the Nanoscale to Mesoscale.  Germany: N. p., 2018. 
        Web.  doi:10.1002/adma.201800714.

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                    Shi, Shaowei, & Russell, Thomas P. Nanoparticle Assembly at Liquid–Liquid Interfaces: From the Nanoscale to Mesoscale.  Germany.  https://doi.org/10.1002/adma.201800714

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                    Shi, Shaowei, and Russell, Thomas P. 2018.  
        "Nanoparticle Assembly at Liquid–Liquid Interfaces: From the Nanoscale to Mesoscale".  Germany.  https://doi.org/10.1002/adma.201800714.

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@article{osti_1461222,

  title        = {Nanoparticle Assembly at Liquid–Liquid Interfaces: From the Nanoscale to Mesoscale},

  author       = {Shi, Shaowei and Russell, Thomas P.},

  abstractNote = {Abstract In the past few decades, novel syntheses of a wide range of nanoparticles (NPs) with well‐defined chemical composition and structure have opened tremendous opportunities in areas ranging from optical and electronic devices to biomedical markers. Controlling the assembly of such well‐defined NPs is important to effectively harness their unique properties. The assembly of NPs at liquid–liquid interfaces is becoming a central topic both in surface and colloid science. Hierarchical structures, including 2D films, 3D capsules, and structured liquids, have been generating significant interest and are showing promise for physical, chemical, and biological applications. Here, a brief overview of the development of the self‐assembly of NPs at liquid–liquid interfaces is provided, from theory to experiment, from synthetic NPs to bio‐nanoparticles, from water–oil to water–water, and from “liquid‐like” to “solid‐like” assemblies.},

  doi          = {10.1002/adma.201800714},

  url          = {https://www.osti.gov/biblio/1461222},
  journal      = {Advanced Materials},

  issn         = {0935-9648},

  number       = 44,

  volume       = 30,

  place        = {Germany},

  year         = {Mon Jul 23 00:00:00 EDT 2018},

  month        = {Mon Jul 23 00:00:00 EDT 2018}

}

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Title: Nanoparticle Assembly at Liquid–Liquid Interfaces: From the Nanoscale to Mesoscale

Abstract

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Interfacial Assembly of Turnip Yellow Mosaic Virus Nanoparticles journal, May 2009

Interfacial assembly of protein–polymer nano-conjugates into stimulus-responsive biomimetic protocells journal, July 2013

Influence of the Protein Particle Morphology and Partitioning on the Behavior of Particle-Stabilized Water-in-Water Emulsions journal, July 2016

Nonspherical Colloidosomes with Multiple Compartments from Double Emulsions journal, September 2009

Synthesis of polyaniline/nano-CeO2 composite microspheres via a solid-stabilized emulsion route journal, July 2005

Bijels formed by direct mixing journal, January 2017

Oil–water interfacial self-assembly: a novel strategy for nanofilm and nanodevice fabrication journal, January 2012

Dissolution Arrest and Stability of Particle-Covered Bubbles journal, October 2007

Bicontinuous emulsions stabilized solely by colloidal particles journal, November 2007

Janus Microspheres for a Highly Flexible and Impregnable Water-Repelling Interface journal, March 2010

Design and Construction of Higher-Order Structure and Function in Proteinosome-Based Protocells journal, June 2014

Aqueous Emulsion Droplets Stabilized by Lipid Vesicles as Microcompartments for Biomimetic Mineralization journal, October 2015

Stepwise Size-Selective Extraction of Carboxylate-Modified Gold Nanoparticles from an Aqueous Suspension into Toluene with Tetraoctylammonium Cations journal, December 2001

Ultrathin Cross-Linked Nanoparticle Membranes journal, October 2003

Magnetic hydrogels with supracolloidal structures prepared by suspension polymerization stabilized by Fe2O3 nanoparticles journal, January 2010

High-Performance NiCo2O4 Nanofilm Photodetectors Fabricated by an Interfacial Self-Assembly Strategy journal, March 2011

Stepwise interfacial self-assembly of nanoparticles via specific DNA pairing journal, January 2007

Self-Regulated Nanoparticle Assembly at Liquid/Liquid Interfaces: A Route to Adaptive Structuring of Liquids journal, August 2017

A Universal Approach for the Self-Assembly of Hydrophilic Nanoparticles into Ordered Monolayer Films at a Toluene/Water Interface journal, April 2006

Self-Assembled Nanofilm of Monodisperse Cobalt Hydroxide Hexagonal Platelets: Topotactic Conversion into Oxide and Resistive Switching journal, December 2010

Nanoparticle Assembly and Transport at Liquid-Liquid Interfaces journal, January 2003

General Fabrication of Monolayer SnO2 Nanonets for High-Performance Ultraviolet Photodetectors journal, January 2012

Interfacial Structuring in a Phase-Separating Mixed Biopolymer Solution Containing Colloidal Particles journal, February 2009

Nanoparticle-Stabilized Double Emulsions and Compressed Droplets journal, November 2011

Reconfigurable Microfluidic Droplets Stabilized by Nanoparticle Surfactants journal, February 2018

Mixed biopolymer aqueous solutions – phase behaviour and rheology journal, December 2010

Effect of Nanoparticle Surfactants on the Breakup of Free-Falling Water Jets during Continuous Processing of Reconfigurable Structured Liquid Droplets journal, April 2017

Celebrating Soft Matter’s 10th Anniversary: Toward jamming by design journal, January 2015

Liquid Letters journal, January 2018

Formation and Size Tuning of Colloidal Microcapsules via Host−Guest Molecular Recognition at the Liquid−Liquid Interface † journal, December 2009

Membrane-mediated cascade reactions by enzyme–polymer proteinosomes journal, January 2014

Control of contact angles at the oil-water-solid interfaces. Emulsions stabilized by solid particles (BaSO4) journal, January 1954

Self-Assembly and Cross-linking of FePt Nanoparticles at Planar and Colloidal Liquid−Liquid Interfaces journal, August 2008

Single-step fabrication of multi-compartmentalized biphasic proteinosomes journal, January 2017

Magnetic Colloidosomes Derived from Nanoparticle Interfacial Self-Assembly journal, May 2005

Self-Assembly Process of Soft Ferritin-PNIPAAm Conjugate Bionanoparticles at Polar–Apolar Interfaces journal, December 2012

Pickering emulsion templated soft capsules by self-assembling cross-linkable ferritin–polymer conjugates journal, January 2011

Drying Droplets: A Window into the Behavior of Nanorods at Interfaces journal, July 2007

Crosslinked Capsules of Quantum Dots by Interfacial Assembly and Ligand Crosslinking journal, September 2005

Stabilization of Water-in-Water Emulsions by Addition of Protein Particles journal, August 2013

Reversible Transference of Au Nanoparticles across the Water and Toluene Interface: A Langmuir Type Adsorption Mechanism journal, February 2001

Making a Robust Interfacial Scaffold: Bijel Rheology and its Link to Processability journal, September 2012

Stepwise Directing of Nanocrystals to Self-Assemble at Water/Oil Interfaces journal, December 2006

Close-Packed Two-Dimensional Silver Nanoparticle Arrays: Quadrupolar and Dipolar Surface Plasmon Resonance Coupling journal, March 2015

The water/oil interface: the emerging horizon for self-assembly of nanoparticles journal, January 2005

Double Emulsion-Templated Nanoparticle Colloidosomes with Selective Permeability journal, August 2008

Carboxylated Fullerene at the Oil/Water Interface journal, April 2017

Microcapsules of PEGylated Gold Nanoparticles Prepared by Fluid−Fluid Interfacial Assembly journal, February 2007

Liquid Tubule Formation and Stabilization Using Cellulose Nanocrystal Surfactants journal, September 2017

Colloidosomes: Selectively Permeable Capsules Composed of Colloidal Particles journal, November 2002

Colloidal Particles at a Range of Fluid–Fluid Interfaces journal, May 2017

Novel, Robust, and Versatile Bijels of Nitromethane, Ethanediol, and Colloidal Silica: Capsules, Sub-Ten-Micrometer Domains, and Mechanical Properties journal, May 2011

Simple shaking yields bicontinuity journal, October 2017

Nanoparticle Assembly at Fluid Interfaces: Structure and Dynamics journal, January 2005

Dual-responsive supramolecular colloidal microcapsules from cucurbit[8]uril molecular recognition in microfluidic droplets journal, January 2016

Assembly and phase transitions of colloidal crystals journal, January 2016

One-Step Fabrication of Supramolecular Microcapsules from Microfluidic Droplets journal, February 2012

Particle-size effects in the formation of bicontinuous Pickering emulsions journal, September 2015

Synthesis of Nano/Microstructures at Fluid Interfaces journal, December 2010

Suspension polymerization based on inverse Pickering emulsion droplets for thermo-sensitive hybrid microcapsules with tunable supracolloidal structures journal, June 2009

Bioreactor droplets from liposome-stabilized all-aqueous emulsions journal, August 2014

On the kinetics of nanoparticle self-assembly at liquid/liquid interfaces journal, January 2007

Colloidal Assembly Route for Responsive Colloidosomes with Tunable Permeability journal, September 2007

Linker-Molecule-Free Gold Nanorod Layer-by-Layer Films for Surface-Enhanced Raman Scattering journal, November 2007

Pickering Stabilized Miniemulsion Polymerization: Preparation of Clay Armored Latexes journal, September 2005

Catalytic Microcapsules Assembled from Enzyme-Nanoparticle Conjugates at Oil-Water Interfaces journal, June 2009

Water-in-Water Emulsions Stabilized by Nanoplates journal, September 2015

Molecular recognition at the liquid–liquid interface of colloidal microcapsules
journal, January 2009

Supramolecular colloidosomes: fabrication, characterisation and triggered release of cargo
journal, January 2014

Hollow microspheres with covalent-bonded colloidal and polymeric shell by Pickering emulsion polymerization
journal, February 2011

Enhanced Stabilization of Emulsions Due to Surfactant-Induced Nanoparticle Flocculation
journal, July 2007

Investigation of internal microstructure and thermo-responsive properties of composite PNIPAM/silica microcapsules
journal, June 2010

A New Technique for the Spontaneous Growth of Colloidal Nanoparticle Superlattices
journal, March 1999

Structured Liquids with pH-Triggered Reconfigurability
journal, May 2016

Assembly of Latex Particles by Using Emulsion Droplets as Templates. 1. Microstructured Hollow Spheres
journal, January 1996

Phase Transfer of Gold Nanoparticles across a Water/Oil Interface by Stoichiometric Ion-Pair Formation on Particle Surfaces
journal, December 2000

Emulsions stabilised solely by colloidal particles
journal, February 2003

Interfacial Assembly of Turnip Yellow Mosaic Virus Nanoparticles
journal, May 2009

Interfacial assembly of protein–polymer nano-conjugates into stimulus-responsive biomimetic protocells
journal, July 2013

Influence of the Protein Particle Morphology and Partitioning on the Behavior of Particle-Stabilized Water-in-Water Emulsions
journal, July 2016

Nonspherical Colloidosomes with Multiple Compartments from Double Emulsions
journal, September 2009

Synthesis of polyaniline/nano-CeO2 composite microspheres via a solid-stabilized emulsion route
journal, July 2005

Bijels formed by direct mixing
journal, January 2017

Oil–water interfacial self-assembly: a novel strategy for nanofilm and nanodevice fabrication
journal, January 2012

Dissolution Arrest and Stability of Particle-Covered Bubbles
journal, October 2007

Bicontinuous emulsions stabilized solely by colloidal particles
journal, November 2007

Janus Microspheres for a Highly Flexible and Impregnable Water-Repelling Interface
journal, March 2010

Design and Construction of Higher-Order Structure and Function in Proteinosome-Based Protocells
journal, June 2014

Aqueous Emulsion Droplets Stabilized by Lipid Vesicles as Microcompartments for Biomimetic Mineralization
journal, October 2015

Stepwise Size-Selective Extraction of Carboxylate-Modified Gold Nanoparticles from an Aqueous Suspension into Toluene with Tetraoctylammonium Cations
journal, December 2001

Ultrathin Cross-Linked Nanoparticle Membranes
journal, October 2003

Magnetic hydrogels with supracolloidal structures prepared by suspension polymerization stabilized by Fe2O3 nanoparticles
journal, January 2010

High-Performance NiCo2O4 Nanofilm Photodetectors Fabricated by an Interfacial Self-Assembly Strategy
journal, March 2011

Stepwise interfacial self-assembly of nanoparticles via specific DNA pairing
journal, January 2007

Self-Regulated Nanoparticle Assembly at Liquid/Liquid Interfaces: A Route to Adaptive Structuring of Liquids
journal, August 2017

A Universal Approach for the Self-Assembly of Hydrophilic Nanoparticles into Ordered Monolayer Films at a Toluene/Water Interface
journal, April 2006

Self-Assembled Nanofilm of Monodisperse Cobalt Hydroxide Hexagonal Platelets: Topotactic Conversion into Oxide and Resistive Switching
journal, December 2010

Nanoparticle Assembly and Transport at Liquid-Liquid Interfaces
journal, January 2003

General Fabrication of Monolayer SnO2 Nanonets for High-Performance Ultraviolet Photodetectors
journal, January 2012

Interfacial Structuring in a Phase-Separating Mixed Biopolymer Solution Containing Colloidal Particles
journal, February 2009

Nanoparticle-Stabilized Double Emulsions and Compressed Droplets
journal, November 2011

Reconfigurable Microfluidic Droplets Stabilized by Nanoparticle Surfactants
journal, February 2018

Mixed biopolymer aqueous solutions – phase behaviour and rheology
journal, December 2010

Effect of Nanoparticle Surfactants on the Breakup of Free-Falling Water Jets during Continuous Processing of Reconfigurable Structured Liquid Droplets
journal, April 2017

Celebrating Soft Matter’s 10th Anniversary: Toward jamming by design
journal, January 2015

Liquid Letters
journal, January 2018

Formation and Size Tuning of Colloidal Microcapsules via Host−Guest Molecular Recognition at the Liquid−Liquid Interface ^†
journal, December 2009

Membrane-mediated cascade reactions by enzyme–polymer proteinosomes
journal, January 2014

Control of contact angles at the oil-water-solid interfaces. Emulsions stabilized by solid particles (BaSO4)
journal, January 1954

Self-Assembly and Cross-linking of FePt Nanoparticles at Planar and Colloidal Liquid−Liquid Interfaces
journal, August 2008

Single-step fabrication of multi-compartmentalized biphasic proteinosomes
journal, January 2017

Magnetic Colloidosomes Derived from Nanoparticle Interfacial Self-Assembly
journal, May 2005

Self-Assembly Process of Soft Ferritin-PNIPAAm Conjugate Bionanoparticles at Polar–Apolar Interfaces
journal, December 2012

Pickering emulsion templated soft capsules by self-assembling cross-linkable ferritin–polymer conjugates
journal, January 2011

Drying Droplets: A Window into the Behavior of Nanorods at Interfaces
journal, July 2007

Crosslinked Capsules of Quantum Dots by Interfacial Assembly and Ligand Crosslinking
journal, September 2005

Stabilization of Water-in-Water Emulsions by Addition of Protein Particles
journal, August 2013

Reversible Transference of Au Nanoparticles across the Water and Toluene Interface: A Langmuir Type Adsorption Mechanism
journal, February 2001

Making a Robust Interfacial Scaffold: Bijel Rheology and its Link to Processability
journal, September 2012

Stepwise Directing of Nanocrystals to Self-Assemble at Water/Oil Interfaces
journal, December 2006

Close-Packed Two-Dimensional Silver Nanoparticle Arrays: Quadrupolar and Dipolar Surface Plasmon Resonance Coupling
journal, March 2015

The water/oil interface: the emerging horizon for self-assembly of nanoparticles
journal, January 2005

Double Emulsion-Templated Nanoparticle Colloidosomes with Selective Permeability
journal, August 2008

Carboxylated Fullerene at the Oil/Water Interface
journal, April 2017

Microcapsules of PEGylated Gold Nanoparticles Prepared by Fluid−Fluid Interfacial Assembly
journal, February 2007

Liquid Tubule Formation and Stabilization Using Cellulose Nanocrystal Surfactants
journal, September 2017

Colloidosomes: Selectively Permeable Capsules Composed of Colloidal Particles
journal, November 2002

Colloidal Particles at a Range of Fluid–Fluid Interfaces
journal, May 2017

Novel, Robust, and Versatile Bijels of Nitromethane, Ethanediol, and Colloidal Silica: Capsules, Sub-Ten-Micrometer Domains, and Mechanical Properties
journal, May 2011

Simple shaking yields bicontinuity
journal, October 2017

Nanoparticle Assembly at Fluid Interfaces: Structure and Dynamics
journal, January 2005

Dual-responsive supramolecular colloidal microcapsules from cucurbit[8]uril molecular recognition in microfluidic droplets
journal, January 2016

Assembly and phase transitions of colloidal crystals
journal, January 2016

One-Step Fabrication of Supramolecular Microcapsules from Microfluidic Droplets
journal, February 2012

Particle-size effects in the formation of bicontinuous Pickering emulsions
journal, September 2015

Synthesis of Nano/Microstructures at Fluid Interfaces
journal, December 2010

Suspension polymerization based on inverse Pickering emulsion droplets for thermo-sensitive hybrid microcapsules with tunable supracolloidal structures
journal, June 2009

Bioreactor droplets from liposome-stabilized all-aqueous emulsions
journal, August 2014

On the kinetics of nanoparticle self-assembly at liquid/liquid interfaces
journal, January 2007

Colloidal Assembly Route for Responsive Colloidosomes with Tunable Permeability
journal, September 2007

Linker-Molecule-Free Gold Nanorod Layer-by-Layer Films for Surface-Enhanced Raman Scattering
journal, November 2007

Pickering Stabilized Miniemulsion Polymerization: Preparation of Clay Armored Latexes
journal, September 2005

Catalytic Microcapsules Assembled from Enzyme-Nanoparticle Conjugates at Oil-Water Interfaces
journal, June 2009

Water-in-Water Emulsions Stabilized by Nanoplates
journal, September 2015

Synthesis of Temperature-Responsive Poly( N -isopropyl acrylamide)/Poly(methyl methacrylate)/Silica Hybrid Capsules from Inverse Pickering Emulsion Polymerization and Their Application in Controlled Drug Release
journal, June 2010

Hollow microspheres with binary colloidal and polymeric membrane: Effect of polymer and particle concentrations
journal, January 2010

Hybrid Capsules via Self-Assembly of Thermoresponsive and Interfacially Active Bionanoparticle-Polymer Conjugates
journal, March 2011