A manganese–hydrogen battery with potential for grid-scale energy storage

Chen, Wei; Li, Guodong; Pei, Allen; Li, Yuzhang; Liao, Lei; Wang, Hongxia; Wan, Jiayu; Liang, Zheng; Chen, Guangxu; Zhang, Hao; Wang, Jiangyan; Cui, Yi

doi:10.1038/s41560-018-0147-7

Title: A manganese–hydrogen battery with potential for grid-scale energy storage

Journal Article · Mon Apr 30 00:00:00 EDT 2018 · Nature Energy

DOI:https://doi.org/10.1038/s41560-018-0147-7· OSTI ID:1461183

Chen, Wei ^[1]; Li, Guodong ^[2];

^[1]; Li, Yuzhang ^[1]; Liao, Lei ^[1]; Wang, Hongxia ^[1]; Wan, Jiayu ^[1]; Liang, Zheng ^[1]; Chen, Guangxu ^[1]; Zhang, Hao ^[1]; Wang, Jiangyan ^[1]; Cui, Yi ^[3]

Stanford Univ., Stanford, CA (United States)
Stanford Univ., Stanford, CA (United States); Chinese Academy of Sciences (CAS) Key Lab of Nanosystem and Hierarchy Fabrication, Beijing (China)
Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)

Batteries including lithium-ion, lead–acid, redox-flow and liquid-metal batteries show promise for grid-scale storage, but they are still far from meeting the grid's storage needs such as low cost, long cycle life, reliable safety and reasonable energy density for cost and footprint reduction. Here, we report a rechargeable manganese–hydrogen battery, where the cathode is cycled between soluble Mn²⁺ and solid MnO₂ with a two-electron reaction, and the anode is cycled between H₂ gas and H₂O through well-known catalytic reactions of hydrogen evolution and oxidation. This battery chemistry exhibits a discharge voltage of ~1.3 V, a rate capability of 100 mA cm^–2 (36 s of discharge) and a lifetime of more than 10,000 cycles without decay. We achieve a gravimetric energy density of ~139 Wh kg^–1 (volumetric energy density of ~210 Wh l^–1), with the theoretical gravimetric energy density of ~174 Wh kg^–1 (volumetric energy density of ~263 Wh l^–1) in a 4 M MnSO₄ electrolyte. In conclusion, the manganese–hydrogen battery involves low-cost abundant materials and has the potential to be scaled up for large-scale energy storage.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: SLAC National Accelerator Lab., Menlo Park, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1461183

Journal Information:: Nature Energy, Vol. 3, Issue 5; ISSN 2058-7546

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 221 works

Citation information provided by
Web of Science

References (31)

Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
MoS₂ Nanoparticles Grown on Graphene An Advanced Catalyst for the Hydrogen Evolution Reaction Li, Yanguang; Wang, Hailiang; Xie, Liming Journal of the American Chemical Society, Vol. 133, Issue 19, p. 7296-7299 https://doi.org/10.1021/ja201269b	journal	May 2011
Nanostructured Mn-based oxides for electrochemical energy storage and conversion Zhang, Kai; Han, Xiaopeng; Hu, Zhe Chemical Society Reviews, Vol. 44, Issue 3 https://doi.org/10.1039/C4CS00218K	journal	January 2015
Lithium–antimony–lead liquid metal battery for grid-level energy storage Wang, Kangli; Jiang, Kai; Chung, Brice Nature, Vol. 514, Issue 7522 https://doi.org/10.1038/nature13700	journal	September 2014
Manganese oxide-based materials as electrochemical supercapacitor electrodes Wei, Weifeng; Cui, Xinwei; Chen, Weixing Chem. Soc. Rev., Vol. 40, Issue 3 https://doi.org/10.1039/C0CS00127A	journal	January 2011
New insights into the electrochemical hydrogen oxidation and evolution reaction mechanism Durst, J.; Siebel, A.; Simon, C. Energy Environ. Sci., Vol. 7, Issue 7 https://doi.org/10.1039/C4EE00440J	journal	January 2014
Nanostructured tungsten carbide catalysts for polymer electrolyte fuel cells Yang, X. G.; Wang, C. Y. Applied Physics Letters, Vol. 86, Issue 22 https://doi.org/10.1063/1.1941473	journal	May 2005
Development of Sodium-Sulfur Batteries Oshima, Taku; Kajita, Masaharu; Okuno, Akiyasu International Journal of Applied Ceramic Technology, Vol. 1, Issue 3 https://doi.org/10.1111/j.1744-7402.2004.tb00179.x	journal	July 2004
Recent Progress in Redox Flow Battery Research and Development Wang, Wei; Luo, Qingtao; Li, Bin Advanced Functional Materials, Vol. 23, Issue 8, p. 970-986 https://doi.org/10.1002/adfm.201200694	journal	September 2012
The Chemistry of Redox-Flow Batteries Noack, Jens; Roznyatovskaya, Nataliya; Herr, Tatjana Angewandte Chemie International Edition, Vol. 54, Issue 34 https://doi.org/10.1002/anie.201410823	journal	June 2015
A Nickel Metal Hydride Battery for Electric Vehicles Ovshinsky, S. R.; Fetcenko, M. A.; Ross, J. Science, Vol. 260, Issue 5105 https://doi.org/10.1126/science.260.5105.176	journal	April 1993
Controlled synthesis of nanostructured manganese oxide: crystalline evolution and catalytic activities Sun, Ming; Lan, Bang; Lin, Ting CrystEngComm, Vol. 15, Issue 35 https://doi.org/10.1039/c3ce40603b	journal	January 2013
Progress in electrical energy storage system: A critical review Chen, Haisheng; Cong, Thang Ngoc; Yang, Wei Progress in Natural Science, Vol. 19, Issue 3 https://doi.org/10.1016/j.pnsc.2008.07.014	journal	March 2009
Rechargeable batteries with aqueous electrolytes Beck, Fritz; Rüetschi, Paul Electrochimica Acta, Vol. 45, Issue 15-16 https://doi.org/10.1016/S0013-4686(00)00344-3	journal	May 2000
Electrolytic manganese dioxide (EMD): a perspective on worldwide production, reserves and its role in electrochemistry Biswal, Avijit; Chandra Tripathy, Bankim; Sanjay, Kali RSC Advances, Vol. 5, Issue 72 https://doi.org/10.1039/C5RA05892A	journal	January 2015
The path towards sustainable energy Chu, Steven; Cui, Yi; Liu, Nian Nature Materials, Vol. 16, Issue 1 https://doi.org/10.1038/nmat4834	journal	December 2016
The Role of Energy Storage in Development of Smart Grids Roberts, Bradford P.; Sandberg, Chet Proceedings of the IEEE, Vol. 99, Issue 6 https://doi.org/10.1109/JPROC.2011.2116752	journal	June 2011
On the Solubility of Manganous Sulphate Cottrell, F. G. The Journal of Physical Chemistry, Vol. 4, Issue 8 https://doi.org/10.1021/j150026a001	journal	November 1900
Liquid Metal Batteries: Past, Present, and Future Kim, Hojong; Boysen, Dane A.; Newhouse, Jocelyn M. Chemical Reviews, Vol. 113, Issue 3 https://doi.org/10.1021/cr300205k	journal	November 2012
Electrical Energy Storage for the Grid: A Battery of Choices Dunn, B.; Kamath, H.; Tarascon, J. -M. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1212741	journal	November 2011
Opportunities and challenges for a sustainable energy future Chu, Steven; Majumdar, Arun Nature, Vol. 488, Issue 7411, p. 294-303 https://doi.org/10.1038/nature11475	journal	August 2012
Charge Storage Mechanism of MnO ₂ Electrode Used in Aqueous Electrochemical Capacitor Toupin, Mathieu; Brousse, Thierry; Bélanger, Daniel Chemistry of Materials, Vol. 16, Issue 16 https://doi.org/10.1021/cm049649j	journal	August 2004
Reversible aqueous zinc/manganese oxide energy storage from conversion reactions Pan, Huilin; Shao, Yuyan; Yan, Pengfei Nature Energy, Vol. 1, Issue 5 https://doi.org/10.1038/nenergy.2016.39	journal	April 2016
Electricity storage for intermittent renewable sources Rugolo, Jason; Aziz, Michael J. Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee02542f	journal	January 2012
Hydrogen Oxidation and Evolution Reaction Kinetics on Platinum: Acid vs Alkaline Electrolytes Sheng, Wenchao; Gasteiger, Hubert A.; Shao-Horn, Yang Journal of The Electrochemical Society, Vol. 157, Issue 11 https://doi.org/10.1149/1.3483106	journal	January 2010
Rechargeable Lithium Batteries with Aqueous Electrolytes Li, W.; Dahn, J. R.; Wainwright, D. S. Science, Vol. 264, Issue 5162, p. 1115-1118 https://doi.org/10.1126/science.264.5162.1115	journal	May 1994
A membrane-free lithium/polysulfide semi-liquid battery for large-scale energy storage Yang, Yuan; Zheng, Guangyuan; Cui, Yi Energy & Environmental Science, Vol. 6, Issue 5 https://doi.org/10.1039/c3ee00072a	journal	January 2013
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction Popczun, Eric J.; McKone, James R.; Read, Carlos G. Journal of the American Chemical Society, Vol. 135, Issue 25 https://doi.org/10.1021/ja403440e	journal	June 2013
Transition metal phosphide catalysts for hydrogen oxidation reaction Izhar, Shamsul; Nagai, Masatoshi Catalysis Today, Vol. 146, Issue 1-2 https://doi.org/10.1016/j.cattod.2009.01.036	journal	August 2009
A metal-free organic–inorganic aqueous flow battery Huskinson, Brian; Marshak, Michael P.; Suh, Changwon Nature, Vol. 505, Issue 7482, p. 195-198 https://doi.org/10.1038/nature12909	journal	January 2014

Cited By (22)

Fully Solar-Powered Uninterrupted Overall Water-Splitting Systems Zhang, Qichong; He, Bing; Tang, Lei Advanced Functional Materials, Vol. 29, Issue 9 https://doi.org/10.1002/adfm.201808889	journal	January 2019
Graphitic Nanocarbon with Engineered Defects for High‐Performance Potassium‐Ion Battery Anodes Zhang, Wenli; Ming, Jun; Zhao, Wenli Advanced Functional Materials, Vol. 29, Issue 35 https://doi.org/10.1002/adfm.201903641	journal	June 2019
A High‐Energy Aqueous Aluminum‐Manganese Battery He, Shiman; Wang, Jie; Zhang, Xu Advanced Functional Materials, Vol. 29, Issue 45 https://doi.org/10.1002/adfm.201905228	journal	September 2019
Commencing an Acidic Battery Based on a Copper Anode with Ultrafast Proton‐Regulated Kinetics and Superior Dendrite‐Free Property Liang, Guojin; Mo, Funian; Yang, Qi Advanced Materials, Vol. 31, Issue 52 https://doi.org/10.1002/adma.201905873	journal	November 2019
Commercialization of Lithium Battery Technologies for Electric Vehicles Zeng, Xiaoqiao; Li, Matthew; Abd El‐Hady, Deia Advanced Energy Materials, Vol. 9, Issue 27 https://doi.org/10.1002/aenm.201900161	journal	June 2019
A Novel Dendrite‐Free Mn ²⁺ /Zn ²⁺ Hybrid Battery with 2.3 V Voltage Window and 11000‐Cycle Lifespan Li, Ming; He, Qiu; Li, Zilan Advanced Energy Materials, Vol. 9, Issue 29 https://doi.org/10.1002/aenm.201901469	journal	June 2019
A Universal Principle to Design Reversible Aqueous Batteries Based on Deposition–Dissolution Mechanism Liang, Guojin; Mo, Funian; Li, Hongfei Advanced Energy Materials, Vol. 9, Issue 32 https://doi.org/10.1002/aenm.201901838	journal	July 2019
Membrane‐Free Zn/MnO ₂ Flow Battery for Large‐Scale Energy Storage Li, Guodong; Chen, Wei; Zhang, Hao Advanced Energy Materials, Vol. 10, Issue 9 https://doi.org/10.1002/aenm.201902085	journal	January 2020
Solvent‐Free Synthesis of Thin, Flexible, Nonflammable Garnet‐Based Composite Solid Electrolyte for All‐Solid‐State Lithium Batteries Jiang, Taoli; He, Pingge; Wang, Guoxu Advanced Energy Materials, Vol. 10, Issue 12 https://doi.org/10.1002/aenm.201903376	journal	March 2020
An Electrolytic Zn–MnO ₂ Battery for High‐Voltage and Scalable Energy Storage Chao, Dongliang; Zhou, Wanhai; Ye, Chao Angewandte Chemie, Vol. 131, Issue 23 https://doi.org/10.1002/ange.201904174	journal	May 2019
An Electrolytic Zn–MnO ₂ Battery for High‐Voltage and Scalable Energy Storage Chao, Dongliang; Zhou, Wanhai; Ye, Chao Angewandte Chemie International Edition, Vol. 58, Issue 23 https://doi.org/10.1002/anie.201904174	journal	June 2019
Recent Progress in Polysulfide Redox‐Flow Batteries Zhang, Sanpei; Guo, Wenjuan; Yang, Fengchang Batteries & Supercaps, Vol. 2, Issue 7 https://doi.org/10.1002/batt.201900056	journal	June 2019
Water in Rechargeable Multivalent-Ion Batteries: An Electrochemical Pandora's Box Manalastas, William; Kumar, Sonal; Verma, Vivek ChemSusChem, Vol. 12, Issue 2 https://doi.org/10.1002/cssc.201801523	journal	January 2019
MnO ₂ Nanosheet‐Assembled Hollow Polyhedron Grown on Carbon Cloth for Flexible Aqueous Zinc‐Ion Batteries Wu, Fangfang; Gao, Xiaobin; Xu, Xilian ChemSusChem, Vol. 13, Issue 6 https://doi.org/10.1002/cssc.201903006	journal	March 2020
Biomimetic organohydrogel electrolytes for high‐environmental adaptive energy storage devices Mo, Funian; Liang, Guojin; Wang, Donghong EcoMat, Vol. 1, Issue 1 https://doi.org/10.1002/eom2.12008	journal	December 2019
One‐dimensional and two‐dimensional synergized nanostructures for high‐performing energy storage and conversion Li, Xin; Wang, John InfoMat, Vol. 2, Issue 1 https://doi.org/10.1002/inf2.12040	journal	November 2019
An Integrated Approach Toward Renewable Energy Storage Using Rechargeable Ag@Ni _0.67 Co _0.33 S‐Based Hybrid Supercapacitors Nagaraju, Goli; Sekhar, S. Chandra; Ramulu, Bhimanaboina Small, Vol. 15, Issue 16 https://doi.org/10.1002/smll.201805418	journal	March 2019
Ultra-High Mass-Loading Cathode for Aqueous Zinc-Ion Battery Based on Graphene-Wrapped Aluminum Vanadate Nanobelts Zhang, Wenyu; Liang, Shuquan; Fang, Guozhao Nano-Micro Letters, Vol. 11, Issue 1 https://doi.org/10.1007/s40820-019-0300-2	journal	August 2019
Multifunctional inorganic nanomaterials for energy applications Wang, Huilin; Liang, Xitong; Wang, Jiutian Nanoscale, Vol. 12, Issue 1 https://doi.org/10.1039/c9nr07008g	journal	January 2020
A novel aqueous sodium–manganese battery system for energy storage Feng, Yazhi; Zhang, Qiu; Liu, Shuang Journal of Materials Chemistry A, Vol. 7, Issue 14 https://doi.org/10.1039/c9ta00474b	journal	January 2019
A generalized approach for selecting solar energy system configurations for a wide range of applications Doron, Pinchas; Karni, Jacob; Slocum, Alexander MRS Energy & Sustainability, Vol. 6 https://doi.org/10.1557/mre.2019.10	journal	January 2019
Suppressing Manganese Dissolution in Potassium Manganate with Rich Oxygen Defects Engaged High‐Energy‐Density and Durable Aqueous Zinc‐Ion Battery Fang, Guozhao; Zhu, Chuyu; Chen, Minghui Advanced Functional Materials, Vol. 29, Issue 15 https://doi.org/10.1002/adfm.201808375	journal	February 2019

Similar Records

Nickel-hydrogen batteries for large-scale energy storage

Journal Article · Mon Oct 29 00:00:00 EDT 2018 · Proceedings of the National Academy of Sciences of the United States of America · OSTI ID:1461183

Chen, Wei; Jin, Yang; Zhao, Jie; +2 more

High performance nickel-metal hydride and lithium-ion batteries

Conference · Wed Dec 31 00:00:00 EST 1997 · OSTI ID:1461183

Koehler, U; Kruger, F J; Kuempers, J; +3 more

Molten Lithium-Brass/Zinc Chloride System as High-Performance and Low-Cost Battery

Journal Article · Tue Sep 15 00:00:00 EDT 2020 · Matter (Online) · OSTI ID:1461183

Liu, Kai; Lang, Jialiang; Yang, Minzheng; +10 more

Related Subjects

25 ENERGY STORAGE

Title: A manganese–hydrogen battery with potential for grid-scale energy storage

Citation Formats

References (31)

Cited By (22)

Similar Records

Related Subjects