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Title: Facile incorporation of technetium into magnetite, magnesioferrite, and hematite by formation of ferrous nitrate in situ : precursors to iron oxide nuclear waste forms

Abstract

The fission product, 99 Tc, presents significant challenges to the long-term disposal of nuclear waste due to its long half-life, high fission yield, and to the environmental mobility of pertechnetate (TcO 4 ), the stable Tc species in aerobic environments.

Authors:
ORCiD logo [1]; ORCiD logo [2]
  1. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA
  2. Geosciences Division, Pacific Northwest National Laboratory, Richland, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Office of Environmental Management (EM)
OSTI Identifier:
1460584
Grant/Contract Number:  
AC02-05CH11231; AC02-76SF00515; DEAC05-76RL01830
Resource Type:
Journal Article: Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 47 Journal Issue: 30; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Lukens, Wayne W., and Saslow, Sarah A.. Facile incorporation of technetium into magnetite, magnesioferrite, and hematite by formation of ferrous nitrate in situ : precursors to iron oxide nuclear waste forms. United Kingdom: N. p., 2018. Web. doi:10.1039/C8DT01356J.
Lukens, Wayne W., & Saslow, Sarah A.. Facile incorporation of technetium into magnetite, magnesioferrite, and hematite by formation of ferrous nitrate in situ : precursors to iron oxide nuclear waste forms. United Kingdom. doi:10.1039/C8DT01356J.
Lukens, Wayne W., and Saslow, Sarah A.. Mon . "Facile incorporation of technetium into magnetite, magnesioferrite, and hematite by formation of ferrous nitrate in situ : precursors to iron oxide nuclear waste forms". United Kingdom. doi:10.1039/C8DT01356J.
@article{osti_1460584,
title = {Facile incorporation of technetium into magnetite, magnesioferrite, and hematite by formation of ferrous nitrate in situ : precursors to iron oxide nuclear waste forms},
author = {Lukens, Wayne W. and Saslow, Sarah A.},
abstractNote = {The fission product, 99 Tc, presents significant challenges to the long-term disposal of nuclear waste due to its long half-life, high fission yield, and to the environmental mobility of pertechnetate (TcO 4 − ), the stable Tc species in aerobic environments.},
doi = {10.1039/C8DT01356J},
journal = {Dalton Transactions},
number = 30,
volume = 47,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on July 17, 2019
Publisher's Accepted Manuscript

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Works referenced in this record:

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976