[RuII(tpy)(bpy)Cl]+-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects

Schneider, T. W.; Hren, M. T.; Ertem, M. Z.; Angeles-Boza, Alfredo M.

doi:10.1039/C8CC03009J

Title: [Ru^II(tpy)(bpy)Cl]⁺-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects

Journal Article · Sat Jul 07 00:00:00 EDT 2018 · ChemComm

DOI:https://doi.org/10.1039/C8CC03009J· OSTI ID:1460826

Schneider, T. W. ^[1]; Hren, M. T. ^[1];

^[2];

^[1]

Univ. of Connecticut, Storrs, CT (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)

¹³ C kinetic isotope effect determinations combined with DFT calculations provide insight on the CO ₂ reduction reaction catalyzed by a ruthenium complex.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1460826

Alternate ID(s):: OSTI ID: 1460466

Report Number(s):: BNL-207858-2018-JAAM

Journal Information:: ChemComm, Vol. 54, Issue 61; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 10 works

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Cited By (1)

Efficient labeling of organic molecules using ¹³ C elemental carbon: universal access to ¹³ C ₂ -labeled synthetic building blocks, polymers and pharmaceuticals Ledovskaya, Maria S.; Voronin, Vladimir V.; Rodygin, Konstantin S. Organic Chemistry Frontiers, Vol. 7, Issue 4 https://doi.org/10.1039/c9qo01357a	journal	January 2020

Figures / Tables (3)

Figure 1(p. 3)

Figure 2(p. 4)

Scheme 1(p. 5)

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Title: [RuII(tpy)(bpy)Cl]+-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects

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