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Title: Modeling Battery Performance Due to Intercalation Driven Volume Change in Porous Electrodes

Abstract

Simulations are presented that result from incorporating dimensional and porosity changes in porous electrodes caused by volume changes in the active material during intercalation into a detailed lithium-ion battery model. Porosity and dimensional changes in an electrode can significantly affect the resistance of the battery during cycling, which in turn alters the reaction distributions in the porous electrodes. In addition, volume changes generate stresses in the electrode which can lead to premature failure of the battery. Material conservation equations are coupled with the mechanical properties of porous electrodes to link dimensional and porosity changes to stresses and the resulting resistances that occur during the intercalation processes. Through the use of porous rock mechanics, porosity and strain gradients can be predicted based on state of discharge and discharge rate. Several different battery casings and discharge rates are examined and operating curves are predicted.

Authors:
 [1];  [2];  [2];  [2];  [3];  [4];  [5]
  1. Univ. of South Carolina, Columbia, SC (United States). Hydrogen and Fuel Cell Center; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Electrochemical Technologies Group
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Electrochemical Technologies Group
  3. Univ. of South Carolina, Columbia, SC (United States). Dept. of Mechanical Engineering
  4. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Electrochemical Technologies Group; Argonne National Lab. (ANL), Argonne, IL (United States). Argonne Collaborative Center for Energy Storage Science
  5. Univ. of South Carolina, Columbia, SC (United States). Hydrogen and Fuel Cell Center
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
OSTI Identifier:
1459379
DOE Contract Number:  
AC02-05CH11231
Resource Type:
Journal Article
Journal Name:
Journal of the Electrochemical Society
Additional Journal Information:
Journal Volume: 164; Journal Issue: 11; Journal ID: ISSN 0013-4651
Publisher:
The Electrochemical Society
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 36 MATERIALS SCIENCE; battery; intercalation; modeling; porous electrodes; volume change

Citation Formats

Garrick, Taylor R., Higa, Kenneth, Wu, Shao-Ling, Dai, Yiling, Huang, Xinyu, Srinivasan, Venkat, and Weidner, John W. Modeling Battery Performance Due to Intercalation Driven Volume Change in Porous Electrodes. United States: N. p., 2017. Web. doi:10.1149/2.0621711jes.
Garrick, Taylor R., Higa, Kenneth, Wu, Shao-Ling, Dai, Yiling, Huang, Xinyu, Srinivasan, Venkat, & Weidner, John W. Modeling Battery Performance Due to Intercalation Driven Volume Change in Porous Electrodes. United States. doi:10.1149/2.0621711jes.
Garrick, Taylor R., Higa, Kenneth, Wu, Shao-Ling, Dai, Yiling, Huang, Xinyu, Srinivasan, Venkat, and Weidner, John W. Fri . "Modeling Battery Performance Due to Intercalation Driven Volume Change in Porous Electrodes". United States. doi:10.1149/2.0621711jes. https://www.osti.gov/servlets/purl/1459379.
@article{osti_1459379,
title = {Modeling Battery Performance Due to Intercalation Driven Volume Change in Porous Electrodes},
author = {Garrick, Taylor R. and Higa, Kenneth and Wu, Shao-Ling and Dai, Yiling and Huang, Xinyu and Srinivasan, Venkat and Weidner, John W.},
abstractNote = {Simulations are presented that result from incorporating dimensional and porosity changes in porous electrodes caused by volume changes in the active material during intercalation into a detailed lithium-ion battery model. Porosity and dimensional changes in an electrode can significantly affect the resistance of the battery during cycling, which in turn alters the reaction distributions in the porous electrodes. In addition, volume changes generate stresses in the electrode which can lead to premature failure of the battery. Material conservation equations are coupled with the mechanical properties of porous electrodes to link dimensional and porosity changes to stresses and the resulting resistances that occur during the intercalation processes. Through the use of porous rock mechanics, porosity and strain gradients can be predicted based on state of discharge and discharge rate. Several different battery casings and discharge rates are examined and operating curves are predicted.},
doi = {10.1149/2.0621711jes},
journal = {Journal of the Electrochemical Society},
issn = {0013-4651},
number = 11,
volume = 164,
place = {United States},
year = {2017},
month = {7}
}

Works referenced in this record:

Electric Motor Design of General Motors’ Chevrolet Bolt Electric Vehicle
journal, April 2016

  • Momen, Faizul; Rahman, Khwaja M.; Son, Yochan
  • SAE International Journal of Alternative Powertrains, Vol. 5, Issue 2
  • DOI: 10.4271/2016-01-1228

Stress and Strain in Silicon Electrode Models
journal, January 2015

  • Higa, Kenneth; Srinivasan, Venkat
  • Journal of The Electrochemical Society, Vol. 162, Issue 6
  • DOI: 10.1149/2.0091507jes

Modeling Battery Performance Due to Intercalation Driven Volume Change in Porous Electrodes
journal, July 2016


Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells
journal, January 2007


Comparing Macroscale and Microscale Simulations of Porous Battery Electrodes
journal, January 2017

  • Higa, Kenneth; Wu, Shao-Ling; Parkinson, Dilworth Y.
  • Journal of The Electrochemical Society, Vol. 164, Issue 11
  • DOI: 10.1149/2.0501711jes

The Development and Future of Lithium Ion Batteries
journal, December 2016

  • Blomgren, George E.
  • Journal of The Electrochemical Society, Vol. 164, Issue 1
  • DOI: 10.1149/2.0251701jes

Real-Time Coordination of Plug-In Electric Vehicle Charging in Smart Grids to Minimize Power Losses and Improve Voltage Profile
journal, September 2011

  • Deilami, Sara; Masoum, Amir S.; Moses, Paul S.
  • IEEE Transactions on Smart Grid, Vol. 2, Issue 3
  • DOI: 10.1109/TSG.2011.2159816

Lessons Learned from the 787 Dreamliner Issue on Lithium-Ion Battery Reliability
journal, September 2013

  • Williard, Nicholas; He, Wei; Hendricks, Christopher
  • Energies, Vol. 6, Issue 9
  • DOI: 10.3390/en6094682

Elastic softening of amorphous and crystalline Li–Si Phases with increasing Li concentration: A first-principles study
journal, October 2010


Stress evolution and capacity fade in constrained lithium-ion pouch cells
journal, January 2014


Modeling Volume Changes in Porous Electrodes
journal, January 2006

  • Gomadam, Parthasarathy M.; Weidner, John W.
  • Journal of The Electrochemical Society, Vol. 153, Issue 1
  • DOI: 10.1149/1.2136087

Electric Vehicles Will Save the World
journal, January 2016


Modeling Volume Change in Dual Insertion Electrodes
journal, January 2017

  • Garrick, Taylor R.; Huang, Xinyu; Srinivasan, Venkat
  • Journal of The Electrochemical Society, Vol. 164, Issue 11
  • DOI: 10.1149/2.0541711jes

Electric vehicles: Driving range
journal, August 2016


Design Optimization, Development and Manufacturing of General Motors New Battery Electric Vehicle Drive Unit (1ET35)
journal, April 2014

  • Hawkins, Shawn; Holmes, Alan; Ames, David
  • SAE International Journal of Alternative Powertrains, Vol. 3, Issue 2
  • DOI: 10.4271/2014-01-1806

Modeling Volume Change due to Intercalation into Porous Electrodes
journal, January 2014

  • Garrick, Taylor R.; Kanneganti, Kumud; Huang, Xinyu
  • Journal of The Electrochemical Society, Vol. 161, Issue 8, p. E3297-E3301
  • DOI: 10.1149/2.030408jes

The Physical Science behind Climate Change
journal, August 2007


Potential for widespread electrification of personal vehicle travel in the United States
journal, August 2016


Aliovalent titanium substitution in layered mixed Li Ni–Mn–Co oxides for lithium battery applications
journal, January 2011

  • Kam, Kinson C.; Doeff, Marca M.
  • Journal of Materials Chemistry, Vol. 21, Issue 27
  • DOI: 10.1039/c0jm04193a

Quantifying microstructural dynamics and electrochemical activity of graphite and silicon-graphite lithium ion battery anodes
journal, September 2016

  • Pietsch, Patrick; Westhoff, Daniel; Feinauer, Julian
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms12909

Development of First Principles Capacity Fade Model for Li-Ion Cells
journal, January 2004

  • Ramadass, P.; Haran, Bala; Gomadam, Parthasarathy M.
  • Journal of The Electrochemical Society, Vol. 151, Issue 2
  • DOI: 10.1149/1.1634273