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Title: Compositional and structural insights into the nature of the H-cluster precursor on HydF

Abstract

Spectroscopic and computational characterization of loaded HydF reveals that the 2Fe subcluster is a coordinatively saturated Fe( i )–Fe( i ) species that contains 4 CO and 2 CN ligands, and is anchored to HydF via coordination to a [4Fe–4S] cluster.

Authors:
 [1]; ORCiD logo [1];  [2];  [2];  [1]; ORCiD logo [2];  [1];  [1]; ORCiD logo [1]
  1. Department of Chemistry and Biochemistry, Montana State University, Bozeman, USA
  2. Biosciences Center, National Renewable Energy Laboratory, Golden, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1458586
Grant/Contract Number:
AC36-08-GO28308; SC0005404
Resource Type:
Journal Article: Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 47; Journal Issue: 28; Related Information: CHORUS Timestamp: 2018-07-17 05:55:10; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Scott, Anna G., Szilagyi, Robert K., Mulder, David W., Ratzloff, Michael W., Byer, Amanda S., King, Paul W., Broderick, William E., Shepard, Eric M., and Broderick, Joan B. Compositional and structural insights into the nature of the H-cluster precursor on HydF. United Kingdom: N. p., 2018. Web. doi:10.1039/C8DT01654B.
Scott, Anna G., Szilagyi, Robert K., Mulder, David W., Ratzloff, Michael W., Byer, Amanda S., King, Paul W., Broderick, William E., Shepard, Eric M., & Broderick, Joan B. Compositional and structural insights into the nature of the H-cluster precursor on HydF. United Kingdom. doi:10.1039/C8DT01654B.
Scott, Anna G., Szilagyi, Robert K., Mulder, David W., Ratzloff, Michael W., Byer, Amanda S., King, Paul W., Broderick, William E., Shepard, Eric M., and Broderick, Joan B. Mon . "Compositional and structural insights into the nature of the H-cluster precursor on HydF". United Kingdom. doi:10.1039/C8DT01654B.
@article{osti_1458586,
title = {Compositional and structural insights into the nature of the H-cluster precursor on HydF},
author = {Scott, Anna G. and Szilagyi, Robert K. and Mulder, David W. and Ratzloff, Michael W. and Byer, Amanda S. and King, Paul W. and Broderick, William E. and Shepard, Eric M. and Broderick, Joan B.},
abstractNote = {Spectroscopic and computational characterization of loaded HydF reveals that the 2Fe subcluster is a coordinatively saturated Fe( i )–Fe( i ) species that contains 4 CO and 2 CN ligands, and is anchored to HydF via coordination to a [4Fe–4S] cluster.},
doi = {10.1039/C8DT01654B},
journal = {Dalton Transactions},
number = 28,
volume = 47,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on June 19, 2019
Publisher's Accepted Manuscript

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