skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: High capacity anode materials for lithium ion batteries

Patent ·
OSTI ID:1458524
; ; ; ; ; ;

High capacity silicon based anode active materials are described for lithium ion batteries. These materials are shown to be effective in combination with high capacity lithium rich cathode active materials. Supplemental lithium is shown to improve the cycling performance and reduce irreversible capacity loss for at least certain silicon based active materials. In particular silicon based active materials can be formed in composites with electrically conductive coatings, such as pyrolytic carbon coatings or metal coatings, and composites can also be formed with other electrically conductive carbon components, such as carbon nanofibers and carbon nanoparticles. Additional alloys with silicon are explored.

Research Organization:
Zenlabs Energy, Inc., Fremont, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AR0000034
Assignee:
Zenlabs Energy, Inc. (Fremont, CA)
Patent Number(s):
10,003,068
Application Number:
14/851,405
OSTI ID:
1458524
Resource Relation:
Patent File Date: 2015 Sep 11
Country of Publication:
United States
Language:
English

References (169)

High energy electrochemical cell having composite solid-state anode patent September 1992
Nonaqueous electrolyte secondary battery patent-application September 2008
Method of Depositing Silicon on Carbon Nanomaterials patent-application October 2012
Battery including carbon foam current collectors patent December 2005
Negative active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery comprising the same patent April 2009
Silicon composite, making method, and non-aqueous electrolyte secondary cell negative electrode material patent-application January 2006
A new approach to improve the high-voltage cyclic performance of Li-rich layered cathode material by electrochemical pre-treatment journal August 2008
Electrochemical secondary element patent November 1992
Electrode for use in lithium battery and rechargeable lithium battery patent March 2007
Lithium Ion Battery With High Voltage Electrolytes And Additives patent-application June 2011
Nanowire battery methods and arrangements patent October 2010
Secondary Battery patent-application December 2009
Negative Electrode Material For Lithium Secondary Battery, Negative Electrode Using The Material, Lithium Secondary Battery Using The Negative Electrode, And Manufacturing Method Of Negative Electrode Material patent-application May 2008
A new SiO/C anode composition for lithium-ion battery journal April 2008
Electrode structure for lithium secondary battery and secondary battery having such electrode structure patent November 2009
Negative electrode for nonaqueous secondary battery patent-application March 2006
Layered Li(Li0.2Ni0.15+0.5zCo0.10Mn0.55−0.5z)O2−zFz cathode materials for Li-ion secondary batteries journal August 2005
Cyclic deterioration and its improvement for Li-rich layered cathode material Li[Ni0.17Li0.2Co0.07Mn0.56]O2 journal January 2010
Amorphous electrode compositions patent March 2004
Lithium Ion Batteries With Long Cycling Performance patent-application January 2011
Electrochemical behaviors of silicon based anode material journal August 2005
Battery including an electrolyte solution comprising a halogenated carbonate derivative patent July 2010
Nano-sized SiOx/C composite anode for lithium ion batteries journal May 2011
Interweaved Si@SiOx/C nanoporous spheres as anode materials for Li-ion batteries journal July 2012
Silicon/germanium particle inks, doped particles, printing and processes for semiconductor applications patent-application July 2008
High Energy Lithium Ion Batteries With Particular Negative Electrode Compositions patent-application December 2009
Secondary lithium ion battery containing a prelithiated anode patent-application July 2010
Very Long Cycling of Lithium Ion Batteries with Lithium Rich Cathode Materials patent-application March 2012
Multiphase nanocomposite material and method for its manufacture patent-application July 2004
Improvement of High-Voltage Cycling Behavior of Surface-Modified Li[Ni[sub 1∕3]Co[sub 1∕3]Mn[sub 1∕3]]O[sub 2] Cathodes by Fluorine Substitution for Li-Ion Batteries journal July 2005
Method for intercalating alkali metal ions into carbon electrodes patent August 1995
Lithium Secondary Battery with High Energy Density patent-application December 2010
Establishing Sustainable US HEV/PHEV Manufacturing Base: Stabilized Lithium Metal Powder, Enabling Material And Revolutionary Technology For High Energy Li-Ion Batteries report December 2012
Hybrid anode compositions for lithium ion batteries patent-application May 2009
Anode for Lithium Ion Cell patent-application November 2008
Carbon−Silicon Core−Shell Nanowires as High Capacity Electrode for Lithium Ion Batteries journal September 2009
Superior Storage Performance of a Si@SiOx/C Nanocomposite as Anode Material for Lithium-Ion Batteries journal February 2008
Non-aqueous electrolyte secondary battery and its production method patent March 1995
Negative electrode material for use in lithium-ion secondary battery and process for producing the same patent August 1998
Lithium ion cell patent February 2000
Non-aqueous electrolyte secondary battery patent July 2000
High density electrode and battery using the electrode patent-application August 2006
Composite Compositions, Negative Electrodes with Composite Compositions and Corresponding Batteries patent-application May 2010
Alloy composition for lithium ion batteries patent January 2011
Composite Anode Active Material, Anode Including the Same and Lithium Battery Using the Anode patent-application January 2009
Method of making activated carbon derived from pitches patent June 2001
Electrode composite, battery electrode formed from said composite, and lithium battery comprising such as electrode patent-application July 2011
High capacity Li[Li0.2Ni0.2Mn0.6]O2 cathode materials via a carbonate co-precipitation method journal November 2006
Conductive silicon composite, preparation thereof, and negative electrode material for non-aqueous electrolyte secondary cell patent-application November 2003
High-performance lithium battery anodes using silicon nanowires
  • Chan, Candace K.; Peng, Hailin; Liu, Gao
  • Materials for Sustainable Energy: A Collection of Peer-Reviewed Research and Review Articles from Nature Publishing Group, p. 187-191 https://doi.org/10.1142/9789814317665_0026
book October 2010
Synthesis of spherical Li[Ni(1/3−z)Co(1/3−z)Mn(1/3−z)Mgz]O2 as positive electrode material for lithium-ion battery journal February 2006
Preloading Lithium Ion Cell Components With Lithium patent-application May 2011
Secondary lithium-ion cell with an auxiliary electrode patent January 2002
High Energy Lithium Ion Secondary Batteries patent-application October 2009
Electrolytes, Electrolyte Additives And Cells patent-application June 2008
Lithium secondary battery, anode for lithium secondary battery, and method for manufacturing the anode patent-application October 2001
Alloy compositions for lithium ion batteries patent December 2010
Nonaqueous secondary battery containing silicic material patent May 2001
Metal Halide Coatings On Lithium Ion Battery Positive Electrode Materials And Corresponding Batteries patent-application March 2012
Nonaqueous Secondary Battery patent-application September 2010
Electrochemical characterization of a novel Si–graphite–Li2.6Co0.4N composite as anode material for lithium secondary batteries journal January 2005
Silicon-Containing Alloys Useful as Electrodes for Lithium-Ion Batteries patent-application June 2007
Lithium Ion Batteries Based On Nanoporous Silicon patent-application March 2013
Silicon-silicon oxide-lithium composite, making method, and non-aqueous electrolyte secondary cell negative electrode material patent August 2010
Electrical transport in doped multiwalled carbon nanotubes journal April 2001
Lithium secondary battery, anode for lithium secondary battery, and method for manufacturing the anode patent November 2003
Lithium Ion Batteries With Supplemental Lithium patent-application May 2012
Method of Producing Silicon Oxide, Negative Electrode Active Material for lithium Ion Secondary Battery and Lithium Ion Secondary Battery Using the Same patent-application July 2010
Lithium-ion battery patent September 2009
Negative Electrode for Lithium Ion Secondary Battery and Lithium Ion Secondary Battery patent-application September 2008
Fluorine Doped Lithium Rich Metal Oxide Positive Electrode Battery Materials With High Specific Capacity and Corresponding Batteries patent-application April 2010
Anodes for rechargeable lithium batteries patent March 2003
Lithium metal dispersion in secondary battery anodes patent October 2007
Improvement of cycling stability of Si anode by mechanochemcial reduction and carbon coating journal April 2009
High-performance lithium battery anodes using silicon nanowires journal December 2007
Rechargeable lithium battery having improved reversible capacity patent February 1998
Comments on the structural complexity of lithium-rich Li1+xM1−xO2 electrodes (M=Mn, Ni, Co) for lithium batteries journal September 2006
Significant Improvement of Electrochemical Performance of AlF3-Coated Li[Ni0.8Co0.1Mn0.1]O2 Cathode Materials journal January 2007
Negative active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery comprising the same patent-application October 2005
High Energy Density Redox Flow Device patent-application February 2010
Process for prelithiation of carbon based anodes for lithium ion electrochemical cells patent May 1998
Non-Aqueous Electrolyte Secondary Battery, Negative Electrode Material, and Making Method patent-application September 2009
Refrigerator patent September 1848
Electrode material for lithium secondary battery and electrode structure having the electrode material patent-application February 2006
Negative active material for lithium secondary battery and method for preparating same patent-application August 2007
Composite for Anode Material, Anode Materials and Lithium Battery Using the Same patent-application July 2009
Negative Electrode Material, Making Method, Lithium Ion Secondary Battery, and Electrochemical Capacitor patent-application January 2010
Composite anode for nonaqueous secondary battery and method for producing the same patent July 1996
Method of producing prelithiated anodes for secondary lithium ion batteries patent-application May 2010
High-performance lithium-ion anodes using a hierarchical bottom-up approach journal March 2010
Electrode including porous particles with embedded active material for use in a secondary electrochemical cell patent April 1978
Lithium metal dispersion in secondary battery anodes patent March 2004
Lithium ion electrochemical cell patent September 1999
Positive Electrode Materials for High Discharge Capacity Lithium Ion Batteries patent-application June 2010
High Capacity, Temperature-Stable Lithium Aluminum Manganese Oxide Cathodes for Rechargeable Batteries journal January 1999
Electrode Material Comprising Graphene Composite Materials in a Graphite Network Formed from Reconstituted Graphene Sheets patent-application May 2011
Metal Oxide Coated Positive Electrode Materials For Lithium-Based Batteries patent-application March 2011
Lithium ion battery and methods of manufacture patent-application April 2006
Method of manufacturing high-surface-area silicon patent-application April 2011
Double current collector negative electrode design for alkali metal ion electrochemical cells patent May 2004
Silicon-Silicon Oxide-Lithium Composite, Making Method, And Non-Aqueous Electrolyte Secondary Cell Negative Electrode Material patent-application September 2007
Lithium secondary battery patent-application September 2004
Electrodes for alkali metal batteries patent-application July 2003
Non-Aqueous Electrolyte Secondary Battery patent-application December 2009
Non-aqueous electrolyte secondary battery and making method patent-application March 2008
Active Material for Non-Aqueous Electrolyte Secondary Battery and Manufacturing Method Therefore patent-application October 2008
Negative electrode active material and non-aqueous electrolyte rechargeable battery using the same patent-application December 2004
AlF3-Coating to Improve High Voltage Cycling Performance of Li[Ni1∕3]Co1∕3]Mn1∕3]O2 Cathode Materials for Lithium Secondary Batteries journal January 2007
Electrode for use in lithium battery and rechargeable lithium battery patent June 2007
Stabilized lithium metal powder for li-ion application, composition and process patent September 2009
Anode active material hybridizing carbon nanofiber for lithium secondary battery patent-application February 2009
Battery Packs for Vehicles and High Capacity Pouch Secondary Batteries for Incorporation into Compact Battery Packs patent-application February 2012
Conductive silicon composite, preparation thereof, and negative electrode material for non-aqueous electrolyte secondary cell patent May 2006
Layer-Layer Lithium Rich Complex Metal Oxides with High Specific Capacity and Excellent Cycling patent-application March 2011
Method for fabricating carbon/lithium-ion electrode for rechargeable lithium cell patent July 1995
Doped Positive Electrode Active Materials And Lithium Ion Secondary Battery Constructed Therefrom patent-application October 2011
Nonaqueous electrolyte secondary battery patent August 2007
Lithium metal dispersion in electrodes patent-application June 2005
Lithium-ion battery patent July 2009
Negative active material composition for a rechargeable lithium battery, a negative electrode for a rechargeable lithium battery, and a rechargeable lithium battery including same patent-application June 2008
Anode and Secondary Battery patent-application August 2009
Method of making a cell using a lithium-deactivated carbon anode patent April 1998
Negative active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery comprising the same patent October 2008
Electrochemical cell electrodes comprising coal-based carbon foam patent May 2005
Negative-electrode active material for nonaqueous electrolyte secondary battery, and negative electrode and nonaqueous electrolyte secondary battery using the same patent-application September 2007
Impedance Analysis of Silicon Nanowire Lithium Ion Battery Anodes journal June 2009
Carbonaceous material and lithium secondary batteries comprising same patent-application November 2002
Negative Electrode Material for Nonaqueous Electrolyte Secondary Battery, Making Method and Lithium Ion Secondary Battery patent-application November 2010
Porous Silicon Particulates for Lithium Batteries patent-application July 2009
Electrode Active Material, Method for Producing Same, Electrode for Nonaqueous Secondary Battery and Nonaqueous Secondary Battery patent-application July 2011
Nonaqueous electrolyte battery patent-application February 2004
Auxiliary Electrodes For Electrochemical Cells Containing High Capacity Active Materials patent-application February 2012
Method of producing porous silicon particles by stain-etching and silicon nanoparticles from stain-etched silicon powder patent April 2009
Nano-Sized Silicon patent-application April 2009
Lithium metal oxide electrodes for lithium batteries patent-application February 2005
Nanosized silicon-based composite derived by in situ mechanochemical reduction for lithium ion batteries journal February 2007
Electrode material, and production method and use thereof patent-application February 2006
Silicon Oxide Based High Capacity Anode Materials For Lithium Ion Batteries patent-application November 2012
Negative active material for rechargeable lithium battery, method of preparing same, and rechargeable lithium battery comprising same patent November 2008
SI/C Composite, Anode Active Materials, and Lithium Battery Including the Same patent-application January 2009
Coated Positive Electrode Materials For Lithium Ion Batteries patent-application May 2011
Lithium Ion Batteries with Supplemental Lithium patent-application May 2012
Carbon-Coated Silicon Particle Powder as the Anode Material for Lithium Ion Batteries and Method of Making the Same patent-application May 2009
Silicon composite particles, preparation thereof, and negative electrode material for non-aqueous electrolyte secondary cell patent-application September 2005
Si-C-O composite, making method, and non-aqueous electrolyte secondary cell negative electrode material patent February 2010
Non-aqueous electrolyte secondary battery patent April 2011
Enhancing the rate capability of high capacity xLi2MnO3 · (1−x)LiMO2 (M=Mn, Ni, Co) electrodes by Li–Ni–PO4 treatment journal April 2009
Lithium metal oxide electrodes for lithium cells and batteries patent January 2004
Negative electrode for rechargeable lithium battery and method for fabrication thereof patent November 2007
Electrode Active Material, Electrode, And Electricity Storage Device patent-application May 2012
Lithium secondary battery patent August 2009
Negative active material, negative electrode using the same, non-aqueous electrolyte battery using the same, and method for preparing the same patent-application February 2004
Anode Active Material, Method of Preparing the Same, Anode and Lithium Battery Containing the Material patent-application August 2008
Electrode material for rechargeable lithium battery, electrode structural body comprising said electrode material, rechargeable lithium battery having said electrode structural body, process for the production of said electrode structural body, and process for the production of said rechargeable lithium battery patent-application August 2003
Alloy for negative electrode of lithium secondary battery patent-application March 2007
Process for prelithiation of carbon based anodes for lithium batteries patent January 1997
Negative Electrode Material for Nonaqueous Electrolyte Secondary Battery, Making Method and Lithium Ion Secondary Battery patent-application September 2010
Layer-By-Layer Assemblies of Carbon-Based Nanostructures and Their Applications in Energy Storage and Generation Devices patent-application June 2010
Positive Electrode Materials for Lithium Ion Batteries Having a Specific Discharge Capacity and Processes for the Synthesis of These Materials patent-application April 2010
SiOx-based anodes for secondary lithium batteries journal December 2002
Lithium Doped Cathode Material patent-application March 2011
Electric separator, method for producing the same and the use thereof patent-application February 2005
Significant improvement of high voltage cycling behavior AlF3-coated LiCoO2 cathode journal May 2006
Negative Electrode Base Member patent-application May 2010
Multiwall carbon nanotubes journal June 2000
Secondary battery patent July 1990
Lithium Insertion in Carbon-Silicon Composite Materials Produced by Mechanical Milling journal January 1998
Secondary battery patent April 2005
Electrode material for anode of rechargeable lithium battery, electrode structural body using said electrode material, rechargeable lithium battery using said electrode structural body, process for producing said electrode structural body, and process for producing said rechargeable lithium battery patent-application August 2005

Similar Records

Related Subjects

25 ENERGY STORAGE