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Composition for fuel cell electrode

Patent ·
OSTI ID:1458518
In some examples, a fuel cell including an anode; electrolyte; and cathode separated from the anode by the electrolyte, wherein the cathode includes a Pr-nickelate based material with (Pr.sub.1-xAx)n+1(Ni1-yBy)nO3n+1+.delta. as a general formula, where n is 1 as an integer, A is an A-site dopant including of a metal of a group formed by one or more lanthanides, and B is a B-site dopant including of a metal of a group formed by one or more transition metals, wherein the A and B-site dopants are provided such that there is an increase in phase-stability and reduction in degradation of the Pr-nickelate based material, and A is at least one metal cation of lanthanides, La, Nd, Sm, or Gd, B is at least one metal cation of transition metals, Cu, Co, Mn, Zn, or Cr, where: 0
Research Organization:
LG Fuel Cell Systems, Inc., North Canton, OH (United States); University of South Carolina, Columbia, SC (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FE0000303
Assignee:
LG Fuel Cell Systems, Inc. (North Canton, OH); University of South Carolina (Columbia, SC)
Patent Number(s):
10,003,083
Application Number:
14/805,279
OSTI ID:
1458518
Country of Publication:
United States
Language:
English

References (29)

Design considerations for segmented-in-series fuel cells journal September 2005
Thermal, electrical, and electrocatalytical properties of lanthanum-doped strontium titanate journal July 2002
Crystal Structure, Diffusion Path, and Oxygen Permeability of a Pr2NiO4-Based Mixed Conductor (Pr0.9La0.1)2(Ni0.74Cu0.21Ga0.05)O4+δ
  • Yashima, Masatomo; Sirikanda, Nuansaeng; Ishihara, Tatsumi
  • Journal of the American Chemical Society, Vol. 132, Issue 7, p. 2385-2392 https://doi.org/10.1021/ja909820h
journal February 2010
Study of Pr and Pr and Co doped La2NiO4+δ as cathodes for La5.5WO11.25−δ based protonic conducting fuel cells journal October 2013
High performance praseodymium nickelate oxide cathode for low temperature solid oxide fuel cell journal February 2011
Preparation and electrochemical characterization of Ruddlesden–Popper oxide La4Ni3O10 cathode for IT-SOFCs by sol–gel method journal July 2013
Stability and oxygen transport properties of Pr2NiO4+δ ceramics journal January 2007
Suppression of Chromium Diffusion to an SOFC Cathode from an Alloy Separator by a Cathode Second Layer journal January 1996
La0.4Sr0.6Ti1 − xMnxO3 − δ Perovskites as Anode Materials for Solid Oxide Fuel Cells journal January 2006
Oxygen permeability, stability and electrochemical behavior of Pr2NiO4+δ-based materials journal February 2007
Short-period segmented-in-series solid oxide fuel cells on flattened tube supports journal January 2007
Oxygen ion transport in La2NiO4‐based ceramics
  • Kharton, Vladislav V.; Viskup, Alexandre P.; Naumovich, Eugene N.
  • Journal of Materials Chemistry, Vol. 9, Issue 10, p. 2623-2629 https://doi.org/10.1039/A903276B
journal January 1999
Fabrication of a MnCo2O4/gadolinia-doped Ceria (GDC) Dual-phase Composite Membrane for Oxygen Separation journal March 2010
Mixed Conductivity and Oxygen Permeability of Doped Pr2NiO4-Based Oxides journal January 2007
Structure and Bonding Anisotropy in Intergrowth Oxides: A Clue to the Manifestation of Bidimensionality in T-, T′-, and T*-Type Structures journal October 1999
Electrical Properties of Yttrium-Doped Strontium Titanate under Reducing Conditions journal January 2002
Mitigating Cr Contamination by Hot Air Filtering in Solid Oxide Fuel Cells journal January 2011
Evaluation of yttrium-doped SrTiO3 as an anode for solid oxide fuel cells journal September 2002
Ionic transport in oxygen-hyperstoichiometric phases with K2NiF4-type structure journal July 2001
Oxygen electrode reaction on Nd2NiO4+δ cathode materials: impedance spectroscopy study journal February 2003
In situ X-ray diffraction studies of Pr2−xNiO4+δ crystal structure relaxation caused by oxygen loss journal September 2014
Ni-doped Sr2Fe1.5Mo0.5O6-δ as Anode Materials for Solid Oxide Fuel Cells journal December 2013
Preparation and Properties for Solid Solution Ce0.8Pr0.2-xNdxO2-δ(x=0.02, 0.05, 0.1) journal December 2014
Enhancing electrochemical performance by control of transport properties in buffer layers – solid oxide fuel/electrolyser cells journal January 2015
WITHDRAWN: Bi-layer structures as solid oxide fuel cell interconnections journal January 2006
Enhancement of oxygen permeation through U-shaped K2NiF4-type oxide hollow fiber membranes by surface modifications journal June 2013
Electrode properties of Ln2NiO4 + δ  ( Ln = La ,  Nd ,  Pr ) AC Impedance and DC Polarization Studies journal January 2006
Electrode properties of doped Pr2NiO4-based oxide cathode for intermediate-temperature SOFCs journal January 2012
Oxygen ion conductors journal March 2003

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