Synthesis of Fluidized CO 2 Sorbents Based on Diamine Coordinated to Metal–Organic Frameworks by Direct Conversion of Metal Oxides Supported on Mesoporous Silica

Luz, Ignacio; Soukri, Mustapha; Lail, Marty

doi:10.1002/chem.201800612

Title: Synthesis of Fluidized CO ₂ Sorbents Based on Diamine Coordinated to Metal–Organic Frameworks by Direct Conversion of Metal Oxides Supported on Mesoporous Silica

Journal Article · Fri Jun 29 00:00:00 EDT 2018 · Chemistry - A European Journal

DOI:https://doi.org/10.1002/chem.201800612· OSTI ID:1457802

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RTI International Research Triangle Park NC 27709-2194 USA

Abstract A general and efficient method for shaping MOFs into fluidized forms has been developed by direct conversion of metal oxides supported on fluidized mesoporous silica. The resulting fluidized MOF hybrid materials containing diamines coordinated at the open metal sites have been studied as CO ₂ solid sorbents from post‐combustion flue gas showing similar performance than their bulk counterparts. These new fluidized MOF hybrid materials can be used for other applications involving fluidized bed reactor configurations, in which MOFs have never been considered.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: FE0026432

OSTI ID:: 1457802

Journal Information:: Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Vol. 24 Journal Issue: 42; ISSN 0947-6539

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 7 works

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Title: Synthesis of Fluidized CO ₂ Sorbents Based on Diamine Coordinated to Metal–Organic Frameworks by Direct Conversion of Metal Oxides Supported on Mesoporous Silica