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Title: Towards an all-vanadium redox flow battery with higher theoretical volumetric capacities by utilizing the VO2+ /V3+ couple

Abstract

In this study, an all-vanadium redox flow battery with V(IV) as the sole parent active species is developed by accessing the VO2+/V3+ redox couple. These batteries, referred to as V4RBs, possess a higher theoretical volumetric capacity than traditional VRBs. Copper ions were identified as an effective additive to boost the battery performance.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1]
  1. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE Office of Electricity (OE)
OSTI Identifier:
1457754
Alternate Identifier(s):
OSTI ID: 1724449
Report Number(s):
PNNL-SA-127931
Journal ID: ISSN 2095-4956; PII: S2095495618300123
Grant/Contract Number:  
AC05-76RL01830; 57558
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Journal of Energy Chemistry
Additional Journal Information:
Journal Volume: 27; Journal Issue: 5; Journal ID: ISSN 2095-4956
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 25 ENERGY STORAGE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Duan, Wentao, Li, Bin, Lu, Dongping, Wei, Xiaoliang, Nie, Zimin, Vijayakumar, M., Kizewski, James P., Hollas, Aaron, Reed, David, Sprenkle, Vincent, and Wang, Wei. Towards an all-vanadium redox flow battery with higher theoretical volumetric capacities by utilizing the VO2+ /V3+ couple. United States: N. p., 2018. Web. doi:10.1016/J.JECHEM.2018.05.020.
Duan, Wentao, Li, Bin, Lu, Dongping, Wei, Xiaoliang, Nie, Zimin, Vijayakumar, M., Kizewski, James P., Hollas, Aaron, Reed, David, Sprenkle, Vincent, & Wang, Wei. Towards an all-vanadium redox flow battery with higher theoretical volumetric capacities by utilizing the VO2+ /V3+ couple. United States. https://doi.org/10.1016/J.JECHEM.2018.05.020
Duan, Wentao, Li, Bin, Lu, Dongping, Wei, Xiaoliang, Nie, Zimin, Vijayakumar, M., Kizewski, James P., Hollas, Aaron, Reed, David, Sprenkle, Vincent, and Wang, Wei. 2018. "Towards an all-vanadium redox flow battery with higher theoretical volumetric capacities by utilizing the VO2+ /V3+ couple". United States. https://doi.org/10.1016/J.JECHEM.2018.05.020. https://www.osti.gov/servlets/purl/1457754.
@article{osti_1457754,
title = {Towards an all-vanadium redox flow battery with higher theoretical volumetric capacities by utilizing the VO2+ /V3+ couple},
author = {Duan, Wentao and Li, Bin and Lu, Dongping and Wei, Xiaoliang and Nie, Zimin and Vijayakumar, M. and Kizewski, James P. and Hollas, Aaron and Reed, David and Sprenkle, Vincent and Wang, Wei},
abstractNote = {In this study, an all-vanadium redox flow battery with V(IV) as the sole parent active species is developed by accessing the VO2+/V3+ redox couple. These batteries, referred to as V4RBs, possess a higher theoretical volumetric capacity than traditional VRBs. Copper ions were identified as an effective additive to boost the battery performance.},
doi = {10.1016/J.JECHEM.2018.05.020},
url = {https://www.osti.gov/biblio/1457754}, journal = {Journal of Energy Chemistry},
issn = {2095-4956},
number = 5,
volume = 27,
place = {United States},
year = {Fri Jun 15 00:00:00 EDT 2018},
month = {Fri Jun 15 00:00:00 EDT 2018}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 10 works
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Figures / Tables:

Fig. 1 Fig. 1: Schematic figure for the design of all-vanadium (Ⅳ) flow batteries, or V4RB, with the same parent active species (VO2+ ).

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Works referenced in this record:

Electrochemical Energy Storage for Green Grid
journal, May 2011


Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011


Material design and engineering of next-generation flow-battery technologies
journal, November 2016


New All-Vanadium Redox Flow Cell
journal, January 1986


Progress in Flow Battery Research and Development
journal, June 2011


Vanadium Flow Battery for Energy Storage: Prospects and Challenges
journal, March 2013


A Stable Vanadium Redox-Flow Battery with High Energy Density for Large-Scale Energy Storage
journal, March 2011


Towards an all-vanadium redox-flow battery electrolyte: electrooxidation of V(III) in V(IV)/V(III) redox couple
journal, September 2016


Capacity Decay and Remediation of Nafion-based All-Vanadium Redox Flow Batteries
journal, December 2012


On the Benefits of a Symmetric Redox Flow Battery
journal, December 2015


Works referencing / citing this record:

Adaptation of Cu(In, Ga)Se 2 photovoltaics for full unbiased photocharge of integrated solar vanadium redox flow batteries
journal, January 2020


Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.