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Title: Modular supramolecular approach for co-crystallization of donors and acceptors into ordered networks

Abstract

Organic charge-transfer (CT) co-crystals in a mixed stack system are disclosed, wherein a donor molecule (D) and an acceptor molecule (A) occupy alternating positions (DADADA) along the CT axis. A platform is provided which amplifies the molecular recognition of donors and acceptors and produces co-crystals at ambient conditions, wherein the platform comprises (i) a molecular design of the first constituent (.alpha.-complement), (ii) a molecular design of the second compound (.beta.-complement), and (iii) a solvent system that promotes co-crystallization.

Inventors:
; ; ; ; ;
Publication Date:
Research Org.:
Northwestern Univ., Evanston, IL (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1457701
Patent Number(s):
9,997,272
Application Number:
15/252,852
Assignee:
Northwestern University (Evanston, IL) EFRC
DOE Contract Number:  
SC0000989
Resource Type:
Patent
Resource Relation:
Patent File Date: 2016 Aug 31
Country of Publication:
United States
Language:
English

Citation Formats

Stupp, Samuel I., Stoddart, J. Fraser, Shveyd, Alexander K., Tayi, Alok S., Sue, Chi-Hau, and Narayanan, Ashwin. Modular supramolecular approach for co-crystallization of donors and acceptors into ordered networks. United States: N. p., 2018. Web.
Stupp, Samuel I., Stoddart, J. Fraser, Shveyd, Alexander K., Tayi, Alok S., Sue, Chi-Hau, & Narayanan, Ashwin. Modular supramolecular approach for co-crystallization of donors and acceptors into ordered networks. United States.
Stupp, Samuel I., Stoddart, J. Fraser, Shveyd, Alexander K., Tayi, Alok S., Sue, Chi-Hau, and Narayanan, Ashwin. Tue . "Modular supramolecular approach for co-crystallization of donors and acceptors into ordered networks". United States. doi:. https://www.osti.gov/servlets/purl/1457701.
@article{osti_1457701,
title = {Modular supramolecular approach for co-crystallization of donors and acceptors into ordered networks},
author = {Stupp, Samuel I. and Stoddart, J. Fraser and Shveyd, Alexander K. and Tayi, Alok S. and Sue, Chi-Hau and Narayanan, Ashwin},
abstractNote = {Organic charge-transfer (CT) co-crystals in a mixed stack system are disclosed, wherein a donor molecule (D) and an acceptor molecule (A) occupy alternating positions (DADADA) along the CT axis. A platform is provided which amplifies the molecular recognition of donors and acceptors and produces co-crystals at ambient conditions, wherein the platform comprises (i) a molecular design of the first constituent (.alpha.-complement), (ii) a molecular design of the second compound (.beta.-complement), and (iii) a solvent system that promotes co-crystallization.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jun 12 00:00:00 EDT 2018},
month = {Tue Jun 12 00:00:00 EDT 2018}
}

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