Highly Permeable Oligo(ethylene oxide)-co-poly(dimethylsiloxane) Membranes for Carbon Dioxide Separation

Hong, Tao; Lai, Sophia C.; Mahurin, Shannon Mark; Cao, Peng -Fei; Voylov, Dmitry N.; Meyer, III, Harry M.; Jacobs, Christopher B.; Carrillo, Jan-Michael Y.; Kisliuk, Alexander; Ivanov, Ilia N.; Jiang, De-en; Long, Brian K.; Mays, Jimmy W.; Sokolov, Alexei P.; Saito, Tomonori

doi:10.1002/adsu.201700113

Title: Highly Permeable Oligo(ethylene oxide)-co-poly(dimethylsiloxane) Membranes for Carbon Dioxide Separation

Journal Article · Wed Dec 27 00:00:00 EST 2017 · Advanced Sustainable Systems

DOI:https://doi.org/10.1002/adsu.201700113· OSTI ID:1456782

^[1]; Lai, Sophia C. ^[2];

^[2];

^[2]; Voylov, Dmitry N. ^[1];

^[2];

^[2]; Kisliuk, Alexander ^[2];

^[2]; Jiang, De-en ^[3]; Long, Brian K. ^[1]; Mays, Jimmy W. ^[4];

^[1];

^[2]

Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of California, Riverside, CA (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Abstract A series of cross‐linked, freestanding oligo(ethylene oxide)‐ co ‐(polydimethylsiloxane‐norbornene) membranes with varied composition is synthesized via in situ ring‐opening metathesis polymerization. These membranes show remarkably high CO ₂ permeabilities (3400 Barrer) and their separation performance approaches the Robeson upper bound. The excellent permeability of these copolymer membranes provides great potential for real‐world applications where enormous volumes of gases must be separated. The gas transport properties of these films are found to be directly proportional to oligo(ethylene oxide) content incorporation, which stems from the increased solubility selectivity change within the copolymer matrix. This work provides a systematic study of how gas separation performance in rubbery membranes can be enhanced by tuning the CO ₂ ‐philicity of their constituent monomeric subunits.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE)

Grant/Contract Number:: AC05-00OR22725; DE‐AC05‐00OR22725

OSTI ID:: 1456782

Alternate ID(s):: OSTI ID: 1414957

Journal Information:: Advanced Sustainable Systems, Vol. 2, Issue 4; ISSN 2366-7486

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 10 works

Citation information provided by
Web of Science

References (43)

Gas separation membranes from polymers of intrinsic microporosity Budd, P.; Msayib, K.; Tattershall, C. Journal of Membrane Science, Vol. 251, Issue 1-2 https://doi.org/10.1016/j.memsci.2005.01.009	journal	April 2005
Impact of tuning CO2-philicity in polydimethylsiloxane-based membranes for carbon dioxide separation Hong, Tao; Chatterjee, Sabornie; Mahurin, Shannon M. Journal of Membrane Science, Vol. 530 https://doi.org/10.1016/j.memsci.2017.02.033	journal	May 2017
Influence of TRIS-based co-monomer on structure and gas transport properties of cross-linked poly(ethylene oxide) Kusuma, Victor A.; Freeman, Benny D.; Smith, Stephan L. Journal of Membrane Science, Vol. 359, Issue 1-2 https://doi.org/10.1016/j.memsci.2010.01.049	journal	September 2010
Basis of Permeability/Selectivity Tradeoff Relations in Polymeric Gas Separation Membranes Freeman, Benny D. Macromolecules, Vol. 32, Issue 2 https://doi.org/10.1021/ma9814548	journal	January 1999
Pebax®/polyethylene glycol blend thin film composite membranes for CO2 separation: Performance with mixed gases Car, Anja; Stropnik, Chrtomir; Yave, Wilfredo Separation and Purification Technology, Vol. 62, Issue 1 https://doi.org/10.1016/j.seppur.2008.01.001	journal	August 2008
Mechanical, electrical and thermal properties of carbon fiber reinforced poly(dimethylsiloxane)/polypyrrole composites Çakmak, Güliz; Küçükyavuz, Zuhal; Küçükyavuz, Savaş Composites Part A: Applied Science and Manufacturing, Vol. 35, Issue 4 https://doi.org/10.1016/j.compositesa.2003.11.006	journal	April 2004
Crystallization and Melting Behavior of Polyethylene Oxide Copolymers Simon, Frederick T.; Rutherford, J. M. Journal of Applied Physics, Vol. 35, Issue 1 https://doi.org/10.1063/1.1713103	journal	January 1964
Poly(ethylene glycol) and poly(dimethyl siloxane): Combining their advantages into efficient CO2 gas separation membranes Reijerkerk, Sander R.; Knoef, Michel H.; Nijmeijer, Kitty Journal of Membrane Science, Vol. 352, Issue 1-2 https://doi.org/10.1016/j.memsci.2010.02.008	journal	April 2010
Gas transport behavior of mixed-matrix membranes composed of silica nanoparticles in a polymer of intrinsic microporosity (PIM-1) Ahn, Juhyeon; Chung, Wook-Jin; Pinnau, Ingo Journal of Membrane Science, Vol. 346, Issue 2 https://doi.org/10.1016/j.memsci.2009.09.047	journal	January 2010
Advances in high permeability polymer-based membrane materials for CO ₂ separations Wang, Shaofei; Li, Xueqin; Wu, Hong Energy & Environmental Science, Vol. 9, Issue 6 https://doi.org/10.1039/C6EE00811A	journal	January 2016
Seven chemical separations to change the world Sholl, David S.; Lively, Ryan P. Nature, Vol. 532, Issue 7600 https://doi.org/10.1038/532435a	journal	April 2016
Recent progress in the design of advanced PEO-containing membranes for CO2 removal Liu, Song Lin; Shao, Lu; Chua, Mei Ling Progress in Polymer Science, Vol. 38, Issue 7 https://doi.org/10.1016/j.progpolymsci.2013.02.002	journal	July 2013
Maximizing the right stuff: The trade-off between membrane permeability and selectivity Park, Ho Bum; Kamcev, Jovan; Robeson, Lloyd M. Science, Vol. 356, Issue 6343 https://doi.org/10.1126/science.aab0530	journal	June 2017
Sorption and transport of various gases in polycarbonate Koros, W. J.; Chan, A. H.; Paul, D. R. Journal of Membrane Science, Vol. 2 https://doi.org/10.1016/S0376-7388(00)83242-1	journal	January 1977
CO ₂ -Philic Polymer Membrane with Extremely High Separation Performance Yave, Wilfredo; Car, Anja; Funari, Sergio S. Macromolecules, Vol. 43, Issue 1 https://doi.org/10.1021/ma901950u	journal	January 2010
Poly[1-(trimethylsilyl)-1-propyne] and related polymers: synthesis, properties and functions Nagai, Kazukiyo; Masuda, Toshio; Nakagawa, Tsutomu Progress in Polymer Science, Vol. 26, Issue 5 https://doi.org/10.1016/S0079-6700(01)00008-9	journal	June 2001
Micro-well arrays for 3D shape control and high resolution analysis of single cells Ochsner, Mirjam; Dusseiller, Marc R.; Grandin, H. Michelle Lab on a Chip, Vol. 7, Issue 8 https://doi.org/10.1039/b704449f	journal	January 2007
Membranes for gas separation based on poly(1-trimethylsilyl-1-propyne)–silica nanocomposites Gomes, Dominique; Nunes, Suzana P.; Peinemann, Klaus-Viktor Journal of Membrane Science, Vol. 246, Issue 1 https://doi.org/10.1016/j.memsci.2004.05.015	journal	January 2005
Gas sorption, diffusion, and permeation in poly(dimethylsiloxane) Merkel, T. C.; Bondar, V. I.; Nagai, K. Journal of Polymer Science Part B: Polymer Physics, Vol. 38, Issue 3, p. 415-434 https://doi.org/10.1002/(SICI)1099-0488(20000201)38:3<415::AID-POLB8>3.0.CO;2-Z	journal	February 2000
High-performance Polymer Membranes with Multi-functional Amphiphilic Micelles for CO ₂ Capture Kim, Sang Jin; Jeon, Harim; Kim, Dong Jun ChemSusChem, Vol. 8, Issue 22 https://doi.org/10.1002/cssc.201501063	journal	October 2015
Poly(dimethylsiloxane)-poly(ethylene oxide)-heparin block copolymers III: Surface and bulk compositional differences Grainger, D. W.; Okano, T.; Kim, S. W. Journal of Biomedical Materials Research, Vol. 24, Issue 5 https://doi.org/10.1002/jbm.820240503	journal	May 1990
Ab Initio Screening of CO₂-philic Groups Tian, Ziqi; Saito, Tomonori; Jiang, De-en The Journal of Physical Chemistry A, Vol. 119, Issue 16, p. 3848-3852 https://doi.org/10.1021/acs.jpca.5b01892	journal	April 2015
Pebax-1657 nanocomposite membranes incorporated with nanoparticles/colloids/carbon nanotubes for CO ₂ /N ₂ and CO ₂ /H ₂ separation Yu, Bing; Cong, Hailin; Li, Zejing Journal of Applied Polymer Science, Vol. 130, Issue 4 https://doi.org/10.1002/app.39500	journal	June 2013
Likelihood of climate change pathways under uncertainty on fossil fuel resource availability Capellán-Pérez, Iñigo; Arto, Iñaki; Polanco-Martínez, Josué M. Energy & Environmental Science, Vol. 9, Issue 8 https://doi.org/10.1039/C6EE01008C	journal	January 2016
Power plant post-combustion carbon dioxide capture: An opportunity for membranes Merkel, Tim C.; Lin, Haiqing; Wei, Xiaotong Journal of Membrane Science, Vol. 359, Issue 1-2, p. 126-139 https://doi.org/10.1016/j.memsci.2009.10.041	journal	September 2010
A Photocurable Poly(dimethylsiloxane) Chemistry Designed for Soft Lithographic Molding and Printing in the Nanometer Regime Choi, Kyung M.; Rogers, John A. Journal of the American Chemical Society, Vol. 125, Issue 14 https://doi.org/10.1021/ja029973k	journal	April 2003
Formation of more stable hydrophilic surfaces of PDMS by plasma and chemical treatments Bodas, Dhananjay; Khan-Malek, Chantal Microelectronic Engineering, Vol. 83, Issue 4-9 https://doi.org/10.1016/j.mee.2006.01.195	journal	April 2006
Correlation of separation factor versus permeability for polymeric membranes Robeson, Lloyd M. Journal of Membrane Science, Vol. 62, Issue 2 https://doi.org/10.1016/0376-7388(91)80060-J	journal	October 1991
Effect of gamma-irradiation on (PEO/PVP)/Au nanocomposite: Materials for electrochemical and optical applications Abdelghany, A. M.; Abdelrazek, E. M.; Badr, S. I. Materials & Design, Vol. 97 https://doi.org/10.1016/j.matdes.2016.02.082	journal	May 2016
Effect of Cross-Link Density on Carbon Dioxide Separation in Polydimethylsiloxane-Norbornene Membranes Hong, Tao; Niu, Zhenbin; Hu, Xunxiang ChemSusChem, Vol. 8, Issue 21 https://doi.org/10.1002/cssc.201500903	journal	October 2015
Gas permeation parameters and other physicochemical properties of a polymer of intrinsic microporosity: Polybenzodioxane PIM-1 Budd, P.; Mckeown, N.; Ghanem, B. Journal of Membrane Science, Vol. 325, Issue 2 https://doi.org/10.1016/j.memsci.2008.09.010	journal	December 2008
Electrical conduction mechanism in NaCl complexed PEO/PVP polymer blend electrolytes K., Kiran Kumar; M., Ravi; Y., Pavani Journal of Non-Crystalline Solids, Vol. 358, Issue 23 https://doi.org/10.1016/j.jnoncrysol.2012.08.022	journal	December 2012
Polydimethylsiloxane/poly(methyl methacrylate) interpenetrating polymer networks: 2. Synthesis and properties He, X. W.; Widmaier, J. M.; Herz, J. E. Polymer, Vol. 33, Issue 4 https://doi.org/10.1016/0032-3861(92)90351-V	journal	January 1992
Gas sorption and characterization of poly(ether-b-amide) segmented block copolymers Bondar, V. I.; Freeman, B. D.; Pinnau, I. Journal of Polymer Science Part B: Polymer Physics, Vol. 37, Issue 17 https://doi.org/10.1002/(SICI)1099-0488(19990901)37:17<2463::AID-POLB18>3.0.CO;2-H	journal	September 1999
An investigation of the high gas permeability of poly (1-Trimethylsilyl-1-Propyne) Ichiraku, Y.; Stern, S. A.; Nakagawa, T. Journal of Membrane Science, Vol. 34, Issue 1 https://doi.org/10.1016/S0376-7388(00)80017-4	journal	November 1987
Poly(amide-12-b-ethylene oxide)/polyethylene glycol blend membranes for carbon dioxide separation Feng, Shichao; Ren, Jizhong; Hua, Kaisheng Separation and Purification Technology, Vol. 116 https://doi.org/10.1016/j.seppur.2013.05.002	journal	September 2013
Synthesis and characterization of polyimide containing PEG/PDMS amphiphilic conetworks by hydrosilylation: Correlation between structure and properties Srividhya, M.; Reddy, B. S. R. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 45, Issue 9 https://doi.org/10.1002/pola.21939	journal	May 2007
Gas separation mechanism of CO ₂ selective amidoxime-poly(1-trimethylsilyl-1-propyne) membranes Feng, Hongbo; Hong, Tao; Mahurin, Shannon M. Polymer Chemistry, Vol. 8, Issue 21 https://doi.org/10.1039/C7PY00056A	journal	January 2017
Enhanced electrochemical, structural, optical, thermal stability and ionic conductivity of (PEO/PVP) polymer blend electrolyte for electrochemical applications Chapi, Sharanappa; S., Raghu; H., Devendrappa Ionics, Vol. 22, Issue 6 https://doi.org/10.1007/s11581-015-1600-2	journal	December 2015
The upper bound revisited Robeson, Lloyd M. Journal of Membrane Science, Vol. 320, Issue 1-2, p. 390-400 https://doi.org/10.1016/j.memsci.2008.04.030	journal	July 2008
Gas solubility, diffusivity and permeability in poly(ethylene oxide) Lin, H.; Freeman, B. D. Journal of Membrane Science, Vol. 239, Issue 1 https://doi.org/10.1016/j.memsci.2003.08.031	journal	August 2004
Preparation of CO ₂ -philic polymeric membranes by blending poly(ether-b-amide-6) and PEG/PPG-containing copolymer Khosravi, Tayebeh; Omidkhah, Mohammadreza RSC Advances, Vol. 5, Issue 17 https://doi.org/10.1039/C4RA14168G	journal	January 2015
Highly permeable polymers for gas separation membranes Budd, Peter M.; McKeown, Neil B. Polymer Chemistry, Vol. 1, Issue 1 https://doi.org/10.1039/b9py00319c	journal	January 2010

Figures / Tables (11)

Similar Records

Impact of tuning CO₂-philicity in polydimethylsiloxane-based membranes for carbon dioxide separation

Journal Article · Wed Feb 22 00:00:00 EST 2017 · Journal of Membrane Science · OSTI ID:1456782

Hong, Tao; Chatterjee, Sabornie; Mahurin, Shannon M.; +7 more

Carbon Capture Membranes Based on Amorphous Polyether Nanofilms Enabled by Thickness Confinement and Interfacial Engineering

Journal Article · Thu Jul 13 00:00:00 EDT 2023 · ACS Applied Materials and Interfaces · OSTI ID:1456782

Zhang, Gengyi; Bui, Vinh; Yin, Yifan; +3 more

Structure and gas transport characteristics of triethylene oxide‐grafted polystyrene‐ b ‐poly(ethylene‐ co ‐butylene)‐ b ‐polystyrene

Journal Article · Tue Sep 15 00:00:00 EDT 2020 · Journal of Polymer Science · OSTI ID:1456782

Tian, Ding; Alebrahim, Taliehsadat; Kline, Gregory K.; +3 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
CO2-philic
high permeability
membrane gas separation
oligo(ethylene oxide)
polydimethylsiloxane

Title: Highly Permeable Oligo(ethylene oxide)-co-poly(dimethylsiloxane) Membranes for Carbon Dioxide Separation

Citation Formats

References (43)

Figures / Tables (11)

Similar Records

Related Subjects