DRILL Interface Makes Ion Soft Landing Broadly Accessible for Energy Science and Applications

Johnson, Grant E.; Prabhakaran, Venkateshkumar; Browning, Nigel D.; Mehdi, B. Layla; Laskin, Julia; Kottke, Peter A.; Fedorov, Andrei G.

doi:10.1002/batt.201800042

Title: DRILL Interface Makes Ion Soft Landing Broadly Accessible for Energy Science and Applications

Journal Article · Fri Jun 22 00:00:00 EDT 2018 · Batteries & Supercaps

DOI:https://doi.org/10.1002/batt.201800042· OSTI ID:1456293

^[1]; Prabhakaran, Venkateshkumar ^[1]; Browning, Nigel D. ^[2]; Mehdi, B. Layla ^[2]; Laskin, Julia ^[3]; Kottke, Peter A. ^[4]; Fedorov, Andrei G. ^[4]

Physical Sciences Division Pacific Northwest National Laboratory Richland WA 99352 USA
School of Engineering Department of Mechanical &, Aerospace Engineering University of Liverpool Liverpool L69 3GQ UK
Department of Chemistry Purdue University West Lafayette IN 47907 USA
School of Mechanical Engineering Georgia Institute of Technology Atlanta GA 30332 USA

Abstract Polyoxometalates (POM) have been deposited onto carbon nanotube (CNT) electrodes using benchtop ion soft landing (SL) enabled by a vortex‐confined electrohydrodynamic desolvation process. The device is based on the dry ion localization and locomotion (DRILL) mass spectrometry interface of Fedorov and co‐workers. By adding electrospray emitters, heating the desolvation gas, and operating at high gas flow rates, it is possible to obtain stable ion currents up to −15 nA that are ideal for deposition. Coupled with ambient ion optics, this interface enables desolvated ions to be delivered to surfaces while excluding solvent and counterions. Electron microscopy of surfaces prepared using the device reveal discrete POM and no aggregation that degrades electrode performance. Characterization of POM‐coated CNT electrodes in a supercapacitor showed an energy storage capacity similar to that achieved with SL in vacuum. For solutions that produce primarily a single ion by electrospray ionization, benchtop SL offers a simpler and less costly approach for surface modification with applications in catalysis, energy storage, and beyond.

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Sponsoring Organization:: USDOE

OSTI ID:: 1456293

Journal Information:: Batteries & Supercaps, Journal Name: Batteries & Supercaps Vol. 1 Journal Issue: 3; ISSN 2566-6223

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 11 works

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