Self-organizing layers from complex molecular anions
Abstract
Ions are promising building blocks for tunable self-organizing materials with advanced technological applications. However, because of strong Coulomb attraction with counterions, the intrinsic properties of ions are difficult to exploit for preparation of bulk materials. Here, we report the precisely-controlled preparation of macroscopic surface layers by soft landing of mass selected complex anions which determine the self organization of the layers with their molecular properties. The family of halogenated dodecaborates [B12X12]2- (X = F, Cl, Br, I), in which the internal charge distribution between core and shell regions of the molecular ions systematically vary, was deposited on different self assembled monolayer surfaces (SAMs) on gold at high coverage. Layers of anions were found to be stabilized by accumulation of neutral molecules. Different phases, self-organization mechanisms and optical properties were observed to depend upon the internal charge distribution of the deposited anions, the underlying surface and the coadsorbed molecules. This demonstrates rational control of the properties of anion based layers.
- Authors:
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1455303
- Report Number(s):
- PNNL-SA-128240
Journal ID: ISSN 2041-1723; KP1704020; KC0302020
- DOE Contract Number:
- AC05-76RL01830
- Resource Type:
- Journal Article
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Warneke, Jonas, McBriarty, Martin E., Riechers, Shawn L., China, Swarup, Engelhard, Mark H., Aprà, Edoardo, Young, Robert P., Washton, Nancy M., Jenne, Carsten, Johnson, Grant E., and Laskin, Julia. Self-organizing layers from complex molecular anions. United States: N. p., 2018.
Web. doi:10.1038/s41467-018-04228-2.
Warneke, Jonas, McBriarty, Martin E., Riechers, Shawn L., China, Swarup, Engelhard, Mark H., Aprà, Edoardo, Young, Robert P., Washton, Nancy M., Jenne, Carsten, Johnson, Grant E., & Laskin, Julia. Self-organizing layers from complex molecular anions. United States. https://doi.org/10.1038/s41467-018-04228-2
Warneke, Jonas, McBriarty, Martin E., Riechers, Shawn L., China, Swarup, Engelhard, Mark H., Aprà, Edoardo, Young, Robert P., Washton, Nancy M., Jenne, Carsten, Johnson, Grant E., and Laskin, Julia. 2018.
"Self-organizing layers from complex molecular anions". United States. https://doi.org/10.1038/s41467-018-04228-2.
@article{osti_1455303,
title = {Self-organizing layers from complex molecular anions},
author = {Warneke, Jonas and McBriarty, Martin E. and Riechers, Shawn L. and China, Swarup and Engelhard, Mark H. and Aprà, Edoardo and Young, Robert P. and Washton, Nancy M. and Jenne, Carsten and Johnson, Grant E. and Laskin, Julia},
abstractNote = {Ions are promising building blocks for tunable self-organizing materials with advanced technological applications. However, because of strong Coulomb attraction with counterions, the intrinsic properties of ions are difficult to exploit for preparation of bulk materials. Here, we report the precisely-controlled preparation of macroscopic surface layers by soft landing of mass selected complex anions which determine the self organization of the layers with their molecular properties. The family of halogenated dodecaborates [B12X12]2- (X = F, Cl, Br, I), in which the internal charge distribution between core and shell regions of the molecular ions systematically vary, was deposited on different self assembled monolayer surfaces (SAMs) on gold at high coverage. Layers of anions were found to be stabilized by accumulation of neutral molecules. Different phases, self-organization mechanisms and optical properties were observed to depend upon the internal charge distribution of the deposited anions, the underlying surface and the coadsorbed molecules. This demonstrates rational control of the properties of anion based layers.},
doi = {10.1038/s41467-018-04228-2},
url = {https://www.osti.gov/biblio/1455303},
journal = {Nature Communications},
issn = {2041-1723},
number = 1,
volume = 9,
place = {United States},
year = {Mon May 14 00:00:00 EDT 2018},
month = {Mon May 14 00:00:00 EDT 2018}
}
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