High selectivity of CO2 hydrogenation to CO by controlling the valence state of nickel using perovskite

Zhao, Baohuai; Yan, Binhang; Jiang, Zhao; Yao, Siyu; Liu, Zongyuan; Wu, Qiyuan; Ran, Rui; Senanayake, Sanjaya D.; Weng, Duan; Chen, Jingguang G.

doi:10.1039/C8CC03829E

Title: High selectivity of CO₂ hydrogenation to CO by controlling the valence state of nickel using perovskite

Journal Article · Mon Jun 11 00:00:00 EDT 2018 · ChemComm

DOI:https://doi.org/10.1039/C8CC03829E· OSTI ID:1466617

Zhao, Baohuai ^[1]; Yan, Binhang ^[1]; Jiang, Zhao ^[2]; Yao, Siyu ^[3];

^[3];

^[4]; Ran, Rui ^[5];

^[3]; Weng, Duan ^[5];

^[6]

Brookhaven National Lab. (BNL), Upton, NY (United States); Tsinghua Univ., Beijing (China)
Columbia Univ., New York, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Stony Brook Univ., NY (United States)
Tsinghua Univ., Beijing (China)
Brookhaven National Lab. (BNL), Upton, NY (United States); Columbia Univ., New York, NY (United States)

The selectivity of CO₂ hydrogenation can be significantly tuned by controlling the valence state of nickel using lanthanum-iron-nickel perovskites. Nickel with higher valence states weakens the binding of CO and increases the activation barrier for further CO hydrogenation, leading to a higher CO selectivity than the metallic nickel.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; AC02-05CH11231

OSTI ID:: 1466617

Alternate ID(s):: OSTI ID: 1454637

Report Number(s):: BNL-207967-2018-JAAM; CHCOFS

Journal Information:: ChemComm, Vol. 54, Issue 53; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 47 works

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Cited By (2)

Cooperative Co ⁰ /Co ^II Sites Stabilized by a Perovskite Matrix Enable Selective C−O and C−C bond Hydrogenolysis of Oxygenated Arenes Shetty, Manish; Zanchet, Daniela; Green, William H. ChemSusChem, Vol. 12, Issue 10 https://doi.org/10.1002/cssc.201900664	journal	April 2019
Hydrogenation of Carbon Dioxide to Value-Added Chemicals by Heterogeneous Catalysis and Plasma Catalysis Liu, Miao; Yi, Yanhui; Wang, Li Catalysts, Vol. 9, Issue 3 https://doi.org/10.3390/catal9030275	journal	March 2019

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Title: High selectivity of CO2 hydrogenation to CO by controlling the valence state of nickel using perovskite

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