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Title: Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species

Abstract

Here, a Ni(ii) complex with nitrogen and sulfur donor ligands degrades electrochemically in the presence of acid in acetonitrile to form an electrode adsorbed film that catalytically evolves hydrogen.

Authors:
 [1];  [1];  [1];  [1]
  1. Univ. of North Carolina, Chapel Hill, NC (United States)
Publication Date:
Research Org.:
Univ. of North Carolina, Chapel Hill, NC (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1454548
Grant/Contract Number:  
SC0001011
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 51; Journal Issue: 25; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Martin, Daniel J., McCarthy, Brian D., Donley, Carrie L., and Dempsey, Jillian L. Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species. United States: N. p., 2014. Web. doi:10.1039/C4CC08662G.
Martin, Daniel J., McCarthy, Brian D., Donley, Carrie L., & Dempsey, Jillian L. Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species. United States. doi:10.1039/C4CC08662G.
Martin, Daniel J., McCarthy, Brian D., Donley, Carrie L., and Dempsey, Jillian L. Thu . "Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species". United States. doi:10.1039/C4CC08662G. https://www.osti.gov/servlets/purl/1454548.
@article{osti_1454548,
title = {Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species},
author = {Martin, Daniel J. and McCarthy, Brian D. and Donley, Carrie L. and Dempsey, Jillian L.},
abstractNote = {Here, a Ni(ii) complex with nitrogen and sulfur donor ligands degrades electrochemically in the presence of acid in acetonitrile to form an electrode adsorbed film that catalytically evolves hydrogen.},
doi = {10.1039/C4CC08662G},
journal = {ChemComm},
issn = {1359-7345},
number = 25,
volume = 51,
place = {United States},
year = {2014},
month = {12}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 20 works
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Works referenced in this record:

Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects
journal, July 2008

  • Savéant, Jean-Michel
  • Chemical Reviews, Vol. 108, Issue 7, p. 2348-2378
  • DOI: 10.1021/cr068079z