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Title: Carbon/tin oxide composite electrodes for improved lithium-ion batteries

Abstract

Tin and tin oxide-based electrodes are promising high-capacity anodes for lithium-ion batteries. However, poor capacity retention is the major issue with these materials due to the large volumetric expansion that occurs when lithium is alloyed with tin during lithiation and delithiation process. Here, a method to prepare a low-cost, scalable carbon and tin(II) oxide composite anode is reported. The composite material was prepared by ball milling of carbon recovered from used tire powders with 25 wt% tin(II) oxide to form lithium-ion battery anode. With the impact of energy from the ball milling, tin oxide powders were uniformly distributed inside the pores of waste-tire-derived carbon. During lithiation and delithiation, the carbon matrix can effectively absorb the volume expansion caused by tin, thereby minimizing pulverization and capacity fade of the electrodes. In conclusion, the as-synthesized anode yielded a capacity of 690 mAh g –1 after 300 cycles at a current density of 40 mA g –1 with a stable battery performance.

Authors:
 [1];  [2]; ORCiD logo [3];  [2]; ORCiD logo [4]; ORCiD logo [3]; ORCiD logo [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); The Univ. of Tennessee, Knoxville, TN (United States)
  2. RJ Lee Group, Monroeville, PA (United States)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  4. The Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1454389
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Journal of Applied Electrochemistry
Additional Journal Information:
Journal Volume: 48; Journal Issue: 7; Journal ID: ISSN 0021-891X
Publisher:
Springer
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; Lithium-ion batteries (LIBs); Composite carbon anodes; Tin oxide; Waste tire recycling; Ball milling

Citation Formats

Li, Yunchao, Levine, Alan M., Zhang, Jinshui, Lee, Richard J., Naskar, Amit K., Dai, Sheng, and Paranthaman, M. Parans. Carbon/tin oxide composite electrodes for improved lithium-ion batteries. United States: N. p., 2018. Web. doi:10.1007/s10800-018-1205-3.
Li, Yunchao, Levine, Alan M., Zhang, Jinshui, Lee, Richard J., Naskar, Amit K., Dai, Sheng, & Paranthaman, M. Parans. Carbon/tin oxide composite electrodes for improved lithium-ion batteries. United States. doi:10.1007/s10800-018-1205-3.
Li, Yunchao, Levine, Alan M., Zhang, Jinshui, Lee, Richard J., Naskar, Amit K., Dai, Sheng, and Paranthaman, M. Parans. Thu . "Carbon/tin oxide composite electrodes for improved lithium-ion batteries". United States. doi:10.1007/s10800-018-1205-3.
@article{osti_1454389,
title = {Carbon/tin oxide composite electrodes for improved lithium-ion batteries},
author = {Li, Yunchao and Levine, Alan M. and Zhang, Jinshui and Lee, Richard J. and Naskar, Amit K. and Dai, Sheng and Paranthaman, M. Parans},
abstractNote = {Tin and tin oxide-based electrodes are promising high-capacity anodes for lithium-ion batteries. However, poor capacity retention is the major issue with these materials due to the large volumetric expansion that occurs when lithium is alloyed with tin during lithiation and delithiation process. Here, a method to prepare a low-cost, scalable carbon and tin(II) oxide composite anode is reported. The composite material was prepared by ball milling of carbon recovered from used tire powders with 25 wt% tin(II) oxide to form lithium-ion battery anode. With the impact of energy from the ball milling, tin oxide powders were uniformly distributed inside the pores of waste-tire-derived carbon. During lithiation and delithiation, the carbon matrix can effectively absorb the volume expansion caused by tin, thereby minimizing pulverization and capacity fade of the electrodes. In conclusion, the as-synthesized anode yielded a capacity of 690 mAh g–1 after 300 cycles at a current density of 40 mA g–1 with a stable battery performance.},
doi = {10.1007/s10800-018-1205-3},
journal = {Journal of Applied Electrochemistry},
number = 7,
volume = 48,
place = {United States},
year = {Thu May 17 00:00:00 EDT 2018},
month = {Thu May 17 00:00:00 EDT 2018}
}

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Works referenced in this record:

Tailored recovery of carbons from waste tires for enhanced performance as anodes in lithium-ion batteries
journal, January 2014

  • Naskar, Amit K.; Bi, Zhonghe; Li, Yunchao
  • RSC Advances, Vol. 4, Issue 72, p. 38213-38221
  • DOI: 10.1039/C4RA03888F

Graphene-Wrapped Sulfur Particles as a Rechargeable Lithium–Sulfur Battery Cathode Material with High Capacity and Cycling Stability
journal, July 2011

  • Wang, Hailiang; Yang, Yuan; Liang, Yongye
  • Nano Letters, Vol. 11, Issue 7, p. 2644-2647
  • DOI: 10.1021/nl200658a

Issues and challenges facing rechargeable lithium batteries
journal, November 2001

  • Tarascon, J.-M.; Armand, M.
  • Nature, Vol. 414, Issue 6861, p. 359-367
  • DOI: 10.1038/35104644

Nanostructured Sn–C Composite as an Advanced Anode Material in High-Performance Lithium-Ion Batteries
journal, September 2007

  • Derrien, G.; Hassoun, J.; Panero, S.
  • Advanced Materials, Vol. 19, Issue 17, p. 2336-2340
  • DOI: 10.1002/adma.200700748

A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
journal, May 2009

  • Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F.
  • Nature Materials, Vol. 8, Issue 6, p. 500-506
  • DOI: 10.1038/nmat2460

Dispersion of Sn and SnO on carbon anodes
journal, September 2000