Flexible and Hierarchical Metal–Organic Framework Composites for High‐Performance Catalysis

Huang, Ning; Drake, Hannah; Li, Jialuo; Pang, Jiandong; Wang, Ying; Yuan, Shuai; Wang, Qi; Cai, Peiyu; Qin, Junsheng; Zhou, Hong‐Cai

doi:10.1002/anie.201803096

Title: Flexible and Hierarchical Metal–Organic Framework Composites for High‐Performance Catalysis

Journal Article · Thu Jun 14 00:00:00 EDT 2018 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201803096· OSTI ID:1454327

^[1]; Drake, Hannah ^[1]; Li, Jialuo ^[1]; Pang, Jiandong ^[1]; Wang, Ying ^[2]; Yuan, Shuai ^[1]; Wang, Qi ^[1]; Cai, Peiyu ^[1]; Qin, Junsheng ^[1];

^[1]

Department of Chemistry Texas A&,M University College Station TX 77842-3012 USA
Department of Chemistry Texas A&,M University College Station TX 77842-3012 USA, College of Chemistry Tianjin Normal University Tianjin 300387 China

Abstract The development of porous composite materials is of great significance for their potentially improved performance over those of individual components and extensive applications in separation, energy storage, and heterogeneous catalysis. Now mesoporous metal–organic frameworks (MOFs) with macroporous melamine foam (MF) have been integrated using a one‐pot process, generating a series of MOF/MF composite materials with preserved crystallinity, hierarchical porosity, and increased stability over that of melamine foam. The MOF nanocrystals were threaded by the melamine foam networks, resembling a ball‐and‐stick model overall. The resulting MOF/MF composite materials were employed as an effective heterogeneous catalyst for the epoxidation of cholesteryl esters. Combining the advantages of interpenetrative mesoporous and macroporous structures, the MOF/melamine foam composite has higher dispersibility and more accessibility of catalytic sites, exhibiting excellent catalytic performance.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: FE0026472

OSTI ID:: 1454327

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Vol. 57 Journal Issue: 29; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 90 works

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