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Title: Conductive open frameworks

Abstract

The disclosure relates generally to materials that comprise conductive covalent organic frameworks. The disclosure also relates to materials that are useful to store and separate gas molecules and sensors.

Inventors:
; ; ; ;
Publication Date:
Research Org.:
Univ. of California, Oakland, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1444073
Patent Number(s):
9,978,474
Application Number:
15/050,136
Assignee:
The Regents of the University of California (Oakland, CA)
DOE Contract Number:  
FG36-05GO15001
Resource Type:
Patent
Resource Relation:
Patent File Date: 2016 Feb 22
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Yaghi, Omar M., Wan, Shun, Doonan, Christian J., Wang, Bo, and Deng, Hexiang. Conductive open frameworks. United States: N. p., 2018. Web.
Yaghi, Omar M., Wan, Shun, Doonan, Christian J., Wang, Bo, & Deng, Hexiang. Conductive open frameworks. United States.
Yaghi, Omar M., Wan, Shun, Doonan, Christian J., Wang, Bo, and Deng, Hexiang. 2018. "Conductive open frameworks". United States. https://www.osti.gov/servlets/purl/1444073.
@article{osti_1444073,
title = {Conductive open frameworks},
author = {Yaghi, Omar M. and Wan, Shun and Doonan, Christian J. and Wang, Bo and Deng, Hexiang},
abstractNote = {The disclosure relates generally to materials that comprise conductive covalent organic frameworks. The disclosure also relates to materials that are useful to store and separate gas molecules and sensors.},
doi = {},
url = {https://www.osti.gov/biblio/1444073}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue May 22 00:00:00 EDT 2018},
month = {Tue May 22 00:00:00 EDT 2018}
}

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Design, Synthesis, Structure, and Gas (N2, Ar, CO2, CH4, and H2) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra
journal, May 2005

  • Sudik, Andrea C.; Millward, Andrew R.; Ockwig, Nathan W.
  • Journal of the American Chemical Society, Vol. 127, Issue 19, p. 7110-7118
  • https://doi.org/10.1021/ja042802q

Construction of a new open-framework solid from 1,3,5-cyclohexanetricarboxylate and zinc(II) building blocks
journal, January 1997

  • Yaghi, Omar M.; Jernigan, Ryan; Li, Hailian
  • Journal of the Chemical Society, Dalton Transactions, Vol. 0, Issue 14, p. 2383-2384
  • https://doi.org/10.1039/a702287e

High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO2 Capture
journal, February 2008


Zeolitic imidazolate framework materials: recent progress in synthesis and applications
journal, January 2014


Syntheses, Structures, and Porous/Luminescent Properties of Silver 3-Alkyl-1,2,4-Triazolate Frameworks with Rare 3-Connected Topologies
journal, March 2011


A new structure type in polyoxoanion chemistry: synthesis and structure of the V5O143- anion
journal, June 1989


Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene
patent-application, November 2011


Process for producing polyalkylene carbonates
patent, September 2003


MOFs as catalysts: Activity, reusability and shape-selectivity of a Pd-containing MOF
journal, September 2007


Polymer-Induced Heteronucleation for the Discovery of New Extended Solids
journal, April 2006


A Multiunit Catalyst with Synergistic Stability and Reactivity: A Polyoxometalate–Metal Organic Framework for Aerobic Decontamination
journal, October 2011


A route to high surface area, porosity and inclusion of large molecules in crystals
journal, February 2004


Metal-organic frameworks based on iron oxide octahedral chains connected by benzenedicarboxylate dianions
journal, September 2005


A Microporous Metal–Organic Framework for Gas-Chromatographic Separation of Alkanes
journal, February 2006


Directed Transformation of Molecules to Solids: Synthesis of a Microporous Sulfide from Molecular Germanium Sulfide Cages
journal, January 1994


Strong and Reversible Binding of Carbon Dioxide in a Green Metal–Organic Framework
journal, October 2011

  • Gassensmith, Jeremiah J.; Furukawa, Hiroyasu; Smaldone, Ronald A.
  • Journal of the American Chemical Society, Vol. 133, Issue 39, p. 15312-15315
  • https://doi.org/10.1021/ja206525x

Post-Synthetic Modification of Tagged Metal-Organic Frameworks
journal, October 2008


Shaped bodies containing metal-organic frameworks
patent, May 2005


Implementation of a strategy for achieving extraordinary levels of surface area and porosity in crystals
patent-application, November 2004


Adsorption process with on-line adsorbent removal
patent-application, November 2006


20 Å Cd4In16S3514- Supertetrahedral T4 Clusters as Building Units in Decorated Cristobalite Frameworks
journal, May 2001


Structural study of new hydrocarbon nano-crystals by energy-filtered electron diffraction
journal, January 2004


Characterization of H2 Binding Sites in Prototypical Metal−Organic Frameworks by Inelastic Neutron Scattering
journal, October 2005

  • Rowsell, Jesse L. C.; Eckert, Juergen; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 127, Issue 42, p. 14904-14910
  • https://doi.org/10.1021/ja0542690

Shaped bodies containing metal-organic frameworks
patent, April 2009


Metal-Organic Frameworks from Edible Natural Products
journal, August 2010


Method of storing, uptaking, releasing of gases by novel framework materials
patent-application, August 2003


Gas Odorous Substance Separation
patent-application, August 2008


Isoreticular Expansion of Metal–Organic Frameworks with Triangular and Square Building Units and the Lowest Calculated Density for Porous Crystals
journal, September 2011


Understanding Inflections and Steps in Carbon Dioxide Adsorption Isotherms in Metal-Organic Frameworks
journal, January 2008


The CdSO4, rutile, cooperite and quartz dual nets: interpenetration and catenation
journal, January 2003


Ge2ZrO6F2·(H2DAB)H2O:1  A 4-Connected Microporous Material with “Bow Tie” Building Units and an Exceptional Proportion of 3-Rings
journal, December 2000


A Thermally Stable Pt/Y-Based Metal−Organic Framework:  Exploring the Accessibility of the Metal Centers with Spectroscopic Methods Using H2O, CH3OH, and CH3CN as Probes
journal, November 2006


CHEMICAL FRAMEWORK COMPOSITIONS AND METHODS OF USE
patent-application, June 2011


Metal–organic frameworks: a new class of porous materials
journal, August 2004


Ammonia Vapor Removal by Cu3(BTC)2 and Its Characterization by MAS NMR
journal, August 2009


Adsorbing Agent, Dust Collection Chamber And Method For Adsorbing Odours
patent-application, January 2008


Synthesis and characterization of a soluble oxide inclusion complex, [CH3CNC(V12O324-)]
journal, July 1989


Chemical Modification of a Bridging Ligand Inside a Metal–Organic Framework while Maintaining the 3D Structure
journal, April 2008


Robust dynamics
journal, May 2010


Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
journal, June 2012


Exceptional Framework Flexibility and Sorption Behavior of a Multifunctional Porous Cuprous Triazolate Framework
journal, May 2008


Reversible ethylene oxide capture in porous frameworks
patent, April 2014


[Cd16In64S134]44-: 31-Å Tetrahedron with a Large Cavity
journal, April 2003


Gas storage system
patent-application, December 2004


One-Step Synthesis and Structure of an Oligo(spiro-orthocarbonate)
journal, May 2002

  • Vodak, David T.; Braun, Matthew; Iordanidis, Lykourgos
  • Journal of the American Chemical Society, Vol. 124, Issue 18, p. 4942-4943
  • https://doi.org/10.1021/ja017683i

MOF-74 building unit has a direct impact on toxic gas adsorption
journal, January 2011


Hydrogen-Bonded Complexes of Aromatic Crown Ethers with (9-Anthracenyl)methylammonium Derivatives. Supramolecular Photochemistry and Photophysics. pH-Controllable Supramolecular Switching
journal, November 1997

  • Ashton, Peter R.; Ballardini, Roberto; Balzani, Vincenzo
  • Journal of the American Chemical Society, Vol. 119, Issue 44, p. 10641-10651
  • https://doi.org/10.1021/ja9715760

Mapping of Functional Groups in Metal-Organic Frameworks
journal, July 2013


Heterogeneity within Order in Crystals of a Porous Metal–Organic Framework
journal, August 2011


Metal-organic framework materials for gaseous hydrocarbon storage
patent-application, August 2006


Layered Structures Constructed from New Linkages of Ge7(O,OH,F)19 Clusters
journal, February 2003


Photoluminescent Metal−Organic Polymer Constructed from Trimetallic Clusters and Mixed Carboxylates
journal, February 2003


Covalent modification of a metal–organic framework with isocyanates: probing substrate scope and reactivity
journal, January 2008


Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
journal, February 2010


In Situ Hydrothermal Growth of Metal−Organic Framework 199 Films on Stainless Steel Fibers for Solid-Phase Microextraction of Gaseous Benzene Homologues
journal, December 2009


Role of Copper Species in the Oxidative Dimerization of Arylboronic Acids: Synthesis of Symmetrical Biaryls
journal, December 2003


Metal catalyzed reactions
patent, February 2004


Covalent Organic Frameworks and Methods of Making Same
patent-application, May 2014


Porous Metal Organic Framework Based On Pyrroles And Pyridinones
patent-application, July 2009


Rotaxanes as ligands: from molecules to materials
journal, January 2007


Industrial applications of metal–organic frameworks
journal, January 2009


Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs
journal, May 2008


A Catenated Strut in a Catenated Metal-Organic Framework
journal, August 2010


Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc)
journal, April 2012


Process for the alkoxylation of organic compounds in the presence of novel framework materials
patent-application, April 2003


Large Free Volume in Maximally Interpenetrating Networks:  The Role of Secondary Building Units Exemplified by Tb2(ADB)3[(CH3)2SO]4·16[(CH3)2SO]1
journal, May 2000


Role of Exposed Metal Sites in Hydrogen Storage in MOFs
journal, July 2008


A High-Throughput Investigation of the Role of pH, Temperature, Concentration, and Time on the Synthesis of Hybrid Inorganic-Organic Materials
journal, November 2005


Reticular Synthesis of Covalent Organic Borosilicate Frameworks
journal, September 2008

  • Hunt, Joseph R.; Doonan, Christian J.; LeVangie, James D.
  • Journal of the American Chemical Society, Vol. 130, Issue 36, p. 11872-11873
  • https://doi.org/10.1021/ja805064f

Rhenium-selenium-chlorine solid phases: cluster excision and core substitution reactions of molecular species
journal, November 1992


An Efficient High Yielding Approach for the Homocoupling of Aryl Boronic Acids
journal, January 2002


A large-cavity zeolite with wide pore windows and potential as an oil refining catalyst
journal, August 2002


Designed Synthesis of 3D Covalent Organic Frameworks
journal, April 2007


Taxonomy of periodic nets and the design of materials
journal, January 2007


Process for preparing and organometallic framework material
patent, August 2008


Highly Porous and Stable Metal−Organic Frameworks: Structure Design and Sorption Properties
journal, February 2000


Porphyrin-based nanoporous network polymers
journal, October 2002


Porous Metal−Organic Truncated Octahedron Constructed from Paddle-Wheel Squares and Terthiophene Links
journal, September 2005