Preparation of Single-Layer MoS2xSe2(1-x) and MoxW1-xS2 Nanosheets with High-Concentration Metallic 1T Phase

Tan, Chaoliang; Zhao, Wei; Chaturvedi, Apoorva; Fei, Zhen; Zeng, Zhiyuan; Chen, Junze; Huang, Ying; Ercius, Peter; Luo, Zhimin; Qi, Xiaoying; Chen, Bo; Lai, Zhuangchai; Li, Bing; Zhang, Xiao; Yang, Jian; Zong, Yun; Jin, Chuanhong; Zheng, Haimei; Kloc, Christian; Zhang, Hua

doi:10.1002/smll.201600014

Title: Preparation of Single-Layer MoS_2xSe_2(1-x) and Mo_xW_1-xS₂ Nanosheets with High-Concentration Metallic 1T Phase

Journal Article · Wed Feb 24 00:00:00 EST 2016 · Small

DOI:https://doi.org/10.1002/smll.201600014· OSTI ID:1440925

Tan, Chaoliang ^[1]; Zhao, Wei ^[1]; Chaturvedi, Apoorva ^[1]; Fei, Zhen ^[2]; Zeng, Zhiyuan ^[3]; Chen, Junze ^[1]; Huang, Ying ^[1]; Ercius, Peter ^[4]; Luo, Zhimin ^[1]; Qi, Xiaoying ^[5]; Chen, Bo ^[1]; Lai, Zhuangchai ^[1]; Li, Bing ^[6]; Zhang, Xiao ^[1]; Yang, Jian ^[1]; Zong, Yun ^[6]; Jin, Chuanhong ^[2]; Zheng, Haimei ^[3]; Kloc, Christian ^[1]; Zhang, Hua ^[1]

Nanyang Technological Univ. (Singapore). Center for Programmable Materials and School of Materials Science and Engineering
Zhejiang Univ., Hangzhou (China). State Key Lab. of Silicon Materials and School of Materials Science and Engineering
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). National Center for Electron Microscopy and Molecular Foundry
Singapore Inst. of Manufacturing Technology (SIMTech) (Singapore)
Agency for Science, Technology and Research (A*STAR) (Singapore). Inst. of Materials Research and Engineering (IMRE)

The high-yield and scalable production of single-layer ternary transition metal dichalcogenide nanosheets with ≈66% of metallic 1T phase, including MoS_2xSe_2(1-x) and Mo_xW_1-xS₂ is here achieved via electrochemical Li-intercalation and the exfoliation method. Thin film MoS_2xSe_2(1-x) nanosheets drop-cast on a fluorine-doped tin oxide substrate are used as an efficient electrocatalyst on the counter electrode for the tri-iodide reduction in a dye-sensitized solar cell.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: SC-22.3 USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Scientific User Facilities Division; Ministry of Education (MOE) (Singapore); National Research Foundation (NRF) (Singapore); National Basic Research Program of China; National Science Foundation of China (NSFC)

Grant/Contract Number:: AC02-05CH11231; M4081296.070.500000; 2014CB932500; 2015CB921000; 51222202; 51472215

OSTI ID:: 1440925

Journal Information:: Small, Vol. 12, Issue 14; Related Information: © 2016 Wiley-VCH Verlag GmbH & Co. KGaA.; ISSN 1613-6810

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 99 works

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References (53)

Composition-dependent Raman modes of Mo _1−x W _x S ₂ monolayer alloys Chen, Yanfeng; Dumcenco, Dumitru O.; Zhu, Yiming Nanoscale, Vol. 6, Issue 5 https://doi.org/10.1039/C3NR05630A	journal	January 2014
Phase engineering of transition metal dichalcogenides Voiry, Damien; Mohite, Aditya; Chhowalla, Manish Chemical Society Reviews, Vol. 44, Issue 9 https://doi.org/10.1039/C5CS00151J	journal	January 2015
In situ growth of a MoSe ₂ /Mo counter electrode for high efficiency dye-sensitized solar cells Chen, Haijie; Xie, Yian; Cui, Houlei Chem. Commun., Vol. 50, Issue 34 https://doi.org/10.1039/C3CC49600G	journal	January 2014
Enhanced Hydrogen Evolution Catalysis from Chemically Exfoliated Metallic MoS ₂ Nanosheets Lukowski, Mark A.; Daniel, Andrew S.; Meng, Fei Journal of the American Chemical Society, Vol. 135, Issue 28 https://doi.org/10.1021/ja404523s	journal	May 2013
Chemical Vapor Sensing with Monolayer MoS₂ Perkins, F. K.; Friedman, A. L.; Cobas, E. Nano Letters, Vol. 13, Issue 2, p. 668-673 https://doi.org/10.1021/nl3043079	journal	January 2013
Structural destabilization induced by lithium intercalation in MoS ₂ and related compounds Py, M. A.; Haering, R. R. Canadian Journal of Physics, Vol. 61, Issue 1 https://doi.org/10.1139/p83-013	journal	January 1983
A Se-doped MoS ₂ nanosheet for improved hydrogen evolution reaction Ren, Xianpei; Ma, Qiang; Fan, Haibo Chemical Communications, Vol. 51, Issue 88 https://doi.org/10.1039/C5CC06847A	journal	January 2015
Growth of Large-Area 2D MoS _{2(1- x )} Se _{2 x} Semiconductor Alloys Feng, Qingliang; Zhu, Yiming; Hong, Jinhua Advanced Materials, Vol. 26, Issue 17 https://doi.org/10.1002/adma.201306095	journal	February 2014
Improvement of efficiency of dye-sensitized solar cells based on analysis of equivalent circuit Koide, Naoki; Islam, Ashraful; Chiba, Yasuo Journal of Photochemistry and Photobiology A: Chemistry, Vol. 182, Issue 3, p. 296-305 https://doi.org/10.1016/j.jphotochem.2006.04.030	journal	September 2006
Active guests in the MoS ₂ /MoSe ₂ host lattice: efficient hydrogen evolution using few-layer alloys of MoS _2(1−x) Se _2x Kiran, Vankayala; Mukherjee, Debdyuti; Jenjeti, Ramesh Naidu Nanoscale, Vol. 6, Issue 21 https://doi.org/10.1039/C4NR03716B	journal	January 2014
Liquid-phase exfoliation of ultrathin layered transition metal dichalcogenide nanosheets composed of solid-solution Mo _{1− x} W _x S ₂ : Liquid-phase exfoliation of ultrathin layered transition metal dichalcogenide nanosheets Funaki, Kazushi; Tezuka, Keitaro; Shan, Yue Jin physica status solidi (a), Vol. 211, Issue 4 https://doi.org/10.1002/pssa.201330507	journal	January 2014
High-Yield Exfoliation of Ultrathin Two-Dimensional Ternary Chalcogenide Nanosheets for Highly Sensitive and Selective Fluorescence DNA Sensors Tan, Chaoliang; Yu, Peng; Hu, Yanling Journal of the American Chemical Society, Vol. 137, Issue 32 https://doi.org/10.1021/jacs.5b06982	journal	August 2015
Economical and effective sulfide catalysts for dye-sensitized solar cells as counter electrodes Wu, Mingxing; Wang, Yudi; Lin, Xiao Physical Chemistry Chemical Physics, Vol. 13, Issue 43 https://doi.org/10.1039/c1cp22819f	journal	January 2011
Metal dichalcogenide nanosheets: preparation, properties and applications Huang, Xiao; Zeng, Zhiyuan; Zhang, Hua Chemical Society Reviews, Vol. 42, Issue 5, p. 1934-1946 https://doi.org/10.1039/c2cs35387c	journal	January 2013
Ultrathin MoS _{2(1– x )} Se _{2 x} Alloy Nanoflakes For Electrocatalytic Hydrogen Evolution Reaction Gong, Qiufang; Cheng, Liang; Liu, Changhai ACS Catalysis, Vol. 5, Issue 4 https://doi.org/10.1021/cs501970w	journal	March 2015
Single-Layer MoS ₂ -Based Nanoprobes for Homogeneous Detection of Biomolecules Zhu, Changfeng; Zeng, Zhiyuan; Li, Hai Journal of the American Chemical Society, Vol. 135, Issue 16 https://doi.org/10.1021/ja4019572	journal	April 2013
Epitaxial Growth of Hetero-Nanostructures Based on Ultrathin Two-Dimensional Nanosheets Tan, Chaoliang; Zhang, Hua Journal of the American Chemical Society, Vol. 137, Issue 38 https://doi.org/10.1021/jacs.5b03590	journal	September 2015
Single-Layer MoS₂ Phototransistors Yin, Zongyou; Li, Hai; Li, Hong ACS Nano, Vol. 6, Issue 1, p. 74-80 https://doi.org/10.1021/nn2024557	journal	December 2011
Phase patterning for ohmic homojunction contact in MoTe2 Cho, S.; Kim, S.; Kim, J. H. Science, Vol. 349, Issue 6248 https://doi.org/10.1126/science.aab3175	journal	August 2015
Conducting MoS ₂ Nanosheets as Catalysts for Hydrogen Evolution Reaction Voiry, Damien; Salehi, Maryam; Silva, Rafael Nano Letters, Vol. 13, Issue 12 https://doi.org/10.1021/nl403661s	journal	November 2013
Colloidal Synthesis of 1T-WS ₂ and 2H-WS ₂ Nanosheets: Applications for Photocatalytic Hydrogen Evolution Mahler, Benoit; Hoepfner, Veronika; Liao, Kristine Journal of the American Chemical Society, Vol. 136, Issue 40 https://doi.org/10.1021/ja506261t	journal	August 2014
Ultrathin Two-Dimensional Nanomaterials Zhang, Hua ACS Nano, Vol. 9, Issue 10 https://doi.org/10.1021/acsnano.5b05040	journal	September 2015
In Situ Preparation of a Flexible Polyaniline/Carbon Composite Counter Electrode and Its Application in Dye-Sensitized Solar Cells Sun, Huicheng; Luo, Yanhong; Zhang, Yiduo The Journal of Physical Chemistry C, Vol. 114, Issue 26 https://doi.org/10.1021/jp1030015	journal	June 2010
2-Dimensional Transition Metal Dichalcogenides with Tunable Direct Band Gaps: MoS _2(1-x) Se _2x Monolayers Mann, John; Ma, Quan; Odenthal, Patrick M. Advanced Materials, Vol. 26, Issue 9 https://doi.org/10.1002/adma.201304389	journal	December 2013
Photoluminescence from Chemically Exfoliated MoS₂ Eda, Goki; Yamaguchi, Hisato; Voiry, Damien Nano Letters, Vol. 11, Issue 12, p. 5111-5116 https://doi.org/10.1021/nl201874w	journal	December 2011
Tunable Band Gap Photoluminescence from Atomically Thin Transition-Metal Dichalcogenide Alloys Chen, Yanfeng; Xi, Jinyang; Dumcenco, Dumitru O. ACS Nano, Vol. 7, Issue 5, p. 4610-4616 https://doi.org/10.1021/nn401420h	journal	April 2013
Characterization of MoSe2 thin films Mallouky, A.; Bernede, J. C. Thin Solid Films, Vol. 158, Issue 2 https://doi.org/10.1016/0040-6090(88)90032-6	journal	April 1988
Band Gap-Tunable Molybdenum Sulfide Selenide Monolayer Alloy Su, Sheng-Han; Hsu, Yu-Te; Chang, Yung-Huang Small, Vol. 10, Issue 13 https://doi.org/10.1002/smll.201302893	journal	March 2014
Controllable Disorder Engineering in Oxygen-Incorporated MoS ₂ Ultrathin Nanosheets for Efficient Hydrogen Evolution Xie, Junfeng; Zhang, Jiajia; Li, Shuang Journal of the American Chemical Society, Vol. 135, Issue 47 https://doi.org/10.1021/ja408329q	journal	November 2013
A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO₂ films O'Regan, Brian; Grätzel, Michael Nature, Vol. 353, Issue 6346, p. 737-740 https://doi.org/10.1038/353737a0	journal	October 1991
XPS investigation of preferential sputtering of S from MoS2 and determination of MoSx stoichiometry from Mo and S peak positions Baker, M. A.; Gilmore, R.; Lenardi, C. Applied Surface Science, Vol. 150, Issue 1-4 https://doi.org/10.1016/S0169-4332(99)00253-6	journal	August 1999
Electronics and optoelectronics of two-dimensional transition metal dichalcogenides Wang, Qing Hua; Kalantar-Zadeh, Kourosh; Kis, Andras Nature Nanotechnology, Vol. 7, Issue 11, p. 699-712 https://doi.org/10.1038/nnano.2012.193	journal	November 2012
PEGylated WS ₂ Nanosheets as a Multifunctional Theranostic Agent for in vivo Dual-Modal CT/Photoacoustic Imaging Guided Photothermal Therapy Cheng, Liang; Liu, Jingjing; Gu, Xing Advanced Materials, Vol. 26, Issue 12 https://doi.org/10.1002/adma.201304497	journal	December 2013
Atomically-thick two-dimensional crystals: electronic structure regulation and energy device construction Sun, Yongfu; Gao, Shan; Xie, Yi Chem. Soc. Rev., Vol. 43, Issue 2 https://doi.org/10.1039/C3CS60231A	journal	January 2014
Atomic mechanism of the semiconducting-to-metallic phase transition in single-layered MoS2 Lin, Yung-Chang; Dumcenco, Dumitru O.; Huang, Ying-Sheng Nature Nanotechnology, Vol. 9, Issue 5 https://doi.org/10.1038/nnano.2014.64	journal	April 2014
Low-Cost Molybdenum Carbide and Tungsten Carbide Counter Electrodes for Dye-Sensitized Solar Cells Wu, Mingxing; Lin, Xiao; Hagfeldt, Anders Angewandte Chemie International Edition, Vol. 50, Issue 15, p. 3520-3524 https://doi.org/10.1002/anie.201006635	journal	March 2011
Two-dimensional transition metal dichalcogenide nanosheet-based composites Tan, Chaoliang; Zhang, Hua Chemical Society Reviews, Vol. 44, Issue 9 https://doi.org/10.1039/C4CS00182F	journal	January 2015
Enhanced catalytic activity in strained chemically exfoliated WS2 nanosheets for hydrogen evolution Voiry, Damien; Yamaguchi, Hisato; Li, Junwen Nature Materials, Vol. 12, Issue 9 https://doi.org/10.1038/nmat3700	journal	July 2013
Gate-tunable phase transitions in thin flakes of 1T-TaS2 Yu, Yijun; Yang, Fangyuan; Lu, Xiu Fang Nature Nanotechnology, Vol. 10, Issue 3 https://doi.org/10.1038/nnano.2014.323	journal	January 2015
Electrochemical tuning of vertically aligned MoS2 nanofilms and its application in improving hydrogen evolution reaction Wang, H.; Lu, Z.; Xu, S. Proceedings of the National Academy of Sciences, Vol. 110, Issue 49 https://doi.org/10.1073/pnas.1316792110	journal	November 2013
Growth of Alloy MoS_2xSe_2(1–x) Nanosheets with Fully Tunable Chemical Compositions and Optical Properties Li, Honglai; Duan, Xidong; Wu, Xueping Journal of the American Chemical Society, Vol. 136, Issue 10, p. 3756-3759 https://doi.org/10.1021/ja500069b	journal	February 2014
Two-dimensional graphene analogues for biomedical applications Chen, Yu; Tan, Chaoliang; Zhang, Hua Chemical Society Reviews, Vol. 44, Issue 9 https://doi.org/10.1039/C4CS00300D	journal	January 2015
Single-Layer Semiconducting Nanosheets: High-Yield Preparation and Device Fabrication Zeng, Zhiyuan; Yin, Zongyou; Huang, Xiao Angewandte Chemie International Edition, Vol. 50, Issue 47, p. 11093-11097 https://doi.org/10.1002/anie.201106004	journal	October 2011
Ultrathin WS ₂ Nanoflakes as a High-Performance Electrocatalyst for the Hydrogen Evolution Reaction Cheng, Liang; Huang, Wenjing; Gong, Qiufang Angewandte Chemie International Edition, Vol. 53, Issue 30 https://doi.org/10.1002/anie.201402315	journal	May 2014
Phase-engineered low-resistance contacts for ultrathin MoS₂ transistors Kappera, Rajesh; Voiry, Damien; Yalcin, Sibel Ebru Nature Materials, Vol. 13, Issue 12, p. 1128-1134 https://doi.org/10.1038/nmat4080	journal	August 2014
Superior stability and high capacity of restacked molybdenum disulfide as anode material for lithium ion batteries Du, Guodong; Guo, Zaiping; Wang, Shiquan Chem. Commun., Vol. 46, Issue 7 https://doi.org/10.1039/B920277C	journal	January 2010
Visualization and quantification of transition metal atomic mixing in Mo_1−xW_xS₂ single layers Dumcenco, Dumitru O.; Kobayashi, Haruka; Liu, Zheng Nature Communications, Vol. 4, Article No. 1351 https://doi.org/10.1038/ncomms2351	journal	January 2013
Solution-phase epitaxial growth of noble metal nanostructures on dispersible single-layer molybdenum disulfide nanosheets Huang, Xiao; Zeng, Zhiyuan; Bao, Shuyu Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2472	journal	February 2013
Single-layer MoS₂ transistors Radisavljevic, B.; Radenovic, A.; Brivio, J. Nature Nanotechnology, Vol. 6, Issue 3, p. 147-150 https://doi.org/10.1038/nnano.2010.279	journal	January 2011
Band Gap Engineering and Layer-by-Layer Mapping of Selenium-Doped Molybdenum Disulfide Gong, Yongji; Liu, Zheng; Lupini, Andrew R. Nano Letters, Vol. 14, Issue 2 https://doi.org/10.1021/nl4032296	journal	December 2013
Metallic 1T phase MoS2 nanosheets as supercapacitor electrode materials Acerce, Muharrem; Voiry, Damien; Chhowalla, Manish Nature Nanotechnology, Vol. 10, Issue 4 https://doi.org/10.1038/nnano.2015.40	journal	March 2015
Single-Layer Semiconducting Nanosheets: High-Yield Preparation and Device Fabrication Zeng, Zhiyuan; Yin, Zongyou; Huang, Xiao Angewandte Chemie, Vol. 123, Issue 47 https://doi.org/10.1002/ange.201106004	journal	October 2011
Low-Cost Molybdenum Carbide and Tungsten Carbide Counter Electrodes for Dye-Sensitized Solar Cells Wu, Mingxing; Lin, Xiao; Hagfeldt, Anders Angewandte Chemie, Vol. 123, Issue 15 https://doi.org/10.1002/ange.201006635	journal	March 2011

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Title: Preparation of Single-Layer MoS2xSe2(1-x) and MoxW1-xS2 Nanosheets with High-Concentration Metallic 1T Phase

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Title: Preparation of Single-Layer MoS_2xSe_2(1-x) and Mo_xW_1-xS₂ Nanosheets with High-Concentration Metallic 1T Phase