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Title: Thickness-independent capacitance of vertically aligned liquid-crystalline MXenes

Abstract

The scalable and sustainable manufacture of thick electrode films with high energy and power densities is critical for the large-scale storage of electrochemical energy for application in transportation and stationary electric grids. Two-dimensional nanomaterials have become the predominant choice of electrode material in the pursuit of high energy and power densities owing to their large surface-area-to-volume ratios and lack of solid-state diffusion. However, traditional electrode fabrication methods often lead to restacking of two-dimensional nanomaterials, which limits ion transport in thick films and results in systems in which the electrochemical performance is highly dependent on the thickness of the film. Strategies for facilitating ion transport—such as increasing the interlayer spacing by intercalation or introducing film porosity by designing nanoarchitectures—result in materials with low volumetric energy storage as well as complex and lengthy ion transport paths that impede performance at high charge–discharge rates. Vertical alignment of two-dimensional flakes enables directional ion transport that can lead to thickness-independent electrochemical performances in thick films. However, so far only limited success has been reported, and the mitigation of performance losses remains a major challenge when working with films of two-dimensional nanomaterials with thicknesses that are near to or exceed the industrial standard of 100 micrometres.more » Here we demonstrate electrochemical energy storage that is independent of film thickness for vertically aligned two-dimensional titanium carbide (Ti 3C 2T x), a material from the MXene family (two-dimensional carbides and nitrides of transition metals (M), where X stands for carbon or nitrogen). The vertical alignment was achieved by mechanical shearing of a discotic lamellar liquid-crystal phase of Ti 3C 2T x. The resulting electrode films show excellent performance that is nearly independent of film thickness up to 200 micrometres, which makes them highly attractive for energy storage applications. In conclusion, the self-assembly approach presented here is scalable and can be extended to other systems that involve directional transport, such as catalysis and filtration.« less

Authors:
 [1];  [2];  [3];  [2];  [4];  [5];  [1];  [2];  [1]
  1. Univ. of Pennsylvania, Philadelphia, PA (United States)
  2. Drexel Univ., Philadelphia, PA (United States)
  3. Drexel Univ., Philadelphia, PA (United States); Univ. of Pennsylvania, Philadelphia, PA (United States)
  4. Univ. of Pennsylvania, Philadelphia, PA (United States); Northwestern Polytechnical Univ., Xi'an (China)
  5. Univ. of Pennsylvania, Philadelphia, PA (United States); Sichuan Univ., Chengdu (China)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1440811
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Nature (London)
Additional Journal Information:
Journal Volume: 557; Journal Issue: 7705; Journal ID: ISSN 0028-0836
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Xia, Yu, Mathis, Tyler S., Zhao, Meng -Qiang, Anasori, Babak, Dang, Alei, Zhou, Zehang, Cho, Hyesung, Gogotsi, Yury G., and Yang, Shu. Thickness-independent capacitance of vertically aligned liquid-crystalline MXenes. United States: N. p., 2018. Web. doi:10.1038/s41586-018-0109-z.
Xia, Yu, Mathis, Tyler S., Zhao, Meng -Qiang, Anasori, Babak, Dang, Alei, Zhou, Zehang, Cho, Hyesung, Gogotsi, Yury G., & Yang, Shu. Thickness-independent capacitance of vertically aligned liquid-crystalline MXenes. United States. doi:10.1038/s41586-018-0109-z.
Xia, Yu, Mathis, Tyler S., Zhao, Meng -Qiang, Anasori, Babak, Dang, Alei, Zhou, Zehang, Cho, Hyesung, Gogotsi, Yury G., and Yang, Shu. Wed . "Thickness-independent capacitance of vertically aligned liquid-crystalline MXenes". United States. doi:10.1038/s41586-018-0109-z. https://www.osti.gov/servlets/purl/1440811.
@article{osti_1440811,
title = {Thickness-independent capacitance of vertically aligned liquid-crystalline MXenes},
author = {Xia, Yu and Mathis, Tyler S. and Zhao, Meng -Qiang and Anasori, Babak and Dang, Alei and Zhou, Zehang and Cho, Hyesung and Gogotsi, Yury G. and Yang, Shu},
abstractNote = {The scalable and sustainable manufacture of thick electrode films with high energy and power densities is critical for the large-scale storage of electrochemical energy for application in transportation and stationary electric grids. Two-dimensional nanomaterials have become the predominant choice of electrode material in the pursuit of high energy and power densities owing to their large surface-area-to-volume ratios and lack of solid-state diffusion. However, traditional electrode fabrication methods often lead to restacking of two-dimensional nanomaterials, which limits ion transport in thick films and results in systems in which the electrochemical performance is highly dependent on the thickness of the film. Strategies for facilitating ion transport—such as increasing the interlayer spacing by intercalation or introducing film porosity by designing nanoarchitectures—result in materials with low volumetric energy storage as well as complex and lengthy ion transport paths that impede performance at high charge–discharge rates. Vertical alignment of two-dimensional flakes enables directional ion transport that can lead to thickness-independent electrochemical performances in thick films. However, so far only limited success has been reported, and the mitigation of performance losses remains a major challenge when working with films of two-dimensional nanomaterials with thicknesses that are near to or exceed the industrial standard of 100 micrometres. Here we demonstrate electrochemical energy storage that is independent of film thickness for vertically aligned two-dimensional titanium carbide (Ti3C2Tx), a material from the MXene family (two-dimensional carbides and nitrides of transition metals (M), where X stands for carbon or nitrogen). The vertical alignment was achieved by mechanical shearing of a discotic lamellar liquid-crystal phase of Ti3C2Tx. The resulting electrode films show excellent performance that is nearly independent of film thickness up to 200 micrometres, which makes them highly attractive for energy storage applications. In conclusion, the self-assembly approach presented here is scalable and can be extended to other systems that involve directional transport, such as catalysis and filtration.},
doi = {10.1038/s41586-018-0109-z},
journal = {Nature (London)},
issn = {0028-0836},
number = 7705,
volume = 557,
place = {United States},
year = {2018},
month = {5}
}

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Works referenced in this record:

Block copolymers and conventional lithography
journal, September 2006


Supercapacitors Based on Three-Dimensional Hierarchical Graphene Aerogels with Periodic Macropores
journal, January 2016