Novel Polyethylenimine–Acrylamide/SiO2 Hybrid Hydrogel Sorbent for Rare-Earth-Element Recycling from Aqueous Sources

Wang, Qiuming; Wilfong, Walter C.; Kail, Brian W.; Yu, Yang; Gray, McMahan L.

doi:10.1021/acssuschemeng.7b02851

Title: Novel Polyethylenimine–Acrylamide/SiO₂ Hybrid Hydrogel Sorbent for Rare-Earth-Element Recycling from Aqueous Sources

Journal Article · Thu Sep 14 00:00:00 EDT 2017 · ACS Sustainable Chemistry & Engineering

DOI:https://doi.org/10.1021/acssuschemeng.7b02851· OSTI ID:1433646

^[1];

^[1]; Kail, Brian W. ^[2]; Yu, Yang ^[2]; Gray, McMahan L. ^[3]

National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); AECOM, Pittsburgh, PA (United States)
National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)

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Research Organization:: National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE)

OSTI ID:: 1433646

Alternate ID(s):: OSTI ID: 1440525

Report Number(s):: NETL-PUB-21238

Journal Information:: ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 11; ISSN 2168-0485

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 27 works

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References (66)

A human health risk assessment of rare earth elements in soil and vegetables from a mining area in Fujian Province, Southeast China Li, Xiaofei; Chen, Zhibiao; Chen, Zhiqiang Chemosphere, Vol. 93, Issue 6 https://doi.org/10.1016/j.chemosphere.2013.06.085	journal	October 2013
Concentration of rare earth elements, As, and Th in human brain and brain tumors, determined by neutron activation analysis Zhuang, Guisun; Zhou, Yunlu; Lu, Huijuan Biological Trace Element Research, Vol. 53, Issue 1-3 https://doi.org/10.1007/BF02784543	journal	June 1996
Rare earth elements in human hair from a mining area of China Wei, Binggan; Li, Yonghua; Li, Hairong Ecotoxicology and Environmental Safety, Vol. 96 https://doi.org/10.1016/j.ecoenv.2013.05.031	journal	October 2013
Distribution of some rare earth elements and their binding species with proteins in human liver studied by instrumental neutron activation analysis combined with biochemical techniques Chen, Chunying; Zhang, Peiqun; Chai, Zhifang Analytica Chimica Acta, Vol. 439, Issue 1 https://doi.org/10.1016/S0003-2670(01)01024-8	journal	July 2001
Geochemistry of Trace Metals and Rare Earth Elements in Stream Water, Stream Sediments and Acid Mine Drainage from Darrehzar Copper Mine, Kerman, Iran Soltani, Naghmeh; Moore, Farid; Keshavarzi, Behnam Water Quality, Exposure and Health, Vol. 6, Issue 3 https://doi.org/10.1007/s12403-014-0114-x	journal	March 2014
The study of rare earth elements in farmer's well waters of the Podwiśniówka acid mine drainage area (south-central Poland) Migaszewski, Zdzisław M.; Gałuszka, Agnieszka; Migaszewski, Andrzej Environmental Monitoring and Assessment, Vol. 186, Issue 3 https://doi.org/10.1007/s10661-013-3478-7	journal	October 2013
Rare earth and trace element signatures for assessing an impact of rock mining and processing on the environment: Wiśniówka case study, south-central Poland Migaszewski, Zdzisław M.; Gałuszka, Agnieszka; Dołęgowska, Sabina Environmental Science and Pollution Research, Vol. 23, Issue 24 https://doi.org/10.1007/s11356-016-7713-y	journal	September 2016
Evaluation of water quality in surface water and shallow groundwater: a case study of a rare earth mining area in southern Jiangxi Province, China Hao, Xiuzhen; Wang, Dengjun; Wang, Peiran Environmental Monitoring and Assessment, Vol. 188, Issue 1 https://doi.org/10.1007/s10661-015-5025-1	journal	December 2015
The geochemistry of rare earth elements (REE) in acid mine drainage from the Sitai coal mine, Shanxi Province, North China Zhao, Fenghua; Cong, Zhiyuan; Sun, Hongfu International Journal of Coal Geology, Vol. 70, Issue 1-3 https://doi.org/10.1016/j.coal.2006.01.009	journal	April 2007
Rare earth elements in river waters Goldstein, Steven J.; Jacobsen, Stein B. Earth and Planetary Science Letters, Vol. 89, Issue 1 https://doi.org/10.1016/0012-821X(88)90031-3	journal	June 1988
Sorption of lanthanides on smectite and kaolinite Coppin, Frédéric; Berger, Gilles; Bauer, Andreas Chemical Geology, Vol. 182, Issue 1 https://doi.org/10.1016/S0009-2541(01)00283-2	journal	January 2002
The aqueous geochemistry of the rare-earth elements and yttrium Wood, Scott A. Chemical Geology, Vol. 82 https://doi.org/10.1016/0009-2541(90)90080-Q	journal	January 1990
Activated carbon from Ceiba pentandra hulls, an agricultural waste, as an adsorbent in the removal of lead and zinc from aqueous solutions Rao, M. Madhava; Rao, G. P. Chandra; Seshaiah, K. Waste Management, Vol. 28, Issue 5 https://doi.org/10.1016/j.wasman.2007.01.017	journal	January 2008
Sorption of toxic metal ions by solid sorbents: A predictive speciation approach based on complex formation constants in aqueous solution Nurchi, Valeria Marina; Villaescusa, Isabel Coordination Chemistry Reviews, Vol. 256, Issue 1-2 https://doi.org/10.1016/j.ccr.2011.09.002	journal	January 2012
Use of natural clays as sorbent materials for rare earth ions: Materials characterization and set up of the operative parameters Iannicelli-Zubiani, Elena Maria; Cristiani, Cinzia; Dotelli, Giovanni Waste Management, Vol. 46 https://doi.org/10.1016/j.wasman.2015.09.017	journal	December 2015
Adsorption of La(III) onto GMZ bentonite: effect of contact time, bentonite content, pH value and ionic strength Chen, Yonggui; Zhu, Chunming; Sun, Yanhong Journal of Radioanalytical and Nuclear Chemistry, Vol. 292, Issue 3 https://doi.org/10.1007/s10967-012-1612-6	journal	January 2012
Time Series Analysis of wind Speed and Temperature in Tiraspol, Moldova Burtiev, Rasid; Greenwell, Fernanda; Kolivenko, Vitalii Environmental Engineering and Management Journal, Vol. 12, Issue 1 https://doi.org/10.30638/eemj.2013.004	journal	January 2013
Hydrogels for Removal of Heavy Metals from Aqueous Solution Zheng, Jie Journal of Environmental & Analytical Toxicology, Vol. 02, Issue 07 https://doi.org/10.4172/2161-0525.S2-001	journal	January 2012
Water-enhanced Removal of Ciprofloxacin from Water by Porous Graphene Hydrogel Ma, Jie; Yang, Mingxuan; Yu, Fei Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep13578	journal	September 2015
Mercapto functionalized silica entrapped polyacrylamide hydrogel: Arsenic adsorption behaviour from aqueous solution Kumar, Rajesh; Jain, S. K.; Verma, S. Journal of Colloid and Interface Science, Vol. 456 https://doi.org/10.1016/j.jcis.2015.06.026	journal	October 2015
Synthesis, characterization and application of a modified acrylamide–styrene sulfonate resin and a composite for sorption of some rare earth elements Borai, Emad Hassan; Hamed, Mahmoud Goneam; El-kamash, Ahmed Mohamed New Journal of Chemistry, Vol. 39, Issue 9 https://doi.org/10.1039/C5NJ01479D	journal	January 2015
Chitosan-graft-poly(acrylic acid)/rice husk ash based superabsorbent hydrogel composite: preparation and characterization Rodrigues, Francisco H. A.; Fajardo, André R.; Pereira, Antonio G. B. Journal of Polymer Research, Vol. 19, Issue 12 https://doi.org/10.1007/s10965-012-0001-8	journal	November 2012
Syntheses and properties of superabsorbent composites based on natural guar gum and attapulgite Wang, Wenbo; Zheng, Yian; Wang, Aiqin Polymers for Advanced Technologies, Vol. 19, Issue 12 https://doi.org/10.1002/pat.1215	journal	December 2008
A Study of Polymer/Clay Hybrid Composite Sorbent-Based AAm/SMA Hydrogels and Semi-IPNs Composed of ɩ -Carrageenan and Montmorillonite for Water and Dye Sorption Karadağ, Erdener; Hasgül, Banu; Kundakci, Semİha Advances in Polymer Technology, Vol. 33, Issue 4 https://doi.org/10.1002/adv.21432	journal	May 2014
Separation free C3N4/SiO2 hybrid hydrogels as high active photocatalysts for TOC removal Zhang, Mo; Luo, Wenjiao; Wei, Zhen Applied Catalysis B: Environmental, Vol. 194 https://doi.org/10.1016/j.apcatb.2016.04.049	journal	October 2016
One-step in situ fabrication of a granular semi-IPN hydrogel based on chitosan and gelatin for fast and efficient adsorption of Cu2+ ion Wang, Wen-Bo; Huang, Da-Jian; Kang, Yu-Ru Colloids and Surfaces B: Biointerfaces, Vol. 106 https://doi.org/10.1016/j.colsurfb.2013.01.030	journal	June 2013
Enhanced Selectivity for Heavy Metals Using Polyaniline-Modified Hydrogel Zheng, Yian; Wang, Wenbo; Zhu, Gong Industrial & Engineering Chemistry Research, Vol. 52, Issue 13 https://doi.org/10.1021/ie302562f	journal	March 2013
pH dependence and thermodynamics of Hg(II) adsorption onto chitosan-poly(vinyl alcohol) hydrogel adsorbent Wang, Xiaohuan; Sun, Ruzhong; Wang, Chuanyi Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 441 https://doi.org/10.1016/j.colsurfa.2013.08.068	journal	January 2014
Environmental remediation of heavy metal ions from aqueous solution through hydrogel adsorption: a critical review Muya, Francis Ntumba; Sunday, Christopher Edoze; Baker, Priscilla Water Science and Technology, Vol. 73, Issue 5 https://doi.org/10.2166/wst.2015.567	journal	November 2015
New trends in removing heavy metals from industrial wastewater Barakat, M. A. Arabian Journal of Chemistry, Vol. 4, Issue 4 https://doi.org/10.1016/j.arabjc.2010.07.019	journal	October 2011
Template polymerization synthesis of hydrogel and silica composite for sorption of some rare earth elements Borai, E. H.; Hamed, M. G.; El-kamash, A. M. Journal of Colloid and Interface Science, Vol. 456 https://doi.org/10.1016/j.jcis.2015.06.020	journal	October 2015
Adsorption of Rare Earths(Ⅲ) Using an Efficient Sodium Alginate Hydrogel Cross-Linked with Poly-γ-Glutamate Xu, Shuxia; Wang, Zhiwei; Gao, Yuqian PLOS ONE, Vol. 10, Issue 5 https://doi.org/10.1371/journal.pone.0124826	journal	May 2015
Rapid enrichment of rare-earth metals by carboxymethyl cellulose-based open-cellular hydrogel adsorbent from HIPEs template Zhu, Yongfeng; Wang, Wenbo; Zheng, Yian Carbohydrate Polymers, Vol. 140 https://doi.org/10.1016/j.carbpol.2015.12.003	journal	April 2016
Hydrogels as new concentrators of the rare-earth and radioactive elements after their leaching from the rocks of the Lovozero Massif during INAA determination Kolesov, G. M.; Ermolaeva, V. N.; Mikhailova, A. V. Geochemistry International, Vol. 50, Issue 3 https://doi.org/10.1134/S0016702912030068	journal	March 2012
Extraction of Noble and Rare-Earth Metals from Aqueous Solutions by DNA Cross-Linked Hydrogels Maeda, Yuko; Zinchenko, Anatoly; Lopatina, Larisa I. ChemPlusChem, Vol. 78, Issue 7 https://doi.org/10.1002/cplu.201300047	journal	April 2013
Recovering Rare Earth Elements from Aqueous Solution with Porous Amine–Epoxy Networks Wilfong, Walter Christopher; Kail, Brian W.; Bank, Tracy L. ACS Applied Materials & Interfaces, Vol. 9, Issue 21 https://doi.org/10.1021/acsami.7b03859	journal	May 2017
Pseudo-second-order kinetic equations for modeling adsorption systems for removal of lead ions using multi-walled carbon nanotube Robati, Dariush Journal of Nanostructure in Chemistry, Vol. 3, Issue 1 https://doi.org/10.1186/2193-8865-3-55	journal	July 2013
Studies on preparing and adsorption property of grafting terpolymer microbeads of PEI-GMA/AM/MBA for bilirubin Gao, Baojiao; Lei, Haibo; Jiang, Liding Journal of Chromatography B, Vol. 853, Issue 1-2 https://doi.org/10.1016/j.jchromb.2007.02.055	journal	June 2007
Graft copolymerized chitosan—present status and applications Jayakumar, R.; Prabaharan, M.; Reis, R. L. Carbohydrate Polymers, Vol. 62, Issue 2 https://doi.org/10.1016/j.carbpol.2005.07.017	journal	November 2005
Spectroscopic study of the modification of cellulose with polyethylenimines: Cellulose Modification with Polyethylenimines De La Orden, M. U.; Matías, M. C.; Martínez Urreaga, J. Journal of Applied Polymer Science, Vol. 92, Issue 4 https://doi.org/10.1002/app.20236	journal	March 2004
Novel polypropylene–cellulose composites using polyethylenimine as coupling agent de la Orden, M. U.; González Sánchez, C.; González Quesada, M. Composites Part A: Applied Science and Manufacturing, Vol. 38, Issue 9 https://doi.org/10.1016/j.compositesa.2007.05.008	journal	September 2007
Characterization of a Polyamine Microsphere and Its Adsorption for Protein Wang, Feng; Liu, Pei; Nie, Tingting International Journal of Molecular Sciences, Vol. 14, Issue 1 https://doi.org/10.3390/ijms14010017	journal	December 2012
Precipitation of amorphous SiO2 particles and their properties Musić, S.; Filipović-Vinceković, N.; Sekovanić, L. Brazilian Journal of Chemical Engineering, Vol. 28, Issue 1 https://doi.org/10.1590/S0104-66322011000100011	journal	March 2011
Detection of LO and TO Phonons in Amorphous SiO2 Films by Oblique Incidence of IR Light Hübner, K.; Schumann, L.; Lehmann, A. physica status solidi (b), Vol. 104, Issue 1 https://doi.org/10.1002/pssb.2221040145	journal	March 1981
Effects of Acylation and Crosslinking on the Material Properties and Cadmium Ion Adsorption Capacity of Porous Chitosan Beads Hsien, Tzu-Yang; Rorrer, Gregory L. Separation Science and Technology, Vol. 30, Issue 12 https://doi.org/10.1080/01496399508021395	journal	July 1995
Modification of chitosan by swelling and crosslinking using epichlorohydrin as heavy metal Cr (VI) adsorbent in batik industry wastes Hastuti, B.; Masykur, A.; Hadi, S. IOP Conference Series: Materials Science and Engineering, Vol. 107 https://doi.org/10.1088/1757-899X/107/1/012020	journal	February 2016
Effect of glutaraldehyde cross-linking degree of chitosan/sporopollenin microcapsules on removal of copper(II) from aqueous solution Sargin, İdris; Arslan, Gulsin Desalination and Water Treatment, Vol. 57, Issue 23 https://doi.org/10.1080/19443994.2015.1038738	journal	April 2015
Environmental-sensitive chitosan-g-polyacrylamide/carboxymethylcellulose superabsorbent composites for wastewater purification I: synthesis and properties Ferfera-Harrar, Hafida; Aouaz, Nacera; Dairi, Nassima Polymer Bulletin, Vol. 73, Issue 3 https://doi.org/10.1007/s00289-015-1521-2	journal	September 2015
Crosslinked carboxymethylchitosan-g-poly(acrylic acid) copolymer as a novel superabsorbent polymer Chen, Yu; Tan, Hui-min Carbohydrate Research, Vol. 341, Issue 7 https://doi.org/10.1016/j.carres.2006.01.027	journal	May 2006
Synthesis and Properties of Poly(acrylic acid)/Mica Superabsorbent Nanocomposite Lin, Jianming; Wu, Jihuai; Yang, Zhengfang Macromolecular Rapid Communications, Vol. 22, Issue 6 https://doi.org/10.1002/1521-3927(20010301)22:6<422::AID-MARC422>3.0.CO;2-R	journal	March 2001
A Two-Stage Batch Sorption Optimized Design for Dye Removal to Minimize Contact Time Ho, Y. S.; McKay, G. Process Safety and Environmental Protection, Vol. 76, Issue 4 https://doi.org/10.1205/095758298529678	journal	November 1998
An EDTA-β-cyclodextrin material for the adsorption of rare earth elements and its application in preconcentration of rare earth elements in seawater Zhao, Feiping; Repo, Eveliina; Meng, Yong Journal of Colloid and Interface Science, Vol. 465 https://doi.org/10.1016/j.jcis.2015.11.069	journal	March 2016
Removal of aqueous rare earth elements (REEs) using nano-iron based materials Unal Yesiller, S.; Eroğlu, A. E.; Shahwan, T. Journal of Industrial and Engineering Chemistry, Vol. 19, Issue 3 https://doi.org/10.1016/j.jiec.2012.11.005	journal	May 2013
Unusual Complex Chemistry of Rare-Earth Elements: Large Ionic Radii—Small Coordination Numbers Dehnicke, Kurt; Greiner, Andreas Angewandte Chemie International Edition, Vol. 42, Issue 12 https://doi.org/10.1002/anie.200390346	journal	March 2003
Chromatographic Separation of Rare Earth Pairs by a Chelating Resin Having Bis(carboxymethyl)amino Groups Kanesato, Masatoshi; Yokoyama, Toshiro; M. Suzuki, Toshishige Bulletin of the Chemical Society of Japan, Vol. 62, Issue 11 https://doi.org/10.1246/bcsj.62.3451	journal	November 1989
Rare earths. LXXIX. Syntheses and properties of ethylenediamine chelates of the tripositive lanthanide ions Forsberg, John H.; Moeller, Therald Inorganic Chemistry, Vol. 8, Issue 4 https://doi.org/10.1021/ic50074a036	journal	April 1969
Synthesis and characterization of lanthanide [Ln(L)]2 complexes of N4O3 amine phenol ligands with phenolate oxygen bridges: evidence for very weak magnetic exchange between lanthanide ions Liu, Shuang; Gelmini, Lucio; Rettig, Steven J. Journal of the American Chemical Society, Vol. 114, Issue 15 https://doi.org/10.1021/ja00041a028	journal	July 1992
Adsorption of Co(II) and Ni(II) by EDTA- and/or DTPA-modified chitosan: Kinetic and equilibrium modeling Repo, Eveliina; Warchol, Jolanta K.; Kurniawan, Tonni Agustiono Chemical Engineering Journal, Vol. 161, Issue 1-2 https://doi.org/10.1016/j.cej.2010.04.030	journal	July 2010
Green Synthesis of Magnetic EDTA- and/or DTPA-Cross-Linked Chitosan Adsorbents for Highly Efficient Removal of Metals Zhao, Feiping; Repo, Eveliina; Sillanpää, Mika Industrial & Engineering Chemistry Research, Vol. 54, Issue 4 https://doi.org/10.1021/ie503874x	journal	January 2015
Modification of cation-exchange membrane properties by electro-adsorption of polyethyleneimine Amara, Mourad; Kerdjoudj, Hacene Desalination, Vol. 155, Issue 1 https://doi.org/10.1016/S0011-9164(03)00241-8	journal	May 2003
Sorbents with non-covalently immobilized β-diketones for preconcentration of rare earth elements Arkhipova, Anna Alexandrovna; Tsysin, Grigory Il’yich; Statkus, Mikhail Alexandrovich Talanta, Vol. 161 https://doi.org/10.1016/j.talanta.2016.08.074	journal	December 2016
Molecularly Imprinted Polymers: Present and Future Prospective Vasapollo, Giuseppe; Sole, Roberta Del; Mergola, Lucia International Journal of Molecular Sciences, Vol. 12, Issue 9 https://doi.org/10.3390/ijms12095908	journal	September 2011
Chelant extraction of heavy metals from contaminated soils Peters, Robert W. Journal of Hazardous Materials, Vol. 66, Issue 1-2 https://doi.org/10.1016/S0304-3894(99)00010-2	journal	April 1999
Bioadsorption of Rare Earth Elements through Cell Surface Display of Lanthanide Binding Tags Park, Dan M.; Reed, David W.; Yung, Mimi C. Environmental Science & Technology, Vol. 50, Issue 5 https://doi.org/10.1021/acs.est.5b06129	journal	February 2016
Selective recovery of heavy rare earth elements from apatite with an adsorbent bearing immobilized tridentate amido ligands Ogata, Takeshi; Narita, Hirokazu; Tanaka, Mikiya Separation and Purification Technology, Vol. 159 https://doi.org/10.1016/j.seppur.2016.01.008	journal	February 2016
Rapid and selective recovery of heavy rare earths by using an adsorbent with diglycol amic acid group Ogata, Takeshi; Narita, Hirokazu; Tanaka, Mikiya Hydrometallurgy, Vol. 155 https://doi.org/10.1016/j.hydromet.2015.04.015	journal	May 2015

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Title: Novel Polyethylenimine–Acrylamide/SiO₂ Hybrid Hydrogel Sorbent for Rare-Earth-Element Recycling from Aqueous Sources